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Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses

We have synthesized aniline based amides (3a–h) via palladium catalyzed Suzuki cross coupling of N-(2,5-dibromophenyl) acetamide with different arylboronic acids in moderate to good yields. A variety of functional groups were well tolerated in reaction conditions. For exploring the possible applicat...

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Main Authors: Israr, Hira, Rasool, Nasir, Rizwan, Komal, Hashmi, Muhammad Ali, Mahmood, Tariq, Rashid, Umer, Mohd Zobir, Hussein, Akhtar, Muhammad Nadeem
Format: Article
Language:English
Published: MDPI AG 2019
Subjects:
QD Chemistry
TP Chemical technology
Online Access:http://umpir.ump.edu.my/id/eprint/25577/1/Synthesis%20and%20reactivities%20of%20triphenyl%20acetamide%20analogs%20for%20potential%20.pdf
http://umpir.ump.edu.my/id/eprint/25577/
https://doi.org/10.3390/sym11050622
https://doi.org/10.3390/sym11050622
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spelling my.ump.umpir.255772019-11-20T07:49:17Z http://umpir.ump.edu.my/id/eprint/25577/ Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses Israr, Hira Rasool, Nasir Rizwan, Komal Hashmi, Muhammad Ali Mahmood, Tariq Rashid, Umer Mohd Zobir, Hussein Akhtar, Muhammad Nadeem QD Chemistry TP Chemical technology We have synthesized aniline based amides (3a–h) via palladium catalyzed Suzuki cross coupling of N-(2,5-dibromophenyl) acetamide with different arylboronic acids in moderate to good yields. A variety of functional groups were well tolerated in reaction conditions. For exploring the possible applications as optoelectronic devices, the nonlinear optical (NLO) properties of all synthesized derivatives (3a–h) were investigated with the help of density functional theory (DFT) methods. The frontier molecular orbitals analysis and reactivity descriptors were investigated for exploring the reactivities. MDPI AG 2019-05-01 Article PeerReviewed pdf en cc_by_4 http://umpir.ump.edu.my/id/eprint/25577/1/Synthesis%20and%20reactivities%20of%20triphenyl%20acetamide%20analogs%20for%20potential%20.pdf Israr, Hira and Rasool, Nasir and Rizwan, Komal and Hashmi, Muhammad Ali and Mahmood, Tariq and Rashid, Umer and Mohd Zobir, Hussein and Akhtar, Muhammad Nadeem (2019) Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses. Symmetry, 11 (5). pp. 1-11. ISSN 2073-8994 https://doi.org/10.3390/sym11050622 https://doi.org/10.3390/sym11050622
institution Universiti Malaysia Pahang
building UMP Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Pahang
content_source UMP Institutional Repository
url_provider http://umpir.ump.edu.my/
language English
topic QD Chemistry
TP Chemical technology
spellingShingle QD Chemistry
TP Chemical technology
Israr, Hira
Rasool, Nasir
Rizwan, Komal
Hashmi, Muhammad Ali
Mahmood, Tariq
Rashid, Umer
Mohd Zobir, Hussein
Akhtar, Muhammad Nadeem
Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses
description We have synthesized aniline based amides (3a–h) via palladium catalyzed Suzuki cross coupling of N-(2,5-dibromophenyl) acetamide with different arylboronic acids in moderate to good yields. A variety of functional groups were well tolerated in reaction conditions. For exploring the possible applications as optoelectronic devices, the nonlinear optical (NLO) properties of all synthesized derivatives (3a–h) were investigated with the help of density functional theory (DFT) methods. The frontier molecular orbitals analysis and reactivity descriptors were investigated for exploring the reactivities.
format Article
author Israr, Hira
Rasool, Nasir
Rizwan, Komal
Hashmi, Muhammad Ali
Mahmood, Tariq
Rashid, Umer
Mohd Zobir, Hussein
Akhtar, Muhammad Nadeem
author_facet Israr, Hira
Rasool, Nasir
Rizwan, Komal
Hashmi, Muhammad Ali
Mahmood, Tariq
Rashid, Umer
Mohd Zobir, Hussein
Akhtar, Muhammad Nadeem
author_sort Israr, Hira
title Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses
title_short Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses
title_full Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses
title_fullStr Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses
title_full_unstemmed Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses
title_sort synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses
publisher MDPI AG
publishDate 2019
url http://umpir.ump.edu.my/id/eprint/25577/1/Synthesis%20and%20reactivities%20of%20triphenyl%20acetamide%20analogs%20for%20potential%20.pdf
http://umpir.ump.edu.my/id/eprint/25577/
https://doi.org/10.3390/sym11050622
https://doi.org/10.3390/sym11050622
_version_ 1651866931894943744
score 13.211869

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