Effect of KOH concentration in the gel polymer electrolyte for direct borohydride fuel cell

The performance of a direct borohydride fuel cell (DBFC) based on a polyacrylamide (PAAm) gel polymer electrolyte system is investigated at different electrolyte concentrations. The DBFC, constructed using 2M sodium borohydride (NaBH4) as the fuel and potassium hydroxide (KOH) solution gelled with P...

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Main Authors: Ng, P.L., Mohamad, A.A., Ahmad, Z.A., Basirun, Wan Jefrey, Alias, Y., Jamaludin, A.
Format: Article
Published: Wiley 2012
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Online Access:http://eprints.um.edu.my/7526/
http://onlinelibrary.wiley.com/doi/10.1002/app.34666/abstract
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spelling my.um.eprints.75262019-01-31T07:59:41Z http://eprints.um.edu.my/7526/ Effect of KOH concentration in the gel polymer electrolyte for direct borohydride fuel cell Ng, P.L. Mohamad, A.A. Ahmad, Z.A. Basirun, Wan Jefrey Alias, Y. Jamaludin, A. QD Chemistry The performance of a direct borohydride fuel cell (DBFC) based on a polyacrylamide (PAAm) gel polymer electrolyte system is investigated at different electrolyte concentrations. The DBFC, constructed using 2M sodium borohydride (NaBH4) as the fuel and potassium hydroxide (KOH) solution gelled with PAAm as the electrolytes yield the highest electrical conductivity of 2.73 x 10-1 S cm-1 at 6M KOH. The optimized composition, PAAm + 2M NaBH4 + 6M KOH, and the selected composition, PAAm + 2M NaBH4 + 3M KOH are then used in preparing the cells. Open-circuit voltages for fuel cells is about 0.85-0.92 V, and the discharge characteristic produce discharge capacities of about 257.12-273.12 mAh cm-2 for cells with PAAm-6M KOH. Current-voltage and current density-power density plots and internal resistance for both cells are almost the same. (c) 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 Wiley 2012 Article PeerReviewed Ng, P.L. and Mohamad, A.A. and Ahmad, Z.A. and Basirun, Wan Jefrey and Alias, Y. and Jamaludin, A. (2012) Effect of KOH concentration in the gel polymer electrolyte for direct borohydride fuel cell. Journal of Applied Polymer Science, 123 (5). pp. 2662-2666. ISSN 0021-8995 http://onlinelibrary.wiley.com/doi/10.1002/app.34666/abstract 10.1002/app.34666
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic QD Chemistry
spellingShingle QD Chemistry
Ng, P.L.
Mohamad, A.A.
Ahmad, Z.A.
Basirun, Wan Jefrey
Alias, Y.
Jamaludin, A.
Effect of KOH concentration in the gel polymer electrolyte for direct borohydride fuel cell
description The performance of a direct borohydride fuel cell (DBFC) based on a polyacrylamide (PAAm) gel polymer electrolyte system is investigated at different electrolyte concentrations. The DBFC, constructed using 2M sodium borohydride (NaBH4) as the fuel and potassium hydroxide (KOH) solution gelled with PAAm as the electrolytes yield the highest electrical conductivity of 2.73 x 10-1 S cm-1 at 6M KOH. The optimized composition, PAAm + 2M NaBH4 + 6M KOH, and the selected composition, PAAm + 2M NaBH4 + 3M KOH are then used in preparing the cells. Open-circuit voltages for fuel cells is about 0.85-0.92 V, and the discharge characteristic produce discharge capacities of about 257.12-273.12 mAh cm-2 for cells with PAAm-6M KOH. Current-voltage and current density-power density plots and internal resistance for both cells are almost the same. (c) 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012
format Article
author Ng, P.L.
Mohamad, A.A.
Ahmad, Z.A.
Basirun, Wan Jefrey
Alias, Y.
Jamaludin, A.
author_facet Ng, P.L.
Mohamad, A.A.
Ahmad, Z.A.
Basirun, Wan Jefrey
Alias, Y.
Jamaludin, A.
author_sort Ng, P.L.
title Effect of KOH concentration in the gel polymer electrolyte for direct borohydride fuel cell
title_short Effect of KOH concentration in the gel polymer electrolyte for direct borohydride fuel cell
title_full Effect of KOH concentration in the gel polymer electrolyte for direct borohydride fuel cell
title_fullStr Effect of KOH concentration in the gel polymer electrolyte for direct borohydride fuel cell
title_full_unstemmed Effect of KOH concentration in the gel polymer electrolyte for direct borohydride fuel cell
title_sort effect of koh concentration in the gel polymer electrolyte for direct borohydride fuel cell
publisher Wiley
publishDate 2012
url http://eprints.um.edu.my/7526/
http://onlinelibrary.wiley.com/doi/10.1002/app.34666/abstract
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score 13.211869