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Bis(-5-hydroxy-2-{[2-(N-phenylthiocarbamoyl)hydrazin-1-ylidene]methyl} phenolato)bis[chloridozinc(II)] N,N-Dimethylformamide tetra-solvate

In the dinuclear title compound, [Zn2(C14H 12N3O2S)2Cl2] ·4C3H7NO, the two monodeprotonated Schiff base ligands N,O,S:Ochelate to Zn atoms. The formally negatively charged O atom involved in chelation also serves as a bridge. The O, O′, N and S atoms comprise a square, and the Cl atom the apex of a...

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Main Authors: Tan, Kong Wai, Ng, S.W., Ng, C.H., Maah, Mohd Jamil
Format: Article
Language:English
Published: International Union of Crystallography 2010
Subjects:
QD Chemistry
Online Access:http://eprints.um.edu.my/8035/1/Tan-2010-Bis%28-5-hydroxy-2-%7B%5B2.pdf
http://eprints.um.edu.my/8035/
http://journals.iucr.org/e/issues/2010/05/00/hg2675/hg2675.pdf
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spelling my.um.eprints.80352019-01-31T05:28:11Z http://eprints.um.edu.my/8035/ Bis(-5-hydroxy-2-{[2-(N-phenylthiocarbamoyl)hydrazin-1-ylidene]methyl} phenolato)bis[chloridozinc(II)] N,N-Dimethylformamide tetra-solvate Tan, Kong Wai Ng, S.W. Ng, C.H. Maah, Mohd Jamil QD Chemistry In the dinuclear title compound, [Zn2(C14H 12N3O2S)2Cl2] ·4C3H7NO, the two monodeprotonated Schiff base ligands N,O,S:Ochelate to Zn atoms. The formally negatively charged O atom involved in chelation also serves as a bridge. The O, O′, N and S atoms comprise a square, and the Cl atom the apex of a square pyramid surrounding each metal atom. The solvate Dimethylformamide molecules, one of which is disordered over two positions in a 3:1 ratio, are hydrogen bonded to the dinuclear molecule. © 2010. International Union of Crystallography 2010 Article PeerReviewed application/pdf en http://eprints.um.edu.my/8035/1/Tan-2010-Bis%28-5-hydroxy-2-%7B%5B2.pdf Tan, Kong Wai and Ng, S.W. and Ng, C.H. and Maah, Mohd Jamil (2010) Bis(-5-hydroxy-2-{[2-(N-phenylthiocarbamoyl)hydrazin-1-ylidene]methyl} phenolato)bis[chloridozinc(II)] N,N-Dimethylformamide tetra-solvate. Acta Crystallographica Section E: Structure Reports Online, 66 (5). ISSN 1600-5368 http://journals.iucr.org/e/issues/2010/05/00/hg2675/hg2675.pdf 10.1107/S1600536810014522
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
language English
topic QD Chemistry
spellingShingle QD Chemistry
Tan, Kong Wai
Ng, S.W.
Ng, C.H.
Maah, Mohd Jamil
Bis(-5-hydroxy-2-{[2-(N-phenylthiocarbamoyl)hydrazin-1-ylidene]methyl} phenolato)bis[chloridozinc(II)] N,N-Dimethylformamide tetra-solvate
description In the dinuclear title compound, [Zn2(C14H 12N3O2S)2Cl2] ·4C3H7NO, the two monodeprotonated Schiff base ligands N,O,S:Ochelate to Zn atoms. The formally negatively charged O atom involved in chelation also serves as a bridge. The O, O′, N and S atoms comprise a square, and the Cl atom the apex of a square pyramid surrounding each metal atom. The solvate Dimethylformamide molecules, one of which is disordered over two positions in a 3:1 ratio, are hydrogen bonded to the dinuclear molecule. © 2010.
format Article
author Tan, Kong Wai
Ng, S.W.
Ng, C.H.
Maah, Mohd Jamil
author_facet Tan, Kong Wai
Ng, S.W.
Ng, C.H.
Maah, Mohd Jamil
author_sort Tan, Kong Wai
title Bis(-5-hydroxy-2-{[2-(N-phenylthiocarbamoyl)hydrazin-1-ylidene]methyl} phenolato)bis[chloridozinc(II)] N,N-Dimethylformamide tetra-solvate
title_short Bis(-5-hydroxy-2-{[2-(N-phenylthiocarbamoyl)hydrazin-1-ylidene]methyl} phenolato)bis[chloridozinc(II)] N,N-Dimethylformamide tetra-solvate
title_full Bis(-5-hydroxy-2-{[2-(N-phenylthiocarbamoyl)hydrazin-1-ylidene]methyl} phenolato)bis[chloridozinc(II)] N,N-Dimethylformamide tetra-solvate
title_fullStr Bis(-5-hydroxy-2-{[2-(N-phenylthiocarbamoyl)hydrazin-1-ylidene]methyl} phenolato)bis[chloridozinc(II)] N,N-Dimethylformamide tetra-solvate
title_full_unstemmed Bis(-5-hydroxy-2-{[2-(N-phenylthiocarbamoyl)hydrazin-1-ylidene]methyl} phenolato)bis[chloridozinc(II)] N,N-Dimethylformamide tetra-solvate
title_sort bis(-5-hydroxy-2-{[2-(n-phenylthiocarbamoyl)hydrazin-1-ylidene]methyl} phenolato)bis[chloridozinc(ii)] n,n-dimethylformamide tetra-solvate
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/8035/1/Tan-2010-Bis%28-5-hydroxy-2-%7B%5B2.pdf
http://eprints.um.edu.my/8035/
http://journals.iucr.org/e/issues/2010/05/00/hg2675/hg2675.pdf
_version_ 1643688200035631104
score 13.211869

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