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Cellulose Supported Poly(amidoxime) Copper Complex for Click Reaction

A highly active poly(amidoxime) copper complex was prepared by the surface modification of kenaf cellulose through graft copolymerization and subsequent amidoximation. The prepared copper complex was characterized by IR, FESEM, TEM, XPS, EDX and ICP-AES analyses. The copper complex was applied to th...

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Main Authors: Sarkar, Shaheen M., Lutfor, M. R.
Format: Article
Language:English
Published: Elsevier Ltd 2017
Subjects:
Q Science (General)
Online Access:http://umpir.ump.edu.my/id/eprint/16586/1/Cellulose%20supported%20poly%28amidoxime%29%20copper%20complex%20for%20Click%20reaction.pdf
http://umpir.ump.edu.my/id/eprint/16586/
http://doi.org/10.1016/j.jclepro.2016.09.153
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spelling my.ump.umpir.165862018-03-20T06:14:11Z http://umpir.ump.edu.my/id/eprint/16586/ Cellulose Supported Poly(amidoxime) Copper Complex for Click Reaction Sarkar, Shaheen M. Lutfor, M. R. Q Science (General) A highly active poly(amidoxime) copper complex was prepared by the surface modification of kenaf cellulose through graft copolymerization and subsequent amidoximation. The prepared copper complex was characterized by IR, FESEM, TEM, XPS, EDX and ICP-AES analyses. The copper complex was applied to the Click reaction of organic azides and alkynes as well as one-pot three-component reactions in presence of sodium ascorbate to give the corresponding cycloaddition products in up to 96% yield. The complex was easy to recover and reused six times without significance loss of its activity. Elsevier Ltd 2017 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/16586/1/Cellulose%20supported%20poly%28amidoxime%29%20copper%20complex%20for%20Click%20reaction.pdf Sarkar, Shaheen M. and Lutfor, M. R. (2017) Cellulose Supported Poly(amidoxime) Copper Complex for Click Reaction. Journal of Cleaner Production, 141. pp. 683-692. ISSN 0959-6526 (print), 1879-1786 (online) http://doi.org/10.1016/j.jclepro.2016.09.153 DOI: 10.1016/j.jclepro.2016.09.153
institution Universiti Malaysia Pahang
building UMP Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Pahang
content_source UMP Institutional Repository
url_provider http://umpir.ump.edu.my/
language English
topic Q Science (General)
spellingShingle Q Science (General)
Sarkar, Shaheen M.
Lutfor, M. R.
Cellulose Supported Poly(amidoxime) Copper Complex for Click Reaction
description A highly active poly(amidoxime) copper complex was prepared by the surface modification of kenaf cellulose through graft copolymerization and subsequent amidoximation. The prepared copper complex was characterized by IR, FESEM, TEM, XPS, EDX and ICP-AES analyses. The copper complex was applied to the Click reaction of organic azides and alkynes as well as one-pot three-component reactions in presence of sodium ascorbate to give the corresponding cycloaddition products in up to 96% yield. The complex was easy to recover and reused six times without significance loss of its activity.
format Article
author Sarkar, Shaheen M.
Lutfor, M. R.
author_facet Sarkar, Shaheen M.
Lutfor, M. R.
author_sort Sarkar, Shaheen M.
title Cellulose Supported Poly(amidoxime) Copper Complex for Click Reaction
title_short Cellulose Supported Poly(amidoxime) Copper Complex for Click Reaction
title_full Cellulose Supported Poly(amidoxime) Copper Complex for Click Reaction
title_fullStr Cellulose Supported Poly(amidoxime) Copper Complex for Click Reaction
title_full_unstemmed Cellulose Supported Poly(amidoxime) Copper Complex for Click Reaction
title_sort cellulose supported poly(amidoxime) copper complex for click reaction
publisher Elsevier Ltd
publishDate 2017
url http://umpir.ump.edu.my/id/eprint/16586/1/Cellulose%20supported%20poly%28amidoxime%29%20copper%20complex%20for%20Click%20reaction.pdf
http://umpir.ump.edu.my/id/eprint/16586/
http://doi.org/10.1016/j.jclepro.2016.09.153
_version_ 1643667965807165440
score 13.211869

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