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Quasi-anisotropic benefits in electrospun nickel–cobalt–manganese oxide nano-octahedron as anode for lithium-ion batteries

Despite having a significantly higher capacity (>1000 mA h g−1) as compared to the conventional graphite anode, the adoption of the conversion-type transition metal oxide (TMO) anodes is restricted due to their inferior cycling stability, sluggish ion transport behavior, high potential plateau vs...

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Main Authors: Ling, Jin Kiong, Karuppiah, Chelladurai, Das, Santanu, Singh, Vivek Kumar, Izan Izwan, Misnon, Mohd Hasbi, Ab. Rahim, Peng, Shengjie, Yang, Chun Chen, Rajan, Jose
Format: Article
Language:English
Published: Royal Society of Chemistry 2022
Subjects:
QD Chemistry
Online Access:http://umpir.ump.edu.my/id/eprint/34773/1/Quasi-anisotropic%20benefits%20in%20electrospun%20.pdf
http://umpir.ump.edu.my/id/eprint/34773/
https://doi.org/10.1039/D2NJ01462A
https://doi.org/10.1039/D2NJ01462A
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spelling my.ump.umpir.347732022-07-22T04:11:38Z http://umpir.ump.edu.my/id/eprint/34773/ Quasi-anisotropic benefits in electrospun nickel–cobalt–manganese oxide nano-octahedron as anode for lithium-ion batteries Ling, Jin Kiong Karuppiah, Chelladurai Das, Santanu Singh, Vivek Kumar Izan Izwan, Misnon Mohd Hasbi, Ab. Rahim Peng, Shengjie Yang, Chun Chen Rajan, Jose QD Chemistry Despite having a significantly higher capacity (>1000 mA h g−1) as compared to the conventional graphite anode, the adoption of the conversion-type transition metal oxide (TMO) anodes is restricted due to their inferior cycling stability, sluggish ion transport behavior, high potential plateau vs. Li/Li+, etc. Subsequent developments through nanostructuring and chemical composition engineering have improved the electrochemical performance of TMO anodes. Herein, a quasi-anisotropic nano-octahedron quaternary metal oxide composite is designed and synthesized using pilot-scale electrospinning by manipulating the conductivity of the polymeric solution. This morphology is first reported via electrospinning, which routinely produces nanofiber morphology. The fabricated nano-octahedron exhibited slightly higher gravimetry specific capacity (∼1184 mA h g−1 at 100 mA g−1) as compared to the nanofiber counterpart (1075 mA h g−1 at 100 mA g−1), with an initial capacity loss of 37.4% and 38.7%, respectively. Owing to the isotropic volume expansion, the nano-octahedron was capable of retaining 78.9% (or 291.2 mA h g−1) capacity after 500 charge/discharge cycles at 1000 mA g−1, compared to the inferior 24.1% (or 71.1 mA h g−1) for its nanofiber counterpart. Overall, the results discussed here provide valuable information on morphology design for future high-performance TMO anodes. Royal Society of Chemistry 2022 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/34773/1/Quasi-anisotropic%20benefits%20in%20electrospun%20.pdf Ling, Jin Kiong and Karuppiah, Chelladurai and Das, Santanu and Singh, Vivek Kumar and Izan Izwan, Misnon and Mohd Hasbi, Ab. Rahim and Peng, Shengjie and Yang, Chun Chen and Rajan, Jose (2022) Quasi-anisotropic benefits in electrospun nickel–cobalt–manganese oxide nano-octahedron as anode for lithium-ion batteries. New Journal of Chemistry, 46 (20). pp. 9799-9810. ISSN 1144-0546 https://doi.org/10.1039/D2NJ01462A https://doi.org/10.1039/D2NJ01462A
institution Universiti Malaysia Pahang
building UMP Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Pahang
content_source UMP Institutional Repository
url_provider http://umpir.ump.edu.my/
language English
topic QD Chemistry
spellingShingle QD Chemistry
Ling, Jin Kiong
Karuppiah, Chelladurai
Das, Santanu
Singh, Vivek Kumar
Izan Izwan, Misnon
Mohd Hasbi, Ab. Rahim
Peng, Shengjie
Yang, Chun Chen
Rajan, Jose
Quasi-anisotropic benefits in electrospun nickel–cobalt–manganese oxide nano-octahedron as anode for lithium-ion batteries
description Despite having a significantly higher capacity (>1000 mA h g−1) as compared to the conventional graphite anode, the adoption of the conversion-type transition metal oxide (TMO) anodes is restricted due to their inferior cycling stability, sluggish ion transport behavior, high potential plateau vs. Li/Li+, etc. Subsequent developments through nanostructuring and chemical composition engineering have improved the electrochemical performance of TMO anodes. Herein, a quasi-anisotropic nano-octahedron quaternary metal oxide composite is designed and synthesized using pilot-scale electrospinning by manipulating the conductivity of the polymeric solution. This morphology is first reported via electrospinning, which routinely produces nanofiber morphology. The fabricated nano-octahedron exhibited slightly higher gravimetry specific capacity (∼1184 mA h g−1 at 100 mA g−1) as compared to the nanofiber counterpart (1075 mA h g−1 at 100 mA g−1), with an initial capacity loss of 37.4% and 38.7%, respectively. Owing to the isotropic volume expansion, the nano-octahedron was capable of retaining 78.9% (or 291.2 mA h g−1) capacity after 500 charge/discharge cycles at 1000 mA g−1, compared to the inferior 24.1% (or 71.1 mA h g−1) for its nanofiber counterpart. Overall, the results discussed here provide valuable information on morphology design for future high-performance TMO anodes.
format Article
author Ling, Jin Kiong
Karuppiah, Chelladurai
Das, Santanu
Singh, Vivek Kumar
Izan Izwan, Misnon
Mohd Hasbi, Ab. Rahim
Peng, Shengjie
Yang, Chun Chen
Rajan, Jose
author_facet Ling, Jin Kiong
Karuppiah, Chelladurai
Das, Santanu
Singh, Vivek Kumar
Izan Izwan, Misnon
Mohd Hasbi, Ab. Rahim
Peng, Shengjie
Yang, Chun Chen
Rajan, Jose
author_sort Ling, Jin Kiong
title Quasi-anisotropic benefits in electrospun nickel–cobalt–manganese oxide nano-octahedron as anode for lithium-ion batteries
title_short Quasi-anisotropic benefits in electrospun nickel–cobalt–manganese oxide nano-octahedron as anode for lithium-ion batteries
title_full Quasi-anisotropic benefits in electrospun nickel–cobalt–manganese oxide nano-octahedron as anode for lithium-ion batteries
title_fullStr Quasi-anisotropic benefits in electrospun nickel–cobalt–manganese oxide nano-octahedron as anode for lithium-ion batteries
title_full_unstemmed Quasi-anisotropic benefits in electrospun nickel–cobalt–manganese oxide nano-octahedron as anode for lithium-ion batteries
title_sort quasi-anisotropic benefits in electrospun nickel–cobalt–manganese oxide nano-octahedron as anode for lithium-ion batteries
publisher Royal Society of Chemistry
publishDate 2022
url http://umpir.ump.edu.my/id/eprint/34773/1/Quasi-anisotropic%20benefits%20in%20electrospun%20.pdf
http://umpir.ump.edu.my/id/eprint/34773/
https://doi.org/10.1039/D2NJ01462A
https://doi.org/10.1039/D2NJ01462A
_version_ 1739828267517476864
score 13.211869

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