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Bis(mu-4-hydroxy-2-oxidobenzaldehyde 4-ethylthiosemicarbazone)-kappa O-4(2),N-1,S:O-2;kappa O-4(2):O-2,N-1,S-bis chloridozinc(II) dimethyl sulfoxide trisolvate

The two Zn-II atoms in the title compound, [Zn-2(C10H12N3O2S)(2)Cl-2]center dot 3C(2)H(6)OS, are each N,O,S-chelated by a mono-deprotonated Schiff base ligand. The Zn atoms are bridged through the phenolate O atom, leading to a central Zn2O2 core. Each Zn atom has a Cl atom in the apical position of...

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Main Authors: Tan, Kong Wai, Ng, S.W., Maah, Mohd Jamil, Ng, C.H.
Format: Article
Language:English
Published: International Union of Crystallography 2009
Subjects:
QD Chemistry
Online Access:http://eprints.um.edu.my/6959/1/Tan-2009-Bis%28mu-4-hydroxy-2-o.pdf
http://eprints.um.edu.my/6959/
http://journals.iucr.org/e/issues/2009/05/00/tk2395/tk2395.pdf
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spelling my.um.eprints.69592019-01-30T08:53:34Z http://eprints.um.edu.my/6959/ Bis(mu-4-hydroxy-2-oxidobenzaldehyde 4-ethylthiosemicarbazone)-kappa O-4(2),N-1,S:O-2;kappa O-4(2):O-2,N-1,S-bis chloridozinc(II) dimethyl sulfoxide trisolvate Tan, Kong Wai Ng, S.W. Maah, Mohd Jamil Ng, C.H. QD Chemistry The two Zn-II atoms in the title compound, [Zn-2(C10H12N3O2S)(2)Cl-2]center dot 3C(2)H(6)OS, are each N,O,S-chelated by a mono-deprotonated Schiff base ligand. The Zn atoms are bridged through the phenolate O atom, leading to a central Zn2O2 core. Each Zn atom has a Cl atom in the apical position of a distorted square-pyramidal environment. Hydroxy-DMSO (DMSO is dimethyl sulfoxide) O-H center dot center dot center dot O and amide-DMSO N-H center dot center dot center dot O hydrogen bonds link the components of the crystal structure. Two of the DMSO molecules are partially disordered, with each modelled over two sites of equal weight. International Union of Crystallography 2009 Article PeerReviewed application/pdf en http://eprints.um.edu.my/6959/1/Tan-2009-Bis%28mu-4-hydroxy-2-o.pdf Tan, Kong Wai and Ng, S.W. and Maah, Mohd Jamil and Ng, C.H. (2009) Bis(mu-4-hydroxy-2-oxidobenzaldehyde 4-ethylthiosemicarbazone)-kappa O-4(2),N-1,S:O-2;kappa O-4(2):O-2,N-1,S-bis chloridozinc(II) dimethyl sulfoxide trisolvate. Acta Crystallographica Section E: Structure Reports Online, 65. M549-U774. ISSN 1600-5368 http://journals.iucr.org/e/issues/2009/05/00/tk2395/tk2395.pdf 10.1107/s1600536809013385
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
language English
topic QD Chemistry
spellingShingle QD Chemistry
Tan, Kong Wai
Ng, S.W.
Maah, Mohd Jamil
Ng, C.H.
Bis(mu-4-hydroxy-2-oxidobenzaldehyde 4-ethylthiosemicarbazone)-kappa O-4(2),N-1,S:O-2;kappa O-4(2):O-2,N-1,S-bis chloridozinc(II) dimethyl sulfoxide trisolvate
description The two Zn-II atoms in the title compound, [Zn-2(C10H12N3O2S)(2)Cl-2]center dot 3C(2)H(6)OS, are each N,O,S-chelated by a mono-deprotonated Schiff base ligand. The Zn atoms are bridged through the phenolate O atom, leading to a central Zn2O2 core. Each Zn atom has a Cl atom in the apical position of a distorted square-pyramidal environment. Hydroxy-DMSO (DMSO is dimethyl sulfoxide) O-H center dot center dot center dot O and amide-DMSO N-H center dot center dot center dot O hydrogen bonds link the components of the crystal structure. Two of the DMSO molecules are partially disordered, with each modelled over two sites of equal weight.
format Article
author Tan, Kong Wai
Ng, S.W.
Maah, Mohd Jamil
Ng, C.H.
author_facet Tan, Kong Wai
Ng, S.W.
Maah, Mohd Jamil
Ng, C.H.
author_sort Tan, Kong Wai
title Bis(mu-4-hydroxy-2-oxidobenzaldehyde 4-ethylthiosemicarbazone)-kappa O-4(2),N-1,S:O-2;kappa O-4(2):O-2,N-1,S-bis chloridozinc(II) dimethyl sulfoxide trisolvate
title_short Bis(mu-4-hydroxy-2-oxidobenzaldehyde 4-ethylthiosemicarbazone)-kappa O-4(2),N-1,S:O-2;kappa O-4(2):O-2,N-1,S-bis chloridozinc(II) dimethyl sulfoxide trisolvate
title_full Bis(mu-4-hydroxy-2-oxidobenzaldehyde 4-ethylthiosemicarbazone)-kappa O-4(2),N-1,S:O-2;kappa O-4(2):O-2,N-1,S-bis chloridozinc(II) dimethyl sulfoxide trisolvate
title_fullStr Bis(mu-4-hydroxy-2-oxidobenzaldehyde 4-ethylthiosemicarbazone)-kappa O-4(2),N-1,S:O-2;kappa O-4(2):O-2,N-1,S-bis chloridozinc(II) dimethyl sulfoxide trisolvate
title_full_unstemmed Bis(mu-4-hydroxy-2-oxidobenzaldehyde 4-ethylthiosemicarbazone)-kappa O-4(2),N-1,S:O-2;kappa O-4(2):O-2,N-1,S-bis chloridozinc(II) dimethyl sulfoxide trisolvate
title_sort bis(mu-4-hydroxy-2-oxidobenzaldehyde 4-ethylthiosemicarbazone)-kappa o-4(2),n-1,s:o-2;kappa o-4(2):o-2,n-1,s-bis chloridozinc(ii) dimethyl sulfoxide trisolvate
publisher International Union of Crystallography
publishDate 2009
url http://eprints.um.edu.my/6959/1/Tan-2009-Bis%28mu-4-hydroxy-2-o.pdf
http://eprints.um.edu.my/6959/
http://journals.iucr.org/e/issues/2009/05/00/tk2395/tk2395.pdf
_version_ 1643687927269556224
score 13.211869

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