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Characterization of a novel terpolymer containing maleic anhydride-co-stearyl methacrylate-cobenhely acrylate for wax inhibition application

Wax deposition in petroleum pipelines is deliberated as one of the most severe operational issues, and extraordinary efforts have been made to remediate and prevent this flow assurance problem. Using, polymeric pour point depressants (PPD) as a wax control strategy to improve the fluidity of waxy cr...

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Main Authors: Elganidi, I., Elarbe, B.S., Norhayati, Abdullah, N., Ridzuan
Format: Article
Language:English
Published: IOP Publishing Ltd 2019
Subjects:
T Technology (General)
TD Environmental technology. Sanitary engineering
TP Chemical technology
Online Access:http://umpir.ump.edu.my/id/eprint/31918/1/IOP%20Conference%20Series%20Materials%20Science%20and%20Engineering.pdf
http://umpir.ump.edu.my/id/eprint/31918/
https://iopscience.iop.org/article/10.1088/1757-899X/702/1/012027
https://iopscience.iop.org/article/10.1088/1757-899X/702/1/012027
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spelling my.ump.umpir.319182021-09-01T08:03:31Z http://umpir.ump.edu.my/id/eprint/31918/ Characterization of a novel terpolymer containing maleic anhydride-co-stearyl methacrylate-cobenhely acrylate for wax inhibition application Elganidi, I. Elarbe, B.S. Norhayati, Abdullah N., Ridzuan T Technology (General) TD Environmental technology. Sanitary engineering TP Chemical technology Wax deposition in petroleum pipelines is deliberated as one of the most severe operational issues, and extraordinary efforts have been made to remediate and prevent this flow assurance problem. Using, polymeric pour point depressants (PPD) as a wax control strategy to improve the fluidity of waxy crude oil and reduce the pour point have received significant attention. The purpose of the current research is to synthesize novel terpolymers which used as PPD and viscosity improvers. The synthesis process occurred via polymerization of stearyl methacrylate (SMA), benhely acrylate (BA), and maleic anhydride (MA) monomers using free radical polymerization method in toluene as a solvent, and (1 wt%) benzoyl peroxide (BZP) as initiator. The chemical structure of the prepared terpolymer was characterized by FTIR and NMR. Also, the crystallization behavior of paraffin wax was investigated by differential scanning calorimetry (DSC). Experimental investigations furnish that the synthesized PPD showed high yield (87%) at the concentration (1:1:1) of BA-co-SMA-co-MA. From FTIR and 1HNMR characterization results observed that maleic anhydride moiety, alkyl chain moiety, and methacrylate moiety are existing in the prepared terpolymer. Furthermore, DSC analysis showed that the glass transition temperature of the prepared terpolymer is weakly stated over a wide temperature range. IOP Publishing Ltd 2019 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/31918/1/IOP%20Conference%20Series%20Materials%20Science%20and%20Engineering.pdf Elganidi, I. and Elarbe, B.S. and Norhayati, Abdullah and N., Ridzuan (2019) Characterization of a novel terpolymer containing maleic anhydride-co-stearyl methacrylate-cobenhely acrylate for wax inhibition application. IOP Conference Series: Materials Science and Engineering, 702 (1). pp. 12-27. ISSN 17578981. (Published) https://iopscience.iop.org/article/10.1088/1757-899X/702/1/012027 https://iopscience.iop.org/article/10.1088/1757-899X/702/1/012027
institution Universiti Malaysia Pahang Al-Sultan Abdullah
building UMPSA Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Pahang Al-Sultan Abdullah
content_source UMPSA Institutional Repository
url_provider http://umpir.ump.edu.my/
language English
topic T Technology (General)
TD Environmental technology. Sanitary engineering
TP Chemical technology
spellingShingle T Technology (General)
TD Environmental technology. Sanitary engineering
TP Chemical technology
Elganidi, I.
Elarbe, B.S.
Norhayati, Abdullah
N., Ridzuan
Characterization of a novel terpolymer containing maleic anhydride-co-stearyl methacrylate-cobenhely acrylate for wax inhibition application
description Wax deposition in petroleum pipelines is deliberated as one of the most severe operational issues, and extraordinary efforts have been made to remediate and prevent this flow assurance problem. Using, polymeric pour point depressants (PPD) as a wax control strategy to improve the fluidity of waxy crude oil and reduce the pour point have received significant attention. The purpose of the current research is to synthesize novel terpolymers which used as PPD and viscosity improvers. The synthesis process occurred via polymerization of stearyl methacrylate (SMA), benhely acrylate (BA), and maleic anhydride (MA) monomers using free radical polymerization method in toluene as a solvent, and (1 wt%) benzoyl peroxide (BZP) as initiator. The chemical structure of the prepared terpolymer was characterized by FTIR and NMR. Also, the crystallization behavior of paraffin wax was investigated by differential scanning calorimetry (DSC). Experimental investigations furnish that the synthesized PPD showed high yield (87%) at the concentration (1:1:1) of BA-co-SMA-co-MA. From FTIR and 1HNMR characterization results observed that maleic anhydride moiety, alkyl chain moiety, and methacrylate moiety are existing in the prepared terpolymer. Furthermore, DSC analysis showed that the glass transition temperature of the prepared terpolymer is weakly stated over a wide temperature range.
format Article
author Elganidi, I.
Elarbe, B.S.
Norhayati, Abdullah
N., Ridzuan
author_facet Elganidi, I.
Elarbe, B.S.
Norhayati, Abdullah
N., Ridzuan
author_sort Elganidi, I.
title Characterization of a novel terpolymer containing maleic anhydride-co-stearyl methacrylate-cobenhely acrylate for wax inhibition application
title_short Characterization of a novel terpolymer containing maleic anhydride-co-stearyl methacrylate-cobenhely acrylate for wax inhibition application
title_full Characterization of a novel terpolymer containing maleic anhydride-co-stearyl methacrylate-cobenhely acrylate for wax inhibition application
title_fullStr Characterization of a novel terpolymer containing maleic anhydride-co-stearyl methacrylate-cobenhely acrylate for wax inhibition application
title_full_unstemmed Characterization of a novel terpolymer containing maleic anhydride-co-stearyl methacrylate-cobenhely acrylate for wax inhibition application
title_sort characterization of a novel terpolymer containing maleic anhydride-co-stearyl methacrylate-cobenhely acrylate for wax inhibition application
publisher IOP Publishing Ltd
publishDate 2019
url http://umpir.ump.edu.my/id/eprint/31918/1/IOP%20Conference%20Series%20Materials%20Science%20and%20Engineering.pdf
http://umpir.ump.edu.my/id/eprint/31918/
https://iopscience.iop.org/article/10.1088/1757-899X/702/1/012027
https://iopscience.iop.org/article/10.1088/1757-899X/702/1/012027
_version_ 1822922160272834560
score 13.251813

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