Bis 1,3-dihydroxy-2-hydroxymethyl-2-(5-nitro-2-oxidobenzylideneamino) propane-kappa N-3,O,O ' nickel(II) pyridine solvate
The Ni-II atom in the title complex, [Ni(C11H13N2O6)(2)]center dot C5H5N, is chelated by a terdentate Schiff base anion in a slightly octahedral geometry. One of the coordinated hydroxyl groups forms a hydrogen bond with the pyridine solvent molecule. In the crystal structure, other hydroxyl groups...
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| Main Authors: | , , |
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| Format: | Article |
| Published: |
International Union of Crystallography
2006
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/5545/ http://scripts.iucr.org/cgi-bin/paper?S1600536806038694 |
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| Summary: | The Ni-II atom in the title complex, [Ni(C11H13N2O6)(2)]center dot C5H5N, is chelated by a terdentate Schiff base anion in a slightly octahedral geometry. One of the coordinated hydroxyl groups forms a hydrogen bond with the pyridine solvent molecule. In the crystal structure, other hydroxyl groups are involved in intermolecular hydrogen bonding, forming a two-dimensional layer. |
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