Cover Image

One-pot furfural production using choline chloride-dicarboxylic acid based deep eutectic solvents under mild conditions

The performances of various anhydrous and aqueous choline chloride-dicarboxylic acid based deep eutectic solvents (DESs) were evaluated for furfural production from oil palm fronds without any additional catalyst. The effects of different carbon chain length dicarboxylic acids and water content in e...

Full description

Saved in:
Bibliographic Details
Main Authors: Loong Lee, Cornelius Basil Tien, Wu, Ta Yeong, Ting, Chow Hung, Tan, Ju Kheng, Siow, Lee Fong, Cheng, C. K., Jamaliah, Md. Jahim, Abdul Wahab, Mohammad
Format: Article
Language:English
Published: Elsevier 2019
Subjects:
TP Chemical technology
Online Access:http://umpir.ump.edu.my/id/eprint/24392/1/One-pot%20furfural%20production%20using%20choline%20chloride-dicarboxylic%20acid%20based%20deep%20eutectic%20solvents%20under%20mild%20conditions.pdf
http://umpir.ump.edu.my/id/eprint/24392/
https://doi.org/10.1016/j.biortech.2018.12.034
https://doi.org/10.1016/j.biortech.2018.12.034
Tags: Add Tag
No Tags, Be the first to tag this record!
id my.ump.umpir.24392
record_format eprints
spelling my.ump.umpir.243922019-03-19T08:43:48Z http://umpir.ump.edu.my/id/eprint/24392/ One-pot furfural production using choline chloride-dicarboxylic acid based deep eutectic solvents under mild conditions Loong Lee, Cornelius Basil Tien Wu, Ta Yeong Ting, Chow Hung Tan, Ju Kheng Siow, Lee Fong Cheng, C. K. Jamaliah, Md. Jahim Abdul Wahab, Mohammad TP Chemical technology The performances of various anhydrous and aqueous choline chloride-dicarboxylic acid based deep eutectic solvents (DESs) were evaluated for furfural production from oil palm fronds without any additional catalyst. The effects of different carbon chain length dicarboxylic acids and water content in each DES on furfural production were investigated. Oil palm fronds, DES and water (0–5 ml) were mixed and reacted in an oil bath (60–300 min). Reacted oil palm fronds had the potential to be reused as cellulose-rich-valuable by-products. At 100 °C, aqueous choline chloride-oxalic acid (16.4 wt% H2O) produced the highest furfural yield of 26.34% and cellulosecomposition up to 72.79% in the reacted oil palm fronds. Despite operating at suitable reaction duration for dicarboxylic acid with longer carbon chain length, aqueous choline chloride-malonic acid and aqueous choline chloride-succinic acid performed poorly with furfural yield of less than 1%. Elsevier 2019 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/24392/1/One-pot%20furfural%20production%20using%20choline%20chloride-dicarboxylic%20acid%20based%20deep%20eutectic%20solvents%20under%20mild%20conditions.pdf Loong Lee, Cornelius Basil Tien and Wu, Ta Yeong and Ting, Chow Hung and Tan, Ju Kheng and Siow, Lee Fong and Cheng, C. K. and Jamaliah, Md. Jahim and Abdul Wahab, Mohammad (2019) One-pot furfural production using choline chloride-dicarboxylic acid based deep eutectic solvents under mild conditions. Bioresource Technology, 278. pp. 486-489. ISSN 0960-8524 https://doi.org/10.1016/j.biortech.2018.12.034 https://doi.org/10.1016/j.biortech.2018.12.034
institution Universiti Malaysia Pahang
building UMP Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Pahang
content_source UMP Institutional Repository
url_provider http://umpir.ump.edu.my/
language English
topic TP Chemical technology
spellingShingle TP Chemical technology
Loong Lee, Cornelius Basil Tien
Wu, Ta Yeong
Ting, Chow Hung
Tan, Ju Kheng
Siow, Lee Fong
Cheng, C. K.
Jamaliah, Md. Jahim
Abdul Wahab, Mohammad
One-pot furfural production using choline chloride-dicarboxylic acid based deep eutectic solvents under mild conditions
description The performances of various anhydrous and aqueous choline chloride-dicarboxylic acid based deep eutectic solvents (DESs) were evaluated for furfural production from oil palm fronds without any additional catalyst. The effects of different carbon chain length dicarboxylic acids and water content in each DES on furfural production were investigated. Oil palm fronds, DES and water (0–5 ml) were mixed and reacted in an oil bath (60–300 min). Reacted oil palm fronds had the potential to be reused as cellulose-rich-valuable by-products. At 100 °C, aqueous choline chloride-oxalic acid (16.4 wt% H2O) produced the highest furfural yield of 26.34% and cellulosecomposition up to 72.79% in the reacted oil palm fronds. Despite operating at suitable reaction duration for dicarboxylic acid with longer carbon chain length, aqueous choline chloride-malonic acid and aqueous choline chloride-succinic acid performed poorly with furfural yield of less than 1%.
format Article
author Loong Lee, Cornelius Basil Tien
Wu, Ta Yeong
Ting, Chow Hung
Tan, Ju Kheng
Siow, Lee Fong
Cheng, C. K.
Jamaliah, Md. Jahim
Abdul Wahab, Mohammad
author_facet Loong Lee, Cornelius Basil Tien
Wu, Ta Yeong
Ting, Chow Hung
Tan, Ju Kheng
Siow, Lee Fong
Cheng, C. K.
Jamaliah, Md. Jahim
Abdul Wahab, Mohammad
author_sort Loong Lee, Cornelius Basil Tien
title One-pot furfural production using choline chloride-dicarboxylic acid based deep eutectic solvents under mild conditions
title_short One-pot furfural production using choline chloride-dicarboxylic acid based deep eutectic solvents under mild conditions
title_full One-pot furfural production using choline chloride-dicarboxylic acid based deep eutectic solvents under mild conditions
title_fullStr One-pot furfural production using choline chloride-dicarboxylic acid based deep eutectic solvents under mild conditions
title_full_unstemmed One-pot furfural production using choline chloride-dicarboxylic acid based deep eutectic solvents under mild conditions
title_sort one-pot furfural production using choline chloride-dicarboxylic acid based deep eutectic solvents under mild conditions
publisher Elsevier
publishDate 2019
url http://umpir.ump.edu.my/id/eprint/24392/1/One-pot%20furfural%20production%20using%20choline%20chloride-dicarboxylic%20acid%20based%20deep%20eutectic%20solvents%20under%20mild%20conditions.pdf
http://umpir.ump.edu.my/id/eprint/24392/
https://doi.org/10.1016/j.biortech.2018.12.034
https://doi.org/10.1016/j.biortech.2018.12.034
_version_ 1643669825717796864
score 13.211869

Similar Items