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Synthesis and electrochemical properties of ternary Co-, Cu- and Ni- based metal-organic frameworks electrode for battery supercapacitor hybrid application

Metal-organic frameworks (MOFs) composed by coordination bonds between metal ion with organic linker has a uniform combination of micro and mesoporous structures has been used for several application including battery supercapacitor hybrid. (BSH). In BSH, MOF offer several advantages including high...

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Main Authors: Sanusi, Amir Luqman, Nurul Khairiyyah, Mohd Zain, Izan Izwan, Misnon, Ahmad Salihin, Samsudin, Jose, Rajan
Format: Book Section
Language:English
English
English
Published: Trans Tech Publications 2020
Subjects:
QD Chemistry
TP Chemical technology
Online Access:http://umpir.ump.edu.my/id/eprint/33732/1/amir.pdf
http://umpir.ump.edu.my/id/eprint/33732/7/MSF.981.pdf
http://umpir.ump.edu.my/id/eprint/33732/8/Synthesis%20and%20electrochemical%20properties%20of%20ternary%20.pdf
http://umpir.ump.edu.my/id/eprint/33732/
https://doi.org/10.4028/www.scientific.net/MSF.981.17
https://www.scientific.net/MSF.981.17
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spelling my.ump.umpir.337322022-07-19T02:11:00Z http://umpir.ump.edu.my/id/eprint/33732/ Synthesis and electrochemical properties of ternary Co-, Cu- and Ni- based metal-organic frameworks electrode for battery supercapacitor hybrid application Sanusi, Amir Luqman Nurul Khairiyyah, Mohd Zain Izan Izwan, Misnon Ahmad Salihin, Samsudin Jose, Rajan QD Chemistry TP Chemical technology Metal-organic frameworks (MOFs) composed by coordination bonds between metal ion with organic linker has a uniform combination of micro and mesoporous structures has been used for several application including battery supercapacitor hybrid. (BSH). In BSH, MOF offer several advantages including high surface area, porous, and structure tunability. This paper reports the synthesis of ternary MOF of copper (Cu), nickel (Ni) and cobalt (Co) with 1,4-benzenedicarboxylic acid. The Co/Cu/Ni-MOF is synthesized using hydrothermal method at 160 °C for 12h and further develop as a BSH electrode. The physicochemical properties of MOF were characterized using FESEM, FTIR, XRD, BET and the electrochemical properties were evaluated using cyclic voltammetry (CV), charge-discharge cycling (CDC) and electrochemical impedance spectroscopy (EIS). Electrochemical analysis indicated that the MOF has high specific capacitance (CS) of 591 F g-1 at a current density of 1 A g-1 and 519 F g-1 at scan rate of 2 mV s-1, and possess low series resistance (RS) of 0.44 Ω and equivalent distributed resistance (Rd) of 1.07 Ω. Trans Tech Publications 2020-03-12 Book Section PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/33732/1/amir.pdf pdf en http://umpir.ump.edu.my/id/eprint/33732/7/MSF.981.pdf pdf en http://umpir.ump.edu.my/id/eprint/33732/8/Synthesis%20and%20electrochemical%20properties%20of%20ternary%20.pdf Sanusi, Amir Luqman and Nurul Khairiyyah, Mohd Zain and Izan Izwan, Misnon and Ahmad Salihin, Samsudin and Jose, Rajan (2020) Synthesis and electrochemical properties of ternary Co-, Cu- and Ni- based metal-organic frameworks electrode for battery supercapacitor hybrid application. In: Materials Science Forum. Trans Tech Publications, Switzerland, pp. 17-22. ISBN 978-303571664-1 https://doi.org/10.4028/www.scientific.net/MSF.981.17 https://www.scientific.net/MSF.981.17
institution Universiti Malaysia Pahang
building UMP Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Pahang
content_source UMP Institutional Repository
url_provider http://umpir.ump.edu.my/
language English
English
English
topic QD Chemistry
TP Chemical technology
spellingShingle QD Chemistry
TP Chemical technology
Sanusi, Amir Luqman
Nurul Khairiyyah, Mohd Zain
Izan Izwan, Misnon
Ahmad Salihin, Samsudin
Jose, Rajan
Synthesis and electrochemical properties of ternary Co-, Cu- and Ni- based metal-organic frameworks electrode for battery supercapacitor hybrid application
description Metal-organic frameworks (MOFs) composed by coordination bonds between metal ion with organic linker has a uniform combination of micro and mesoporous structures has been used for several application including battery supercapacitor hybrid. (BSH). In BSH, MOF offer several advantages including high surface area, porous, and structure tunability. This paper reports the synthesis of ternary MOF of copper (Cu), nickel (Ni) and cobalt (Co) with 1,4-benzenedicarboxylic acid. The Co/Cu/Ni-MOF is synthesized using hydrothermal method at 160 °C for 12h and further develop as a BSH electrode. The physicochemical properties of MOF were characterized using FESEM, FTIR, XRD, BET and the electrochemical properties were evaluated using cyclic voltammetry (CV), charge-discharge cycling (CDC) and electrochemical impedance spectroscopy (EIS). Electrochemical analysis indicated that the MOF has high specific capacitance (CS) of 591 F g-1 at a current density of 1 A g-1 and 519 F g-1 at scan rate of 2 mV s-1, and possess low series resistance (RS) of 0.44 Ω and equivalent distributed resistance (Rd) of 1.07 Ω.
format Book Section
author Sanusi, Amir Luqman
Nurul Khairiyyah, Mohd Zain
Izan Izwan, Misnon
Ahmad Salihin, Samsudin
Jose, Rajan
author_facet Sanusi, Amir Luqman
Nurul Khairiyyah, Mohd Zain
Izan Izwan, Misnon
Ahmad Salihin, Samsudin
Jose, Rajan
author_sort Sanusi, Amir Luqman
title Synthesis and electrochemical properties of ternary Co-, Cu- and Ni- based metal-organic frameworks electrode for battery supercapacitor hybrid application
title_short Synthesis and electrochemical properties of ternary Co-, Cu- and Ni- based metal-organic frameworks electrode for battery supercapacitor hybrid application
title_full Synthesis and electrochemical properties of ternary Co-, Cu- and Ni- based metal-organic frameworks electrode for battery supercapacitor hybrid application
title_fullStr Synthesis and electrochemical properties of ternary Co-, Cu- and Ni- based metal-organic frameworks electrode for battery supercapacitor hybrid application
title_full_unstemmed Synthesis and electrochemical properties of ternary Co-, Cu- and Ni- based metal-organic frameworks electrode for battery supercapacitor hybrid application
title_sort synthesis and electrochemical properties of ternary co-, cu- and ni- based metal-organic frameworks electrode for battery supercapacitor hybrid application
publisher Trans Tech Publications
publishDate 2020
url http://umpir.ump.edu.my/id/eprint/33732/1/amir.pdf
http://umpir.ump.edu.my/id/eprint/33732/7/MSF.981.pdf
http://umpir.ump.edu.my/id/eprint/33732/8/Synthesis%20and%20electrochemical%20properties%20of%20ternary%20.pdf
http://umpir.ump.edu.my/id/eprint/33732/
https://doi.org/10.4028/www.scientific.net/MSF.981.17
https://www.scientific.net/MSF.981.17
_version_ 1739828260493066240
score 13.211869

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