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Development of glutamic acid incorporated with fluorine ionic liquid for dissolution of solid scale

Solid scale formation such as calcite (CaCO3), barite (BaSO4) and ferrite (FeS) in oil production is known to be one of the major problems that cost operator huge amount of expenditure. Chemical compound with carboxylic group and amine has been widely used due to its ability to dissolve and chelate...

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Main Author: Adam, Fatmawati
Format: Research Report
Language:English
Subjects:
TP Chemical technology
Online Access:http://umpir.ump.edu.my/id/eprint/36538/1/Development%20of%20glutamic%20acid%20incorporated%20with%20fluorine%20ionic%20liquid%20for%20dissolution%20of%20solid%20scale.wm.pdf
http://umpir.ump.edu.my/id/eprint/36538/
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spelling my.ump.umpir.365382023-03-15T06:26:28Z http://umpir.ump.edu.my/id/eprint/36538/ Development of glutamic acid incorporated with fluorine ionic liquid for dissolution of solid scale Adam, Fatmawati TP Chemical technology Solid scale formation such as calcite (CaCO3), barite (BaSO4) and ferrite (FeS) in oil production is known to be one of the major problems that cost operator huge amount of expenditure. Chemical compound with carboxylic group and amine has been widely used due to its ability to dissolve and chelate metal ions in solid scale to prevent reprecipitation. This research aims to to synthesise and characterise the amino acid-based solid scale dissolver from monosodium glutamate (MSG). The second objective is to evaluate the dissolution of calcite and barite solid scale using synthesised amino acid-based solid scale dissolver. Acidification produces two amino based dissolver, glutamic acid hydrochloride (solid) and glutamic acid hydro fluoroborate (liquid). Metathesis produces glutamic acid trifluoromethyl sulfonate (liquid). Glutamic acid hydrochloride can dissolve 3865 ppm of calcium in 24 hours at 60 °C and less than 5ppm of barium. Glu-BF4 can dissolve up to 2381 ppm of calcium and only 74 ppm of barium. GluTFMS can dissolve up to 2013.5 ppm of calcium and 60.0 ppm of barite. Based on the dissolution result, GluCl, GluBF4 and Glu TFMS is a good dissolver for calcite as it can dissolve more than 2000 ppm of calcite at low concentration. Barite is known as the most difficult solid scale to dissolve. In this study, all dissolver synthesised can only dissolve less than 100 ppm of barite. Research Report NonPeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/36538/1/Development%20of%20glutamic%20acid%20incorporated%20with%20fluorine%20ionic%20liquid%20for%20dissolution%20of%20solid%20scale.wm.pdf Adam, Fatmawati Development of glutamic acid incorporated with fluorine ionic liquid for dissolution of solid scale. , [Research Report: Research Report] (Unpublished)
institution Universiti Malaysia Pahang
building UMP Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Pahang
content_source UMP Institutional Repository
url_provider http://umpir.ump.edu.my/
language English
topic TP Chemical technology
spellingShingle TP Chemical technology
Adam, Fatmawati
Development of glutamic acid incorporated with fluorine ionic liquid for dissolution of solid scale
description Solid scale formation such as calcite (CaCO3), barite (BaSO4) and ferrite (FeS) in oil production is known to be one of the major problems that cost operator huge amount of expenditure. Chemical compound with carboxylic group and amine has been widely used due to its ability to dissolve and chelate metal ions in solid scale to prevent reprecipitation. This research aims to to synthesise and characterise the amino acid-based solid scale dissolver from monosodium glutamate (MSG). The second objective is to evaluate the dissolution of calcite and barite solid scale using synthesised amino acid-based solid scale dissolver. Acidification produces two amino based dissolver, glutamic acid hydrochloride (solid) and glutamic acid hydro fluoroborate (liquid). Metathesis produces glutamic acid trifluoromethyl sulfonate (liquid). Glutamic acid hydrochloride can dissolve 3865 ppm of calcium in 24 hours at 60 °C and less than 5ppm of barium. Glu-BF4 can dissolve up to 2381 ppm of calcium and only 74 ppm of barium. GluTFMS can dissolve up to 2013.5 ppm of calcium and 60.0 ppm of barite. Based on the dissolution result, GluCl, GluBF4 and Glu TFMS is a good dissolver for calcite as it can dissolve more than 2000 ppm of calcite at low concentration. Barite is known as the most difficult solid scale to dissolve. In this study, all dissolver synthesised can only dissolve less than 100 ppm of barite.
format Research Report
author Adam, Fatmawati
author_facet Adam, Fatmawati
author_sort Adam, Fatmawati
title Development of glutamic acid incorporated with fluorine ionic liquid for dissolution of solid scale
title_short Development of glutamic acid incorporated with fluorine ionic liquid for dissolution of solid scale
title_full Development of glutamic acid incorporated with fluorine ionic liquid for dissolution of solid scale
title_fullStr Development of glutamic acid incorporated with fluorine ionic liquid for dissolution of solid scale
title_full_unstemmed Development of glutamic acid incorporated with fluorine ionic liquid for dissolution of solid scale
title_sort development of glutamic acid incorporated with fluorine ionic liquid for dissolution of solid scale
url http://umpir.ump.edu.my/id/eprint/36538/1/Development%20of%20glutamic%20acid%20incorporated%20with%20fluorine%20ionic%20liquid%20for%20dissolution%20of%20solid%20scale.wm.pdf
http://umpir.ump.edu.my/id/eprint/36538/
_version_ 1761616591808626688
score 13.211869

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