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Ionic transport studies of solid bio-polymer electrolytes based on carboxymethyl cellulose doped with ammonium acetate and its potential application as an electrical double layer capacitor.

CMC-NH4CH3CO2 complexes were characterized via theoretical and experimental approaches using molecular dynamics (MD) calculation, Fourier transform infrared spectrometry (FTIR), X-ray diffraction (XRD), and electrical impedance spectroscopy (EIS) analysis. These analyses successfully disclosed the s...

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Main Authors:	N. M.J, Rasali, M. A., Saadiah, N. K., Zainuddin, Nagao, Y., Ahmad Salihin, Samsudin
Format:	Article
Language:	English
Published:	BME-PT and GTE 2019
Subjects:	QC Physics
Online Access:	http://umpir.ump.edu.my/id/eprint/28700/7/Ionic%20transport%20studies%20of%20solid%20bio-polymer%20electrolytes%20based%20on%20carboxymethyl%20cellulose%20doped%20with%20ammonium%20acetate%20and%20its%20potential%20application%20as%20an%20electrical%20double%20layer%20capacitor.pdf http://umpir.ump.edu.my/id/eprint/28700/ https://doi.org/10.3144/expresspolymlett.2020.51 https://doi.org/10.3144/expresspolymlett.2020.51
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spelling	my.ump.umpir.287002020-10-27T08:05:21Z http://umpir.ump.edu.my/id/eprint/28700/ Ionic transport studies of solid bio-polymer electrolytes based on carboxymethyl cellulose doped with ammonium acetate and its potential application as an electrical double layer capacitor. N. M.J, Rasali M. A., Saadiah N. K., Zainuddin Nagao, Y. Ahmad Salihin, Samsudin QC Physics CMC-NH4CH3CO2 complexes were characterized via theoretical and experimental approaches using molecular dynamics (MD) calculation, Fourier transform infrared spectrometry (FTIR), X-ray diffraction (XRD), and electrical impedance spectroscopy (EIS) analysis. These analyses successfully disclosed the structural and ion conduction properties of the bio-polymer electrolytes (BPE) system. The FTIR analysis further revealed that an interaction exists between the carboxylate anion group (COO–) from CMC and the H+ substructure of NH4CH3CO2. The ionic conductivity value at ambient temperature was found to achieve an optimum value of 5.07×10–6 S/cm for a system containing 10 wt% NH4CH3CO2. The ionic conductivity improvement was demonstrated via the increment on the amorphous phase of the BPEs system as shown in the XRD analysis upon the inclusion of NH4CH3CO2. Based on the IR-deconvolution approach, the mobility (µ) and diffusion coefficient (D) were found to influence the ionic conductivity and aligned with the theoretical molecular dynamic (MD) calculation. To evaluate the potential application of the CMC-NH4CH3CO2, an electrical double-layer capacitor (EDLC) was fabricated from the BPE and tested using cyclic voltammetry (CV), and charge-discharge (GCD) for 300 cycles and the BPE exhibited a specific of capacitance ~2.4 F/g. BME-PT and GTE 2019-11-15 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/28700/7/Ionic%20transport%20studies%20of%20solid%20bio-polymer%20electrolytes%20based%20on%20carboxymethyl%20cellulose%20doped%20with%20ammonium%20acetate%20and%20its%20potential%20application%20as%20an%20electrical%20double%20layer%20capacitor.pdf N. M.J, Rasali and M. A., Saadiah and N. K., Zainuddin and Nagao, Y. and Ahmad Salihin, Samsudin (2019) Ionic transport studies of solid bio-polymer electrolytes based on carboxymethyl cellulose doped with ammonium acetate and its potential application as an electrical double layer capacitor. Express Polymer Letters, 14 (7). pp. 619-637. ISSN 1788618X https://doi.org/10.3144/expresspolymlett.2020.51 https://doi.org/10.3144/expresspolymlett.2020.51
institution	Universiti Malaysia Pahang
building	UMP Library
collection	Institutional Repository
continent	Asia
country	Malaysia
content_provider	Universiti Malaysia Pahang
content_source	UMP Institutional Repository
url_provider	http://umpir.ump.edu.my/
language	English
topic	QC Physics
spellingShingle	QC Physics N. M.J, Rasali M. A., Saadiah N. K., Zainuddin Nagao, Y. Ahmad Salihin, Samsudin Ionic transport studies of solid bio-polymer electrolytes based on carboxymethyl cellulose doped with ammonium acetate and its potential application as an electrical double layer capacitor.
description	CMC-NH4CH3CO2 complexes were characterized via theoretical and experimental approaches using molecular dynamics (MD) calculation, Fourier transform infrared spectrometry (FTIR), X-ray diffraction (XRD), and electrical impedance spectroscopy (EIS) analysis. These analyses successfully disclosed the structural and ion conduction properties of the bio-polymer electrolytes (BPE) system. The FTIR analysis further revealed that an interaction exists between the carboxylate anion group (COO–) from CMC and the H+ substructure of NH4CH3CO2. The ionic conductivity value at ambient temperature was found to achieve an optimum value of 5.07×10–6 S/cm for a system containing 10 wt% NH4CH3CO2. The ionic conductivity improvement was demonstrated via the increment on the amorphous phase of the BPEs system as shown in the XRD analysis upon the inclusion of NH4CH3CO2. Based on the IR-deconvolution approach, the mobility (µ) and diffusion coefficient (D) were found to influence the ionic conductivity and aligned with the theoretical molecular dynamic (MD) calculation. To evaluate the potential application of the CMC-NH4CH3CO2, an electrical double-layer capacitor (EDLC) was fabricated from the BPE and tested using cyclic voltammetry (CV), and charge-discharge (GCD) for 300 cycles and the BPE exhibited a specific of capacitance ~2.4 F/g.
format	Article
author	N. M.J, Rasali M. A., Saadiah N. K., Zainuddin Nagao, Y. Ahmad Salihin, Samsudin
author_facet	N. M.J, Rasali M. A., Saadiah N. K., Zainuddin Nagao, Y. Ahmad Salihin, Samsudin
author_sort	N. M.J, Rasali
title	Ionic transport studies of solid bio-polymer electrolytes based on carboxymethyl cellulose doped with ammonium acetate and its potential application as an electrical double layer capacitor.
title_short	Ionic transport studies of solid bio-polymer electrolytes based on carboxymethyl cellulose doped with ammonium acetate and its potential application as an electrical double layer capacitor.
title_full	Ionic transport studies of solid bio-polymer electrolytes based on carboxymethyl cellulose doped with ammonium acetate and its potential application as an electrical double layer capacitor.
title_fullStr	Ionic transport studies of solid bio-polymer electrolytes based on carboxymethyl cellulose doped with ammonium acetate and its potential application as an electrical double layer capacitor.
title_full_unstemmed	Ionic transport studies of solid bio-polymer electrolytes based on carboxymethyl cellulose doped with ammonium acetate and its potential application as an electrical double layer capacitor.
title_sort	ionic transport studies of solid bio-polymer electrolytes based on carboxymethyl cellulose doped with ammonium acetate and its potential application as an electrical double layer capacitor.
publisher	BME-PT and GTE
publishDate	2019
url	http://umpir.ump.edu.my/id/eprint/28700/7/Ionic%20transport%20studies%20of%20solid%20bio-polymer%20electrolytes%20based%20on%20carboxymethyl%20cellulose%20doped%20with%20ammonium%20acetate%20and%20its%20potential%20application%20as%20an%20electrical%20double%20layer%20capacitor.pdf http://umpir.ump.edu.my/id/eprint/28700/ https://doi.org/10.3144/expresspolymlett.2020.51 https://doi.org/10.3144/expresspolymlett.2020.51
_version_	1683230921674719232
score	13.211869

Ionic transport studies of solid bio-polymer electrolytes based on carboxymethyl cellulose doped with ammonium acetate and its potential application as an electrical double layer capacitor.

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