Cover Image

Sorption and thermodynamic study of nitrate removal by using Amberlite IRA 900 (AI900) resin

This paper presents the efficiency removal and thermodynamics studies of nitrates by using ion exchange resin, Amberlite IRA 900-Cl (AI900). The effect of experimental factors of contact time resin (1–6 h), resin dosage resin (1–6 g), initial concentration of nitrate influent in the range between 20...

Full description

Saved in:
Bibliographic Details
Main Authors: Aimi Asyiqin, Abu Kassim, Norhayati, Abdullah
Format: Article
Language:English
Published: Elsevier Ltd 2021
Subjects:
TP Chemical technology
Online Access:http://umpir.ump.edu.my/id/eprint/32096/1/Sorption%20and%20Thermodynamic%20Study%20of%20Nitrate%20Removal%20by%20Using%20Amberlite%20IRA%20900%20%28AI900%29%20Resin%20%281%29.pdf
http://umpir.ump.edu.my/id/eprint/32096/
https://doi.org/10.1016/j.matpr.2020.11.1014
https://doi.org/10.1016/j.matpr.2020.11.1014
Tags: Add Tag
No Tags, Be the first to tag this record!
id my.ump.umpir.32096
record_format eprints
spelling my.ump.umpir.320962021-09-20T03:45:32Z http://umpir.ump.edu.my/id/eprint/32096/ Sorption and thermodynamic study of nitrate removal by using Amberlite IRA 900 (AI900) resin Aimi Asyiqin, Abu Kassim Norhayati, Abdullah TP Chemical technology This paper presents the efficiency removal and thermodynamics studies of nitrates by using ion exchange resin, Amberlite IRA 900-Cl (AI900). The effect of experimental factors of contact time resin (1–6 h), resin dosage resin (1–6 g), initial concentration of nitrate influent in the range between 20 and 250 mg/L and temperature between 25 and 65 °C were studied by using a batch sorption method. From the overall study, the data clearly demonstrated that the optimum temperature for the nitrate ions were removed was at 25℃ as the sorption of nitrate decreased when the temperature increased. The sorption managed to obtain 85% removal of nitrates from bulk concentration by using 2 g of AI900 resin in 1-hour contact time. While increasing the contact time of resin until 6 h in 1 g resin and increasing the amount of resin to 6 g of AI900 resin in 1-hour contact time, the adsorption capacity managed to rise at 98 and 97%, respectively. AI900 resin demonstrated an exothermic and spontaneous process of nitrate removal at the varied temperatures as both enthalpy (ΔH°) and entropy (ΔS°) showed negative signs at −26.801 kJ/mol and −43 J/K∙mol respectively. The sorption was feasible and favored at low temperature as the Gibb energy (ΔG°) showed negative sign and decreased with the increasing temperature. Elsevier Ltd 2021 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/32096/1/Sorption%20and%20Thermodynamic%20Study%20of%20Nitrate%20Removal%20by%20Using%20Amberlite%20IRA%20900%20%28AI900%29%20Resin%20%281%29.pdf Aimi Asyiqin, Abu Kassim and Norhayati, Abdullah (2021) Sorption and thermodynamic study of nitrate removal by using Amberlite IRA 900 (AI900) resin. Materials Today: Proceedings, 41 (Part 1). pp. 102-108. ISSN 2214-7853 https://doi.org/10.1016/j.matpr.2020.11.1014 https://doi.org/10.1016/j.matpr.2020.11.1014
institution Universiti Malaysia Pahang
building UMP Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Pahang
content_source UMP Institutional Repository
url_provider http://umpir.ump.edu.my/
language English
topic TP Chemical technology
spellingShingle TP Chemical technology
Aimi Asyiqin, Abu Kassim
Norhayati, Abdullah
Sorption and thermodynamic study of nitrate removal by using Amberlite IRA 900 (AI900) resin
description This paper presents the efficiency removal and thermodynamics studies of nitrates by using ion exchange resin, Amberlite IRA 900-Cl (AI900). The effect of experimental factors of contact time resin (1–6 h), resin dosage resin (1–6 g), initial concentration of nitrate influent in the range between 20 and 250 mg/L and temperature between 25 and 65 °C were studied by using a batch sorption method. From the overall study, the data clearly demonstrated that the optimum temperature for the nitrate ions were removed was at 25℃ as the sorption of nitrate decreased when the temperature increased. The sorption managed to obtain 85% removal of nitrates from bulk concentration by using 2 g of AI900 resin in 1-hour contact time. While increasing the contact time of resin until 6 h in 1 g resin and increasing the amount of resin to 6 g of AI900 resin in 1-hour contact time, the adsorption capacity managed to rise at 98 and 97%, respectively. AI900 resin demonstrated an exothermic and spontaneous process of nitrate removal at the varied temperatures as both enthalpy (ΔH°) and entropy (ΔS°) showed negative signs at −26.801 kJ/mol and −43 J/K∙mol respectively. The sorption was feasible and favored at low temperature as the Gibb energy (ΔG°) showed negative sign and decreased with the increasing temperature.
format Article
author Aimi Asyiqin, Abu Kassim
Norhayati, Abdullah
author_facet Aimi Asyiqin, Abu Kassim
Norhayati, Abdullah
author_sort Aimi Asyiqin, Abu Kassim
title Sorption and thermodynamic study of nitrate removal by using Amberlite IRA 900 (AI900) resin
title_short Sorption and thermodynamic study of nitrate removal by using Amberlite IRA 900 (AI900) resin
title_full Sorption and thermodynamic study of nitrate removal by using Amberlite IRA 900 (AI900) resin
title_fullStr Sorption and thermodynamic study of nitrate removal by using Amberlite IRA 900 (AI900) resin
title_full_unstemmed Sorption and thermodynamic study of nitrate removal by using Amberlite IRA 900 (AI900) resin
title_sort sorption and thermodynamic study of nitrate removal by using amberlite ira 900 (ai900) resin
publisher Elsevier Ltd
publishDate 2021
url http://umpir.ump.edu.my/id/eprint/32096/1/Sorption%20and%20Thermodynamic%20Study%20of%20Nitrate%20Removal%20by%20Using%20Amberlite%20IRA%20900%20%28AI900%29%20Resin%20%281%29.pdf
http://umpir.ump.edu.my/id/eprint/32096/
https://doi.org/10.1016/j.matpr.2020.11.1014
https://doi.org/10.1016/j.matpr.2020.11.1014
_version_ 1712285331847380992
score 13.211869

Similar Items