Dual-functional single stranded deoxyribonucleic acid for graphene

This study reports a one-step process to produce single-stranded deoxyribonucleic acid (ssDNA) functionalized reduced graphene oxide (ssDNA/rGO). The ssDNA acts as a reducing agent for the reduction of GO into rGO and simultaneously performs functionalization onto rGO, which is confirmed by spectros...

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Bibliographic Details
Main Authors: Albarqouni, Yasin, Ali, Gomaa A. M., Lee, Soon Poh, Mohd Hairul, Ab. Rahim, Algarni, H., Chong, Kwok Feng
Format: Article
Language:English
English
Published: Elsevier 2021
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Online Access:http://umpir.ump.edu.my/id/eprint/32602/1/Dual-functional%20single%20stranded%20deoxyribonucleic%20acid%20for%20graphene%20.pdf
http://umpir.ump.edu.my/id/eprint/32602/2/Dual-functional%20single%20stranded%20deoxyribonucleic%20acid%20for%20graphene_FULL.pdf
http://umpir.ump.edu.my/id/eprint/32602/
https://doi.org/10.1016/j.electacta.2021.139366
https://doi.org/10.1016/j.electacta.2021.139366
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Summary:This study reports a one-step process to produce single-stranded deoxyribonucleic acid (ssDNA) functionalized reduced graphene oxide (ssDNA/rGO). The ssDNA acts as a reducing agent for the reduction of GO into rGO and simultaneously performs functionalization onto rGO, which is confirmed by spectroscopic and microscopic analyses. Such reduction capability is not being observed in double-stranded DNA (dsDNA). The high charge density of ssDNA on rGO is investigated for its application in electrochemical supercapacitor, and it is revealed that the ssDNA/rGO exhibits a specific capacitance of 129 F g−1 with high stability (92%) up to 10,000 cycles. The findings open the gateway to develop a biomolecule-based energy storage system.