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Ni/Fibrous type SBA-15: Highly active and coke resistant catalyst for CO2 methanation

The rod-like SBA-15 was transformed into fibrous type SBA-15 (F-SBA-15). The Ni/F-SBA-15 was catalytically evaluated in CO2 methanation and compared with conventional Ni/SBA-15. A superior catalytic performance was shown by Ni/F-SBA-15 (CO2 conversion = 99.7%, and CH4 yield = 98.2%) than Ni/SBA-15 (...

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Main Authors:	Syahida Nasuha, Bukhari, Chi, Cheng Chong, Setiabudi, Herma Dina, Yoke, Wang Cheng, Lee, Peng Teh, Aishah, Abdul Jalil
Format:	Article
Language:	English
Published:	Elsevier 2021
Subjects:	TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/33852/1/NiFibrous%20type%20SBA-15.pdf http://umpir.ump.edu.my/id/eprint/33852/ https://doi.org/10.1016/j.ces.2020.116141 https://doi.org/10.1016/j.ces.2020.116141
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id	my.ump.umpir.33852
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spelling	my.ump.umpir.338522022-04-22T04:25:43Z http://umpir.ump.edu.my/id/eprint/33852/ Ni/Fibrous type SBA-15: Highly active and coke resistant catalyst for CO2 methanation Syahida Nasuha, Bukhari Chi, Cheng Chong Setiabudi, Herma Dina Yoke, Wang Cheng Lee, Peng Teh Aishah, Abdul Jalil TP Chemical technology The rod-like SBA-15 was transformed into fibrous type SBA-15 (F-SBA-15). The Ni/F-SBA-15 was catalytically evaluated in CO2 methanation and compared with conventional Ni/SBA-15. A superior catalytic performance was shown by Ni/F-SBA-15 (CO2 conversion = 99.7%, and CH4 yield = 98.2%) than Ni/SBA-15 (CO2 conversion = 91.1%, and CH4 yield = 87.5%). This phenomenon was attributed to the favorable physicochemical properties of F-SBA-15 as evidenced by the characterization results. A higher homogeneity of finer Ni was embedded onto the F-SBA-15 support, subsequently strengthened the Ni interaction with F-SBA-15, and increased the amount of moderate basic sites. The in situ FTIR studies evidenced the CO2 methanation over both catalysts proceeded via CO2 dissociation pathway. Three intermediate species (linear carbonyl, unidentate, and bidentate carbonates) were detected for Ni/F-SBA-15, while only bidentate carbonates were detected for Ni/SBA-15, signifying excellent catalytic attributes of Ni/F-SBA-15. Additionally, Ni/F-SBA-15 demonstrated higher stability and coke resistance ability than Ni/SBA-15. Elsevier 2021 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/33852/1/NiFibrous%20type%20SBA-15.pdf Syahida Nasuha, Bukhari and Chi, Cheng Chong and Setiabudi, Herma Dina and Yoke, Wang Cheng and Lee, Peng Teh and Aishah, Abdul Jalil (2021) Ni/Fibrous type SBA-15: Highly active and coke resistant catalyst for CO2 methanation. Chemical Engineering Science, 229 (116141). pp. 1-12. ISSN 0009-2509 https://doi.org/10.1016/j.ces.2020.116141 https://doi.org/10.1016/j.ces.2020.116141
institution	Universiti Malaysia Pahang
building	UMP Library
collection	Institutional Repository
continent	Asia
country	Malaysia
content_provider	Universiti Malaysia Pahang
content_source	UMP Institutional Repository
url_provider	http://umpir.ump.edu.my/
language	English
topic	TP Chemical technology
spellingShingle	TP Chemical technology Syahida Nasuha, Bukhari Chi, Cheng Chong Setiabudi, Herma Dina Yoke, Wang Cheng Lee, Peng Teh Aishah, Abdul Jalil Ni/Fibrous type SBA-15: Highly active and coke resistant catalyst for CO2 methanation
description	The rod-like SBA-15 was transformed into fibrous type SBA-15 (F-SBA-15). The Ni/F-SBA-15 was catalytically evaluated in CO2 methanation and compared with conventional Ni/SBA-15. A superior catalytic performance was shown by Ni/F-SBA-15 (CO2 conversion = 99.7%, and CH4 yield = 98.2%) than Ni/SBA-15 (CO2 conversion = 91.1%, and CH4 yield = 87.5%). This phenomenon was attributed to the favorable physicochemical properties of F-SBA-15 as evidenced by the characterization results. A higher homogeneity of finer Ni was embedded onto the F-SBA-15 support, subsequently strengthened the Ni interaction with F-SBA-15, and increased the amount of moderate basic sites. The in situ FTIR studies evidenced the CO2 methanation over both catalysts proceeded via CO2 dissociation pathway. Three intermediate species (linear carbonyl, unidentate, and bidentate carbonates) were detected for Ni/F-SBA-15, while only bidentate carbonates were detected for Ni/SBA-15, signifying excellent catalytic attributes of Ni/F-SBA-15. Additionally, Ni/F-SBA-15 demonstrated higher stability and coke resistance ability than Ni/SBA-15.
format	Article
author	Syahida Nasuha, Bukhari Chi, Cheng Chong Setiabudi, Herma Dina Yoke, Wang Cheng Lee, Peng Teh Aishah, Abdul Jalil
author_facet	Syahida Nasuha, Bukhari Chi, Cheng Chong Setiabudi, Herma Dina Yoke, Wang Cheng Lee, Peng Teh Aishah, Abdul Jalil
author_sort	Syahida Nasuha, Bukhari
title	Ni/Fibrous type SBA-15: Highly active and coke resistant catalyst for CO2 methanation
title_short	Ni/Fibrous type SBA-15: Highly active and coke resistant catalyst for CO2 methanation
title_full	Ni/Fibrous type SBA-15: Highly active and coke resistant catalyst for CO2 methanation
title_fullStr	Ni/Fibrous type SBA-15: Highly active and coke resistant catalyst for CO2 methanation
title_full_unstemmed	Ni/Fibrous type SBA-15: Highly active and coke resistant catalyst for CO2 methanation
title_sort	ni/fibrous type sba-15: highly active and coke resistant catalyst for co2 methanation
publisher	Elsevier
publishDate	2021
url	http://umpir.ump.edu.my/id/eprint/33852/1/NiFibrous%20type%20SBA-15.pdf http://umpir.ump.edu.my/id/eprint/33852/ https://doi.org/10.1016/j.ces.2020.116141 https://doi.org/10.1016/j.ces.2020.116141
_version_	1731225804116852736
score	13.211869

Ni/Fibrous type SBA-15: Highly active and coke resistant catalyst for CO2 methanation

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