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Synthesis and electrochemical properties of ternary Co-, Cu- and Ni- based metal-organic frameworks electrode for battery supercapacitor hybrid application

Metal-organic frameworks (MOFs) composed by coordination bonds between metal ion with organic linker has a uniform combination of micro and mesoporous structures has been used for several application including battery supercapacitor hybrid. (BSH). In BSH, MOF offer several advantages including high...

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Main Authors:	Amir Luqman, Sanusi, Nurul Khairiyyah, Mohd Zain, Izan Izwan, Misnon, Ahmad Salihin, Samsudin, Jose, Rajan
Format:	Book Chapter
Language:	English English English
Published:	Trans Tech Publications 2020
Subjects:	QD Chemistry TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/33732/1/amir.pdf http://umpir.ump.edu.my/id/eprint/33732/7/MSF.981.pdf http://umpir.ump.edu.my/id/eprint/33732/8/Synthesis%20and%20electrochemical%20properties%20of%20ternary%20.pdf http://umpir.ump.edu.my/id/eprint/33732/ https://doi.org/10.4028/www.scientific.net/MSF.981.17 https://www.scientific.net/MSF.981.17
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spelling	my.ump.umpir.337322024-01-03T03:30:59Z http://umpir.ump.edu.my/id/eprint/33732/ Synthesis and electrochemical properties of ternary Co-, Cu- and Ni- based metal-organic frameworks electrode for battery supercapacitor hybrid application Amir Luqman, Sanusi Nurul Khairiyyah, Mohd Zain Izan Izwan, Misnon Ahmad Salihin, Samsudin Jose, Rajan QD Chemistry TP Chemical technology Metal-organic frameworks (MOFs) composed by coordination bonds between metal ion with organic linker has a uniform combination of micro and mesoporous structures has been used for several application including battery supercapacitor hybrid. (BSH). In BSH, MOF offer several advantages including high surface area, porous, and structure tunability. This paper reports the synthesis of ternary MOF of copper (Cu), nickel (Ni) and cobalt (Co) with 1,4-benzenedicarboxylic acid. The Co/Cu/Ni-MOF is synthesized using hydrothermal method at 160 °C for 12h and further develop as a BSH electrode. The physicochemical properties of MOF were characterized using FESEM, FTIR, XRD, BET and the electrochemical properties were evaluated using cyclic voltammetry (CV), charge-discharge cycling (CDC) and electrochemical impedance spectroscopy (EIS). Electrochemical analysis indicated that the MOF has high specific capacitance (CS) of 591 F g-1 at a current density of 1 A g-1 and 519 F g-1 at scan rate of 2 mV s-1, and possess low series resistance (RS) of 0.44 Ω and equivalent distributed resistance (Rd) of 1.07 Ω. Trans Tech Publications 2020-03-12 Book Chapter PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/33732/1/amir.pdf pdf en http://umpir.ump.edu.my/id/eprint/33732/7/MSF.981.pdf pdf en http://umpir.ump.edu.my/id/eprint/33732/8/Synthesis%20and%20electrochemical%20properties%20of%20ternary%20.pdf Amir Luqman, Sanusi and Nurul Khairiyyah, Mohd Zain and Izan Izwan, Misnon and Ahmad Salihin, Samsudin and Jose, Rajan (2020) Synthesis and electrochemical properties of ternary Co-, Cu- and Ni- based metal-organic frameworks electrode for battery supercapacitor hybrid application. In: Materials Science Forum. Trans Tech Publications, Switzerland, pp. 17-22. ISBN 978-303571664-1 https://doi.org/10.4028/www.scientific.net/MSF.981.17 https://www.scientific.net/MSF.981.17
institution	Universiti Malaysia Pahang Al-Sultan Abdullah
building	UMPSA Library
collection	Institutional Repository
continent	Asia
country	Malaysia
content_provider	Universiti Malaysia Pahang Al-Sultan Abdullah
content_source	UMPSA Institutional Repository
url_provider	http://umpir.ump.edu.my/
language	English English English
topic	QD Chemistry TP Chemical technology
spellingShingle	QD Chemistry TP Chemical technology Amir Luqman, Sanusi Nurul Khairiyyah, Mohd Zain Izan Izwan, Misnon Ahmad Salihin, Samsudin Jose, Rajan Synthesis and electrochemical properties of ternary Co-, Cu- and Ni- based metal-organic frameworks electrode for battery supercapacitor hybrid application
description	Metal-organic frameworks (MOFs) composed by coordination bonds between metal ion with organic linker has a uniform combination of micro and mesoporous structures has been used for several application including battery supercapacitor hybrid. (BSH). In BSH, MOF offer several advantages including high surface area, porous, and structure tunability. This paper reports the synthesis of ternary MOF of copper (Cu), nickel (Ni) and cobalt (Co) with 1,4-benzenedicarboxylic acid. The Co/Cu/Ni-MOF is synthesized using hydrothermal method at 160 °C for 12h and further develop as a BSH electrode. The physicochemical properties of MOF were characterized using FESEM, FTIR, XRD, BET and the electrochemical properties were evaluated using cyclic voltammetry (CV), charge-discharge cycling (CDC) and electrochemical impedance spectroscopy (EIS). Electrochemical analysis indicated that the MOF has high specific capacitance (CS) of 591 F g-1 at a current density of 1 A g-1 and 519 F g-1 at scan rate of 2 mV s-1, and possess low series resistance (RS) of 0.44 Ω and equivalent distributed resistance (Rd) of 1.07 Ω.
format	Book Chapter
author	Amir Luqman, Sanusi Nurul Khairiyyah, Mohd Zain Izan Izwan, Misnon Ahmad Salihin, Samsudin Jose, Rajan
author_facet	Amir Luqman, Sanusi Nurul Khairiyyah, Mohd Zain Izan Izwan, Misnon Ahmad Salihin, Samsudin Jose, Rajan
author_sort	Amir Luqman, Sanusi
title	Synthesis and electrochemical properties of ternary Co-, Cu- and Ni- based metal-organic frameworks electrode for battery supercapacitor hybrid application
title_short	Synthesis and electrochemical properties of ternary Co-, Cu- and Ni- based metal-organic frameworks electrode for battery supercapacitor hybrid application
title_full	Synthesis and electrochemical properties of ternary Co-, Cu- and Ni- based metal-organic frameworks electrode for battery supercapacitor hybrid application
title_fullStr	Synthesis and electrochemical properties of ternary Co-, Cu- and Ni- based metal-organic frameworks electrode for battery supercapacitor hybrid application
title_full_unstemmed	Synthesis and electrochemical properties of ternary Co-, Cu- and Ni- based metal-organic frameworks electrode for battery supercapacitor hybrid application
title_sort	synthesis and electrochemical properties of ternary co-, cu- and ni- based metal-organic frameworks electrode for battery supercapacitor hybrid application
publisher	Trans Tech Publications
publishDate	2020
url	http://umpir.ump.edu.my/id/eprint/33732/1/amir.pdf http://umpir.ump.edu.my/id/eprint/33732/7/MSF.981.pdf http://umpir.ump.edu.my/id/eprint/33732/8/Synthesis%20and%20electrochemical%20properties%20of%20ternary%20.pdf http://umpir.ump.edu.my/id/eprint/33732/ https://doi.org/10.4028/www.scientific.net/MSF.981.17 https://www.scientific.net/MSF.981.17
_version_	1822923955116179456
score	13.244109

Synthesis and electrochemical properties of ternary Co-, Cu- and Ni- based metal-organic frameworks electrode for battery supercapacitor hybrid application

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