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Bis[μ-bis-(diphenyl-phosphino)methane-κP:P']bis-[(chloro-difluoro-acetato-κO)silver(I)](Ag-Ag).

The asymmetric unit of the title compound, [Ag(2)(C(2)ClF(2)O(2))(2)(C(25)H(22)P(2))(2)], consists of two half-mol-ecules, each Ag(I) ion lying on a center of symmetry. In each complete mol-ecule, two bis-(diphenyl-phosphino)methane ligands bridge two Ag(I) ions, which are further coordinated by one...

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Main Authors: Lo, K.M., Ng, S.W.
Format: Article
Published: International Union of Crystallography 2008
Subjects:
QD Chemistry
Online Access:http://eprints.um.edu.my/846/
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961164/
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spelling my.um.eprints.8462019-01-31T02:22:05Z http://eprints.um.edu.my/846/ Bis[μ-bis-(diphenyl-phosphino)methane-κP:P']bis-[(chloro-difluoro-acetato-κO)silver(I)](Ag-Ag). Lo, K.M. Ng, S.W. QD Chemistry The asymmetric unit of the title compound, [Ag(2)(C(2)ClF(2)O(2))(2)(C(25)H(22)P(2))(2)], consists of two half-mol-ecules, each Ag(I) ion lying on a center of symmetry. In each complete mol-ecule, two bis-(diphenyl-phosphino)methane ligands bridge two Ag(I) ions, which are further coordinated by one chloro-difluoro-acetate ligand, giving T-shaped geometries and short intra-molecular Ag⋯Ag distances of 3.1078 (6) and 2.9950 (6) Å. In one mol-ecule, the unique -CF(2)Cl group is rotationally disordered over two sites with approximate occupancies of 0.53 and 0.47 for the major and minor components, respectively. International Union of Crystallography 2008 Article PeerReviewed Lo, K.M. and Ng, S.W. (2008) Bis[μ-bis-(diphenyl-phosphino)methane-κP:P']bis-[(chloro-difluoro-acetato-κO)silver(I)](Ag-Ag). Acta Crystallographica Section E: Structure Reports Online, 64 (Pt 5). m717. ISSN 1600-5368 http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961164/ 21202244
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic QD Chemistry
spellingShingle QD Chemistry
Lo, K.M.
Ng, S.W.
Bis[μ-bis-(diphenyl-phosphino)methane-κP:P']bis-[(chloro-difluoro-acetato-κO)silver(I)](Ag-Ag).
description The asymmetric unit of the title compound, [Ag(2)(C(2)ClF(2)O(2))(2)(C(25)H(22)P(2))(2)], consists of two half-mol-ecules, each Ag(I) ion lying on a center of symmetry. In each complete mol-ecule, two bis-(diphenyl-phosphino)methane ligands bridge two Ag(I) ions, which are further coordinated by one chloro-difluoro-acetate ligand, giving T-shaped geometries and short intra-molecular Ag⋯Ag distances of 3.1078 (6) and 2.9950 (6) Å. In one mol-ecule, the unique -CF(2)Cl group is rotationally disordered over two sites with approximate occupancies of 0.53 and 0.47 for the major and minor components, respectively.
format Article
author Lo, K.M.
Ng, S.W.
author_facet Lo, K.M.
Ng, S.W.
author_sort Lo, K.M.
title Bis[μ-bis-(diphenyl-phosphino)methane-κP:P']bis-[(chloro-difluoro-acetato-κO)silver(I)](Ag-Ag).
title_short Bis[μ-bis-(diphenyl-phosphino)methane-κP:P']bis-[(chloro-difluoro-acetato-κO)silver(I)](Ag-Ag).
title_full Bis[μ-bis-(diphenyl-phosphino)methane-κP:P']bis-[(chloro-difluoro-acetato-κO)silver(I)](Ag-Ag).
title_fullStr Bis[μ-bis-(diphenyl-phosphino)methane-κP:P']bis-[(chloro-difluoro-acetato-κO)silver(I)](Ag-Ag).
title_full_unstemmed Bis[μ-bis-(diphenyl-phosphino)methane-κP:P']bis-[(chloro-difluoro-acetato-κO)silver(I)](Ag-Ag).
title_sort bis[μ-bis-(diphenyl-phosphino)methane-κp:p']bis-[(chloro-difluoro-acetato-κo)silver(i)](ag-ag).
publisher International Union of Crystallography
publishDate 2008
url http://eprints.um.edu.my/846/
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961164/
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score 13.211869

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