Tailoring the Properties and Catalytic Activities of Ni/SBA-15 via Different TEOS/P123 Mass Ratios for CO2 Reforming of CH4
The influences of tetraethylorthosilicate/ triblockcopolymer (TEOS/P123) mass ratios on the properties and catalytic activity of Ni/SBA-15 towards CO2 reforming of CH4 were studied. A series of samples with different mass ratios of TEOS/P123 (1.5, 2.21 and 3.0) were prepared and characterized by XRD...
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | English English |
| Published: |
Elsevier Ltd
2017
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| Subjects: | |
| Online Access: | http://umpir.ump.edu.my/id/eprint/18073/1/Tailoring%20the%20properties%20and%20catalytic%20activities%20of%20Ni-SBA-15%20via%20different%20TEOS-P123%20mass%20ratios%20for%20CO2%20reforming%20of%20CH4.pdf http://umpir.ump.edu.my/id/eprint/18073/7/Tailoring%20the%20properties%20and%20catalytic%20activities%20of%20Ni-SBA-15%20via%20different%20TEOS-P123%20mass%20ratios%20for%20CO2%20reforming%20of%20CH4%201.pdf http://umpir.ump.edu.my/id/eprint/18073/ https://doi.org/10.1016/j.jece.2017.06.012 |
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| Summary: | The influences of tetraethylorthosilicate/ triblockcopolymer (TEOS/P123) mass ratios on the properties and catalytic activity of Ni/SBA-15 towards CO2 reforming of CH4 were studied. A series of samples with different mass ratios of TEOS/P123 (1.5, 2.21 and 3.0) were prepared and characterized by XRD, BET, SEM, TEM, FTIR and UV–vis DRS. The characterization results clearly indicated that TEOS/P123 mass ratio of 2.21 was the optimal synthesis ratio of Ni/SBA-15 which produces the well-ordered hexagonal mesoporous structure with the highest Ni-support interaction. The catalytically favorable textural properties of Ni/SBA-15(R2.21) enhanced the dispersion of metal particles, improved the catalyst activity, increased the catalyst stability and reduced the carbon deposition. The conversion of CH4 and CO2 over Ni/SBA-15(R2.21) were about 89% and 88%, respectively and H2/CO ratio of 1.02. This study provides new perspectives on the Ni-based catalyst, particularly on the influence of TEOS/P123 mass ratio on the properties and catalytic activity of Ni/SBA-15 towards CO2 reforming of CH4. |
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