Cover Image

Investigation on the effect of NH4Br at transport properties in k–carrageenan based biopolymer electrolytes via structural and electrical analysis

The present work deals with the investigation on ionic conductivity and transports properties of biopolymer electrolytes (BEs) based on kappa-carrageenan (KC) by incorporating NH4Br as polymer-salt system. The BEs was successfully prepared via solution-casting method and characterized by means of Fo...

Full description

Saved in:
Bibliographic Details
Main Authors: Nur Khalidah, Zainuddin, Ahmad Salihin, Samsudin
Format: Article
Language:English
English
Published: Elsevier 2018
Subjects:
Q Science (General)
QC Physics
QD Chemistry
Online Access:http://umpir.ump.edu.my/id/eprint/23984/7/Investigation%20on%20the%20effect%20of%20NH4Br%20at%20transport%20properties%20in%20k%E2%80%93carrageenan%20based%20biopolymer%20electrolytes%20via%20structural%20and%20electrical%20analysis.pdf
http://umpir.ump.edu.my/id/eprint/23984/13/Investigation%20on%20the%20effect%20of%20NH4Br%20at%20transport%20properties%20in%20k%E2%80%93carrageenan%20based%20biopolymer%20electrolytes%20via%20structural%20and%20electrical%20analysis_ABS.pdf
http://umpir.ump.edu.my/id/eprint/23984/
https://doi.org/10.1016/j.mtcomm.2018.01.004
https://doi.org/10.1016/j.mtcomm.2018.01.004
Tags: Add Tag
No Tags, Be the first to tag this record!
id my.ump.umpir.23984
record_format eprints
spelling my.ump.umpir.239842023-12-04T03:11:31Z http://umpir.ump.edu.my/id/eprint/23984/ Investigation on the effect of NH4Br at transport properties in k–carrageenan based biopolymer electrolytes via structural and electrical analysis Nur Khalidah, Zainuddin Ahmad Salihin, Samsudin Q Science (General) QC Physics QD Chemistry The present work deals with the investigation on ionic conductivity and transports properties of biopolymer electrolytes (BEs) based on kappa-carrageenan (KC) by incorporating NH4Br as polymer-salt system. The BEs was successfully prepared via solution-casting method and characterized by means of Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD) and electrochemical impedance spectroscopy (EIS). It was established that the ionic conductivity for BEs system increased and achieved an optimum value of 3.89 × 10−4 S/cm for a sample containing 20 wt.% NH4Br at ambient temperature (303 K). XRD analysis indicates that the highest ion conductivity complex exhibits optimum amorphous nature via the evaluation of the degree of crystallinity (Xc %). The conducting element in the BEs does favor the association of ion count from NH4Br where the ionic mobility and diffusion coefficient of the transport properties were found increase parallel with the conductivity until it reaches optimum composition of BEs. Elsevier 2018-03 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/23984/7/Investigation%20on%20the%20effect%20of%20NH4Br%20at%20transport%20properties%20in%20k%E2%80%93carrageenan%20based%20biopolymer%20electrolytes%20via%20structural%20and%20electrical%20analysis.pdf pdf en http://umpir.ump.edu.my/id/eprint/23984/13/Investigation%20on%20the%20effect%20of%20NH4Br%20at%20transport%20properties%20in%20k%E2%80%93carrageenan%20based%20biopolymer%20electrolytes%20via%20structural%20and%20electrical%20analysis_ABS.pdf Nur Khalidah, Zainuddin and Ahmad Salihin, Samsudin (2018) Investigation on the effect of NH4Br at transport properties in k–carrageenan based biopolymer electrolytes via structural and electrical analysis. Materials Today Communications, 14. pp. 199-209. ISSN 2352-4928. (Published) https://doi.org/10.1016/j.mtcomm.2018.01.004 https://doi.org/10.1016/j.mtcomm.2018.01.004
institution Universiti Malaysia Pahang Al-Sultan Abdullah
building UMPSA Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Pahang Al-Sultan Abdullah
content_source UMPSA Institutional Repository
url_provider http://umpir.ump.edu.my/
language English
English
topic Q Science (General)
QC Physics
QD Chemistry
spellingShingle Q Science (General)
QC Physics
QD Chemistry
Nur Khalidah, Zainuddin
Ahmad Salihin, Samsudin
Investigation on the effect of NH4Br at transport properties in k–carrageenan based biopolymer electrolytes via structural and electrical analysis
description The present work deals with the investigation on ionic conductivity and transports properties of biopolymer electrolytes (BEs) based on kappa-carrageenan (KC) by incorporating NH4Br as polymer-salt system. The BEs was successfully prepared via solution-casting method and characterized by means of Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD) and electrochemical impedance spectroscopy (EIS). It was established that the ionic conductivity for BEs system increased and achieved an optimum value of 3.89 × 10−4 S/cm for a sample containing 20 wt.% NH4Br at ambient temperature (303 K). XRD analysis indicates that the highest ion conductivity complex exhibits optimum amorphous nature via the evaluation of the degree of crystallinity (Xc %). The conducting element in the BEs does favor the association of ion count from NH4Br where the ionic mobility and diffusion coefficient of the transport properties were found increase parallel with the conductivity until it reaches optimum composition of BEs.
format Article
author Nur Khalidah, Zainuddin
Ahmad Salihin, Samsudin
author_facet Nur Khalidah, Zainuddin
Ahmad Salihin, Samsudin
author_sort Nur Khalidah, Zainuddin
title Investigation on the effect of NH4Br at transport properties in k–carrageenan based biopolymer electrolytes via structural and electrical analysis
title_short Investigation on the effect of NH4Br at transport properties in k–carrageenan based biopolymer electrolytes via structural and electrical analysis
title_full Investigation on the effect of NH4Br at transport properties in k–carrageenan based biopolymer electrolytes via structural and electrical analysis
title_fullStr Investigation on the effect of NH4Br at transport properties in k–carrageenan based biopolymer electrolytes via structural and electrical analysis
title_full_unstemmed Investigation on the effect of NH4Br at transport properties in k–carrageenan based biopolymer electrolytes via structural and electrical analysis
title_sort investigation on the effect of nh4br at transport properties in k–carrageenan based biopolymer electrolytes via structural and electrical analysis
publisher Elsevier
publishDate 2018
url http://umpir.ump.edu.my/id/eprint/23984/7/Investigation%20on%20the%20effect%20of%20NH4Br%20at%20transport%20properties%20in%20k%E2%80%93carrageenan%20based%20biopolymer%20electrolytes%20via%20structural%20and%20electrical%20analysis.pdf
http://umpir.ump.edu.my/id/eprint/23984/13/Investigation%20on%20the%20effect%20of%20NH4Br%20at%20transport%20properties%20in%20k%E2%80%93carrageenan%20based%20biopolymer%20electrolytes%20via%20structural%20and%20electrical%20analysis_ABS.pdf
http://umpir.ump.edu.my/id/eprint/23984/
https://doi.org/10.1016/j.mtcomm.2018.01.004
https://doi.org/10.1016/j.mtcomm.2018.01.004
_version_ 1822923882591420416
score 13.244109

Similar Items