Characteristics of PEMA/PVdF-HFP blend polymeric gel films incorporated with lithium triflate salt in electrochromic device
Poly(ethyl methacrylate), PEMA and poly(vinylidenefluoride-co-hexafluoropropylene), PVdF-HFP have been blended in the weight ratio 70:30. The blend has been incorporated with lithium trifluoromethanesulfonate (LiCF3SO3) and added with ethylene carbonate (EC) and propylene carbonate (PC). The sample...
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| Main Authors: | , , |
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| Format: | Article |
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Elsevier
2012
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| Online Access: | http://eprints.um.edu.my/7700/ https://doi.org/10.1016/j.ssi.2011.11.035 |
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| Summary: | Poly(ethyl methacrylate), PEMA and poly(vinylidenefluoride-co-hexafluoropropylene), PVdF-HFP have been blended in the weight ratio 70:30. The blend has been incorporated with lithium trifluoromethanesulfonate (LiCF3SO3) and added with ethylene carbonate (EC) and propylene carbonate (PC). The sample 70 wt.% PEMA/PVdF-HFP - 30 wt.% LiCF3SO3 exhibits the highest room temperature ionic conductivity of 2.87 x 10(-7) S cm(-1) for the blend-salt system. The sample in the PC system (designated 6PC) has the highest room temperature conductivity of 1.46 x 10(-6) S cm(-1). The highest conducting EC system has conductivity of 1.05 x 10(-4) S cm(-1) and the sample is designated as 6EC. The polymeric gel electrolytes are transparent and mechanically stable at room temperature. An electrochromic device (ECD) with configuration glass/FTO/WO3/sample/CeO2-TiO2/FTO/glass utilizing S30, 6PC and 6EC as electrolytes have been fabricated. The cyclic voltammogram (CV) of glass/FTO/WO3/6EC/CeO2-TiO2/FTO/glass shows a cathodic peak occurring at -1.3 V upon coloration while an anodic peak is observed at -0.8 V during bleaching process. (c) 2011 Elsevier B.V. All rights reserved. |
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