Staff View: Octa-n-butyl-1κ 2 C,2κ 2 C,3κ 2 C,4κ 2 C-tetrakis(μ-2-hydroxybenzoato)-1:2κ 2 O:O;2:3κ2 O:O′;3:4κ 2 O:O;1:4κ 2 O:O′-di-μ 3-oxido-1:2:3κ 3 O:O:O;1:3:4κ 3 O:O:O-tetratin(IV)

Octa-n-butyl-1κ 2 C,2κ 2 C,3κ 2 C,4κ 2 C-tetrakis(μ-2-hydroxybenzoato)-1:2κ 2 O:O;2:3κ2 O:O′;3:4κ 2 O:O;1:4κ 2 O:O′-di-μ 3-oxido-1:2:3κ 3 O:O:O;1:3:4κ 3 O:O:O-tetratin(IV)

In the centrosymmetric tetranuclear title compound, [Sn4(C4H9)8(C7H5O3)4O2], one of the two independent Sn atoms is five-coordinate in a cis-C2SnO3 trigonal-bipyramidal geometry [C—Sn—C = 142.7 (1)°]; the geometry is distorted owing to a long Sn⋯O(double bond) interaction [Sn⋯O = 2.862 (1) Å]. The...

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Main Authors:	Reisi, Reza, Shahirin, Siti Munirah, Misran, Misni, Lo, Kong Mun, Ng, Seik Weng
Format:	Article
Language:	English
Published:	International Union of Crystallography 2008
Subjects:	QD Chemistry
Online Access:	http://eprints.um.edu.my/6850/1/Octa-n-butyl-1kappaC%2C2kappaC%2C3kappaC%2C4kappaC-tetra-kis%28mu-2-hydroxy-benzoato%29-12_kappaOO%3B23kappaOO%27%3B34kappaOO%3B14kappaOO%27-di-mu%283%29-oxido-123kappaOOO%3B13_4kappaOOO-tetra-tin.pdf http://eprints.um.edu.my/6850/ https://doi.org/10.1107/S1600536808023787
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spelling	my.um.eprints.68502020-12-11T06:39:44Z http://eprints.um.edu.my/6850/ Octa-n-butyl-1κ 2 C,2κ 2 C,3κ 2 C,4κ 2 C-tetrakis(μ-2-hydroxybenzoato)-1:2κ 2 O:O;2:3κ2 O:O′;3:4κ 2 O:O;1:4κ 2 O:O′-di-μ 3-oxido-1:2:3κ 3 O:O:O;1:3:4κ 3 O:O:O-tetratin(IV) Reisi, Reza Shahirin, Siti Munirah Misran, Misni Lo, Kong Mun Ng, Seik Weng QD Chemistry In the centrosymmetric tetranuclear title compound, [Sn4(C4H9)8(C7H5O3)4O2], one of the two independent Sn atoms is five-coordinate in a cis-C2SnO3 trigonal-bipyramidal geometry [C—Sn—C = 142.7 (1)°]; the geometry is distorted owing to a long Sn⋯O(double bond) interaction [Sn⋯O = 2.862 (1) Å]. The other Sn atom has a bent R 2Sn skeleton [C—Sn—C = 144.0 (1)°], but the geometry is best regarded as being a trans-C2SnO4 octahedron as the Sn–O(single bond) interaction is shorter [Sn—O = 2.674 (1) Å]. International Union of Crystallography 2008 Article PeerReviewed application/pdf en http://eprints.um.edu.my/6850/1/Octa-n-butyl-1kappaC%2C2kappaC%2C3kappaC%2C4kappaC-tetra-kis%28mu-2-hydroxy-benzoato%29-12_kappaOO%3B23kappaOO%27%3B34kappaOO%3B14kappaOO%27-di-mu%283%29-oxido-123kappaOOO%3B13_4kappaOOO-tetra-tin.pdf Reisi, Reza and Shahirin, Siti Munirah and Misran, Misni and Lo, Kong Mun and Ng, Seik Weng (2008) Octa-n-butyl-1κ 2 C,2κ 2 C,3κ 2 C,4κ 2 C-tetrakis(μ-2-hydroxybenzoato)-1:2κ 2 O:O;2:3κ2 O:O′;3:4κ 2 O:O;1:4κ 2 O:O′-di-μ 3-oxido-1:2:3κ 3 O:O:O;1:3:4κ 3 O:O:O-tetratin(IV). Acta Crystallographica Section E: Structure Reports Online, 64 (8). m1103. ISSN 1600-5368 https://doi.org/10.1107/S1600536808023787 doi:10.1107/S1600536808023787
institution	Universiti Malaya
building	UM Library
collection	Institutional Repository
continent	Asia
country	Malaysia
content_provider	Universiti Malaya
content_source	UM Research Repository
url_provider	http://eprints.um.edu.my/
language	English
topic	QD Chemistry
spellingShingle	QD Chemistry Reisi, Reza Shahirin, Siti Munirah Misran, Misni Lo, Kong Mun Ng, Seik Weng Octa-n-butyl-1κ 2 C,2κ 2 C,3κ 2 C,4κ 2 C-tetrakis(μ-2-hydroxybenzoato)-1:2κ 2 O:O;2:3κ2 O:O′;3:4κ 2 O:O;1:4κ 2 O:O′-di-μ 3-oxido-1:2:3κ 3 O:O:O;1:3:4κ 3 O:O:O-tetratin(IV)
description	In the centrosymmetric tetranuclear title compound, [Sn4(C4H9)8(C7H5O3)4O2], one of the two independent Sn atoms is five-coordinate in a cis-C2SnO3 trigonal-bipyramidal geometry [C—Sn—C = 142.7 (1)°]; the geometry is distorted owing to a long Sn⋯O(double bond) interaction [Sn⋯O = 2.862 (1) Å]. The other Sn atom has a bent R 2Sn skeleton [C—Sn—C = 144.0 (1)°], but the geometry is best regarded as being a trans-C2SnO4 octahedron as the Sn–O(single bond) interaction is shorter [Sn—O = 2.674 (1) Å].
format	Article
author	Reisi, Reza Shahirin, Siti Munirah Misran, Misni Lo, Kong Mun Ng, Seik Weng
author_facet	Reisi, Reza Shahirin, Siti Munirah Misran, Misni Lo, Kong Mun Ng, Seik Weng
author_sort	Reisi, Reza
title	Octa-n-butyl-1κ 2 C,2κ 2 C,3κ 2 C,4κ 2 C-tetrakis(μ-2-hydroxybenzoato)-1:2κ 2 O:O;2:3κ2 O:O′;3:4κ 2 O:O;1:4κ 2 O:O′-di-μ 3-oxido-1:2:3κ 3 O:O:O;1:3:4κ 3 O:O:O-tetratin(IV)
title_short	Octa-n-butyl-1κ 2 C,2κ 2 C,3κ 2 C,4κ 2 C-tetrakis(μ-2-hydroxybenzoato)-1:2κ 2 O:O;2:3κ2 O:O′;3:4κ 2 O:O;1:4κ 2 O:O′-di-μ 3-oxido-1:2:3κ 3 O:O:O;1:3:4κ 3 O:O:O-tetratin(IV)
title_full	Octa-n-butyl-1κ 2 C,2κ 2 C,3κ 2 C,4κ 2 C-tetrakis(μ-2-hydroxybenzoato)-1:2κ 2 O:O;2:3κ2 O:O′;3:4κ 2 O:O;1:4κ 2 O:O′-di-μ 3-oxido-1:2:3κ 3 O:O:O;1:3:4κ 3 O:O:O-tetratin(IV)
title_fullStr	Octa-n-butyl-1κ 2 C,2κ 2 C,3κ 2 C,4κ 2 C-tetrakis(μ-2-hydroxybenzoato)-1:2κ 2 O:O;2:3κ2 O:O′;3:4κ 2 O:O;1:4κ 2 O:O′-di-μ 3-oxido-1:2:3κ 3 O:O:O;1:3:4κ 3 O:O:O-tetratin(IV)
title_full_unstemmed	Octa-n-butyl-1κ 2 C,2κ 2 C,3κ 2 C,4κ 2 C-tetrakis(μ-2-hydroxybenzoato)-1:2κ 2 O:O;2:3κ2 O:O′;3:4κ 2 O:O;1:4κ 2 O:O′-di-μ 3-oxido-1:2:3κ 3 O:O:O;1:3:4κ 3 O:O:O-tetratin(IV)
title_sort	octa-n-butyl-1κ 2 c,2κ 2 c,3κ 2 c,4κ 2 c-tetrakis(μ-2-hydroxybenzoato)-1:2κ 2 o:o;2:3κ2 o:o′;3:4κ 2 o:o;1:4κ 2 o:o′-di-μ 3-oxido-1:2:3κ 3 o:o:o;1:3:4κ 3 o:o:o-tetratin(iv)
publisher	International Union of Crystallography
publishDate	2008
url	http://eprints.um.edu.my/6850/1/Octa-n-butyl-1kappaC%2C2kappaC%2C3kappaC%2C4kappaC-tetra-kis%28mu-2-hydroxy-benzoato%29-12_kappaOO%3B23kappaOO%27%3B34kappaOO%3B14kappaOO%27-di-mu%283%29-oxido-123kappaOOO%3B13_4kappaOOO-tetra-tin.pdf http://eprints.um.edu.my/6850/ https://doi.org/10.1107/S1600536808023787
_version_	1687394116046946304
score	13.211869

Octa-n-butyl-1κ 2 C,2κ 2 C,3κ 2 C,4κ 2 C-tetra­kis(μ-2-hydroxy­benzoato)-1:2κ 2 O:O;2:3κ2 O:O′;3:4κ 2 O:O;1:4κ 2 O:O′-di-μ 3-oxido-1:2:3κ 3 O:O:O;1:3:4κ 3 O:O:O-tetra­tin(IV)

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Octa-n-butyl-1κ 2 C,2κ 2 C,3κ 2 C,4κ 2 C-tetrakis(μ-2-hydroxybenzoato)-1:2κ 2 O:O;2:3κ2 O:O′;3:4κ 2 O:O;1:4κ 2 O:O′-di-μ 3-oxido-1:2:3κ 3 O:O:O;1:3:4κ 3 O:O:O-tetratin(IV)