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Surface functionalization of graphene oxide with octadecylamine for improved thermal and mechanical properties in polybutylene succinate nanocomposite

Modification of graphene oxide (GO) with long-chain aliphatic amine offers a substantial improvement in high-performance polymer as nanofiller in the composite. In this work, graphene oxide was functionalized with octadecylamine via sonochemical exfoliation method producing mono- to few-layer graphe...

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Main Authors: Anis Sakinah, Zainal Abidin, Kamal, Yusoh, Saidatul Shima, Jamari, Abu Hannifa, Abdullah, Zulhelmi, Ismail
Format: Article
Language:English
English
Published: Springer Berlin Heidelberg 2018
Subjects:
TP Chemical technology
Online Access:http://umpir.ump.edu.my/id/eprint/19847/1/Surface%20functionalization%20of%20graphene%20oxide1.pdf
http://umpir.ump.edu.my/id/eprint/19847/2/Surface%20functionalization%20of%20graphene%20oxide.pdf
http://umpir.ump.edu.my/id/eprint/19847/
https://doi.org/10.1007/s00289-017-2217-6
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spelling my.ump.umpir.198472018-08-08T07:13:34Z http://umpir.ump.edu.my/id/eprint/19847/ Surface functionalization of graphene oxide with octadecylamine for improved thermal and mechanical properties in polybutylene succinate nanocomposite Anis Sakinah, Zainal Abidin Kamal, Yusoh Saidatul Shima, Jamari Abu Hannifa, Abdullah Zulhelmi, Ismail TP Chemical technology Modification of graphene oxide (GO) with long-chain aliphatic amine offers a substantial improvement in high-performance polymer as nanofiller in the composite. In this work, graphene oxide was functionalized with octadecylamine via sonochemical exfoliation method producing mono- to few-layer graphene oxide/octadecylamine (GOODA) nanofiller. Biodegradable polybutylene succinate (PBS) was incorporated with GOODA via solution intercalation method. GOODA does not profoundly affect the crystallinity of PBS/GOODA nanocomposite, but interestingly improves the mechanical and thermal properties. The addition of only 0.1 wt% GOODA nanofiller loading exhibited a sharp increase in tensile strength and Young’s modulus of up to 50 and 58.9%, respectively. The improvement in strength and thermal behavior could be attributed to the successful interfacial interaction between amine group in GOODA and carboxylic group in PBS chain tail via nucleophilic substitution reaction. This improved interphase structure enhanced the dispersion and exfoliation of GOODA in PBS matrix. Springer Berlin Heidelberg 2018 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/19847/1/Surface%20functionalization%20of%20graphene%20oxide1.pdf pdf en http://umpir.ump.edu.my/id/eprint/19847/2/Surface%20functionalization%20of%20graphene%20oxide.pdf Anis Sakinah, Zainal Abidin and Kamal, Yusoh and Saidatul Shima, Jamari and Abu Hannifa, Abdullah and Zulhelmi, Ismail (2018) Surface functionalization of graphene oxide with octadecylamine for improved thermal and mechanical properties in polybutylene succinate nanocomposite. Polymer Bulletin, 75 (8). pp. 3499-3522. ISSN 0170-0839(Print); 1436-2449(Online) https://doi.org/10.1007/s00289-017-2217-6 doi: 10.1007/s00289-017-2217-6
institution Universiti Malaysia Pahang
building UMP Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Pahang
content_source UMP Institutional Repository
url_provider http://umpir.ump.edu.my/
language English
English
topic TP Chemical technology
spellingShingle TP Chemical technology
Anis Sakinah, Zainal Abidin
Kamal, Yusoh
Saidatul Shima, Jamari
Abu Hannifa, Abdullah
Zulhelmi, Ismail
Surface functionalization of graphene oxide with octadecylamine for improved thermal and mechanical properties in polybutylene succinate nanocomposite
description Modification of graphene oxide (GO) with long-chain aliphatic amine offers a substantial improvement in high-performance polymer as nanofiller in the composite. In this work, graphene oxide was functionalized with octadecylamine via sonochemical exfoliation method producing mono- to few-layer graphene oxide/octadecylamine (GOODA) nanofiller. Biodegradable polybutylene succinate (PBS) was incorporated with GOODA via solution intercalation method. GOODA does not profoundly affect the crystallinity of PBS/GOODA nanocomposite, but interestingly improves the mechanical and thermal properties. The addition of only 0.1 wt% GOODA nanofiller loading exhibited a sharp increase in tensile strength and Young’s modulus of up to 50 and 58.9%, respectively. The improvement in strength and thermal behavior could be attributed to the successful interfacial interaction between amine group in GOODA and carboxylic group in PBS chain tail via nucleophilic substitution reaction. This improved interphase structure enhanced the dispersion and exfoliation of GOODA in PBS matrix.
format Article
author Anis Sakinah, Zainal Abidin
Kamal, Yusoh
Saidatul Shima, Jamari
Abu Hannifa, Abdullah
Zulhelmi, Ismail
author_facet Anis Sakinah, Zainal Abidin
Kamal, Yusoh
Saidatul Shima, Jamari
Abu Hannifa, Abdullah
Zulhelmi, Ismail
author_sort Anis Sakinah, Zainal Abidin
title Surface functionalization of graphene oxide with octadecylamine for improved thermal and mechanical properties in polybutylene succinate nanocomposite
title_short Surface functionalization of graphene oxide with octadecylamine for improved thermal and mechanical properties in polybutylene succinate nanocomposite
title_full Surface functionalization of graphene oxide with octadecylamine for improved thermal and mechanical properties in polybutylene succinate nanocomposite
title_fullStr Surface functionalization of graphene oxide with octadecylamine for improved thermal and mechanical properties in polybutylene succinate nanocomposite
title_full_unstemmed Surface functionalization of graphene oxide with octadecylamine for improved thermal and mechanical properties in polybutylene succinate nanocomposite
title_sort surface functionalization of graphene oxide with octadecylamine for improved thermal and mechanical properties in polybutylene succinate nanocomposite
publisher Springer Berlin Heidelberg
publishDate 2018
url http://umpir.ump.edu.my/id/eprint/19847/1/Surface%20functionalization%20of%20graphene%20oxide1.pdf
http://umpir.ump.edu.my/id/eprint/19847/2/Surface%20functionalization%20of%20graphene%20oxide.pdf
http://umpir.ump.edu.my/id/eprint/19847/
https://doi.org/10.1007/s00289-017-2217-6
_version_ 1643668744000503808
score 13.211869

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