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CO2 Reforming of CH4 over Ni/SBA-15: Influence of Ni Loading on the Metalsupport Interaction and Catalytic Activity

The influence of Ni loading on the properties of Ni/SBA-15 and CO2 reforming of CH4 were studied. XRD, BET and TGA results indicated that the increasing Ni loading (3–10 wt%) decreased the crystallinity, surface area and physically adsorbed water content of the catalysts. FTIR, TEM and H2-TPR analys...

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Main Authors: Setiabudi, H. D., Lim, K.H., N., Ainirazali, Chin, S. Y., N. H. N., Kamarudin
Format: Article
Language:English
English
Published: University of Mohammed Premier Oujda 2017
Subjects:
TP Chemical technology
Online Access:http://umpir.ump.edu.my/id/eprint/18044/1/CO2%20reforming%20of%20CH4%20over%20Ni-SBA-15-%20Influence%20of%20Ni%20loading%20on%20the%20metalsupport%20interaction%20and%20catalytic%20activity.pdf
http://umpir.ump.edu.my/id/eprint/18044/7/CO2%20reforming%20of%20CH4%20over%20Ni-SBA-15-%20Influence%20of%20Ni%20loading%20on%20the%20metalsupport%20interaction%20and%20catalytic%20activity%201.pdf
http://umpir.ump.edu.my/id/eprint/18044/
https://www.jmaterenvironsci.com/Document/vol8/vol8_N2/62-JMES-2692-Setiabudi.pdf
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spelling my.ump.umpir.180442017-12-14T02:42:38Z http://umpir.ump.edu.my/id/eprint/18044/ CO2 Reforming of CH4 over Ni/SBA-15: Influence of Ni Loading on the Metalsupport Interaction and Catalytic Activity Setiabudi, H. D. Lim, K.H. N., Ainirazali Chin, S. Y. N. H. N., Kamarudin TP Chemical technology The influence of Ni loading on the properties of Ni/SBA-15 and CO2 reforming of CH4 were studied. XRD, BET and TGA results indicated that the increasing Ni loading (3–10 wt%) decreased the crystallinity, surface area and physically adsorbed water content of the catalysts. FTIR, TEM and H2-TPR analysis confirmed the formation of Ni–O–Si by the substitution of surface silanol groups with Ni species and the maximum substitution of surface silanol groups with Ni were achieved at 5 wt%, while further increased in Ni loading stimulate the agglomeration of Ni particles. The activity of catalysts followed the order of 5Ni/SBA-15 > 3Ni/SBA-15 ≈ 10Ni/SBA-15 > SBA-15, with the conversion of CH4 and CO2 over 5Ni/SBA-15 was about 89% and 88% respectively, and CO2/CH4 ratio of 1.02. The superior catalytic performance of 5Ni/SBA-15 towards CO2 reforming of CH4 probably was related with the formation of metal-support interaction, Ni–O–Si, which enhanced the stabilization of the active Ni species on SBA-15 support and altered the properties of catalyst towards an excellent catalytic performance. The analysis of spent catalysts found that the presence of Ni–O–Si minimizes the growth of encapsulating graphite carbon and thus enhanced the stability of catalyst. This study provides new perspectives on the Ni-based catalyst, particularly on the influence of Ni on the metal-support interaction and catalytic performance of Ni/SBA-15 towards CO2 reforming of CH4. University of Mohammed Premier Oujda 2017 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/18044/1/CO2%20reforming%20of%20CH4%20over%20Ni-SBA-15-%20Influence%20of%20Ni%20loading%20on%20the%20metalsupport%20interaction%20and%20catalytic%20activity.pdf application/pdf en http://umpir.ump.edu.my/id/eprint/18044/7/CO2%20reforming%20of%20CH4%20over%20Ni-SBA-15-%20Influence%20of%20Ni%20loading%20on%20the%20metalsupport%20interaction%20and%20catalytic%20activity%201.pdf Setiabudi, H. D. and Lim, K.H. and N., Ainirazali and Chin, S. Y. and N. H. N., Kamarudin (2017) CO2 Reforming of CH4 over Ni/SBA-15: Influence of Ni Loading on the Metalsupport Interaction and Catalytic Activity. Journal of Materials and Environmental Sciences , 8 (2). pp. 573-581. ISSN 2028-2508 https://www.jmaterenvironsci.com/Document/vol8/vol8_N2/62-JMES-2692-Setiabudi.pdf
institution Universiti Malaysia Pahang
building UMP Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Pahang
content_source UMP Institutional Repository
url_provider http://umpir.ump.edu.my/
language English
English
topic TP Chemical technology
spellingShingle TP Chemical technology
Setiabudi, H. D.
Lim, K.H.
N., Ainirazali
Chin, S. Y.
N. H. N., Kamarudin
CO2 Reforming of CH4 over Ni/SBA-15: Influence of Ni Loading on the Metalsupport Interaction and Catalytic Activity
description The influence of Ni loading on the properties of Ni/SBA-15 and CO2 reforming of CH4 were studied. XRD, BET and TGA results indicated that the increasing Ni loading (3–10 wt%) decreased the crystallinity, surface area and physically adsorbed water content of the catalysts. FTIR, TEM and H2-TPR analysis confirmed the formation of Ni–O–Si by the substitution of surface silanol groups with Ni species and the maximum substitution of surface silanol groups with Ni were achieved at 5 wt%, while further increased in Ni loading stimulate the agglomeration of Ni particles. The activity of catalysts followed the order of 5Ni/SBA-15 > 3Ni/SBA-15 ≈ 10Ni/SBA-15 > SBA-15, with the conversion of CH4 and CO2 over 5Ni/SBA-15 was about 89% and 88% respectively, and CO2/CH4 ratio of 1.02. The superior catalytic performance of 5Ni/SBA-15 towards CO2 reforming of CH4 probably was related with the formation of metal-support interaction, Ni–O–Si, which enhanced the stabilization of the active Ni species on SBA-15 support and altered the properties of catalyst towards an excellent catalytic performance. The analysis of spent catalysts found that the presence of Ni–O–Si minimizes the growth of encapsulating graphite carbon and thus enhanced the stability of catalyst. This study provides new perspectives on the Ni-based catalyst, particularly on the influence of Ni on the metal-support interaction and catalytic performance of Ni/SBA-15 towards CO2 reforming of CH4.
format Article
author Setiabudi, H. D.
Lim, K.H.
N., Ainirazali
Chin, S. Y.
N. H. N., Kamarudin
author_facet Setiabudi, H. D.
Lim, K.H.
N., Ainirazali
Chin, S. Y.
N. H. N., Kamarudin
author_sort Setiabudi, H. D.
title CO2 Reforming of CH4 over Ni/SBA-15: Influence of Ni Loading on the Metalsupport Interaction and Catalytic Activity
title_short CO2 Reforming of CH4 over Ni/SBA-15: Influence of Ni Loading on the Metalsupport Interaction and Catalytic Activity
title_full CO2 Reforming of CH4 over Ni/SBA-15: Influence of Ni Loading on the Metalsupport Interaction and Catalytic Activity
title_fullStr CO2 Reforming of CH4 over Ni/SBA-15: Influence of Ni Loading on the Metalsupport Interaction and Catalytic Activity
title_full_unstemmed CO2 Reforming of CH4 over Ni/SBA-15: Influence of Ni Loading on the Metalsupport Interaction and Catalytic Activity
title_sort co2 reforming of ch4 over ni/sba-15: influence of ni loading on the metalsupport interaction and catalytic activity
publisher University of Mohammed Premier Oujda
publishDate 2017
url http://umpir.ump.edu.my/id/eprint/18044/1/CO2%20reforming%20of%20CH4%20over%20Ni-SBA-15-%20Influence%20of%20Ni%20loading%20on%20the%20metalsupport%20interaction%20and%20catalytic%20activity.pdf
http://umpir.ump.edu.my/id/eprint/18044/7/CO2%20reforming%20of%20CH4%20over%20Ni-SBA-15-%20Influence%20of%20Ni%20loading%20on%20the%20metalsupport%20interaction%20and%20catalytic%20activity%201.pdf
http://umpir.ump.edu.my/id/eprint/18044/
https://www.jmaterenvironsci.com/Document/vol8/vol8_N2/62-JMES-2692-Setiabudi.pdf
_version_ 1643668341160673280
score 13.211869

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