Comparison of two different UV-grafted nanofiltration membranes prepared for reduction of humic acid fouling using acrylic acid and N-vinylpyrrolidone

UV-photografting using two different monomers, acrylic acid and N-vinylpyrrolidone, with different concentrations in an aqueous solution and various irradiation times were studied. Irreversible fouling of both the un-grafted polyethersulfone and the UV-grafted membranes have been studied using humic...

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Bibliographic Details
Main Authors: Mazrul Nizam, Abu Seman, Khayet, M., Hilal, N.
Format: Article
Language:English
Published: Elsevier 2012
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/26999/1/Comparison%20of%20two%20different%20UV-grafted%20nanofiltration%20membranes.pdf
http://umpir.ump.edu.my/id/eprint/26999/
https://doi.org/10.1016/j.desal.2010.10.031
https://doi.org/10.1016/j.desal.2010.10.031
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Summary:UV-photografting using two different monomers, acrylic acid and N-vinylpyrrolidone, with different concentrations in an aqueous solution and various irradiation times were studied. Irreversible fouling of both the un-grafted polyethersulfone and the UV-grafted membranes have been studied using humic acid model solutions at two different pH values; 7 and 3. It was observed that the UV-grafted membranes exhibited practically less tendency to be irreversibly fouled by humic acid molecules at pH 7. However at the acidic condition of pH 3, some membranes exhibited a higher degree of fouling more than the un-grafted membrane, especially for membranes with higher roughness values. The smaller pore size generated after UV-grafting of polyethersulfone membrane did not significantly affect humic acid removal due to the larger humic acid molecular size.