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Bis[1,5-bis­(1H-indol-3-ylmethyl­ene)thio­carbazonato-κ2 N,S]nickel(II) dimethyl sulfoxide disolvate

The Ni atom in the crystal structure of the centrosymmetric title compound, [Ni(C19H15N6S)2]·2C2H6OS, is N,S-chelated by the deprotonated Schiff bases in a square-planar geometry. The –CH=N—N=C(S)—NH—N=CH– frament is planar. The two indolyl –NH (donor) sites inter­act with dimethyl sulfoxide mol­ecu...

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Main Authors: Rizal, Mohd Razali, Ali, Hapipah Mohd, Ng, Seik Weng
Format: Article
Language:English
Published: International Union of Crystallography 2008
Subjects:
QD Chemistry
Online Access:http://eprints.um.edu.my/5440/1/Rizal-2008-Bis_1%2C5-bis%281H-indol.pdf
http://eprints.um.edu.my/5440/
https://doi.org/10.1107/S1600536808011975
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spelling my.um.eprints.54402020-12-11T07:24:16Z http://eprints.um.edu.my/5440/ Bis[1,5-bis­(1H-indol-3-ylmethyl­ene)thio­carbazonato-κ2 N,S]nickel(II) dimethyl sulfoxide disolvate Rizal, Mohd Razali Ali, Hapipah Mohd Ng, Seik Weng QD Chemistry The Ni atom in the crystal structure of the centrosymmetric title compound, [Ni(C19H15N6S)2]·2C2H6OS, is N,S-chelated by the deprotonated Schiff bases in a square-planar geometry. The –CH=N—N=C(S)—NH—N=CH– frament is planar. The two indolyl –NH (donor) sites inter­act with dimethyl sulfoxide mol­ecules to furnish a layer motif. International Union of Crystallography 2008 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5440/1/Rizal-2008-Bis_1%2C5-bis%281H-indol.pdf Rizal, Mohd Razali and Ali, Hapipah Mohd and Ng, Seik Weng (2008) Bis[1,5-bis­(1H-indol-3-ylmethyl­ene)thio­carbazonato-κ2 N,S]nickel(II) dimethyl sulfoxide disolvate. Acta Crystallographica Section E: Structure Reports Online, 64 (Pt 6). m755. ISSN 1600-5368 https://doi.org/10.1107/S1600536808011975 doi:10.1107/s1600536808011975
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
language English
topic QD Chemistry
spellingShingle QD Chemistry
Rizal, Mohd Razali
Ali, Hapipah Mohd
Ng, Seik Weng
Bis[1,5-bis­(1H-indol-3-ylmethyl­ene)thio­carbazonato-κ2 N,S]nickel(II) dimethyl sulfoxide disolvate
description The Ni atom in the crystal structure of the centrosymmetric title compound, [Ni(C19H15N6S)2]·2C2H6OS, is N,S-chelated by the deprotonated Schiff bases in a square-planar geometry. The –CH=N—N=C(S)—NH—N=CH– frament is planar. The two indolyl –NH (donor) sites inter­act with dimethyl sulfoxide mol­ecules to furnish a layer motif.
format Article
author Rizal, Mohd Razali
Ali, Hapipah Mohd
Ng, Seik Weng
author_facet Rizal, Mohd Razali
Ali, Hapipah Mohd
Ng, Seik Weng
author_sort Rizal, Mohd Razali
title Bis[1,5-bis­(1H-indol-3-ylmethyl­ene)thio­carbazonato-κ2 N,S]nickel(II) dimethyl sulfoxide disolvate
title_short Bis[1,5-bis­(1H-indol-3-ylmethyl­ene)thio­carbazonato-κ2 N,S]nickel(II) dimethyl sulfoxide disolvate
title_full Bis[1,5-bis­(1H-indol-3-ylmethyl­ene)thio­carbazonato-κ2 N,S]nickel(II) dimethyl sulfoxide disolvate
title_fullStr Bis[1,5-bis­(1H-indol-3-ylmethyl­ene)thio­carbazonato-κ2 N,S]nickel(II) dimethyl sulfoxide disolvate
title_full_unstemmed Bis[1,5-bis­(1H-indol-3-ylmethyl­ene)thio­carbazonato-κ2 N,S]nickel(II) dimethyl sulfoxide disolvate
title_sort bis[1,5-bis­(1h-indol-3-ylmethyl­ene)thio­carbazonato-κ2 n,s]nickel(ii) dimethyl sulfoxide disolvate
publisher International Union of Crystallography
publishDate 2008
url http://eprints.um.edu.my/5440/1/Rizal-2008-Bis_1%2C5-bis%281H-indol.pdf
http://eprints.um.edu.my/5440/
https://doi.org/10.1107/S1600536808011975
_version_ 1687394115283582976
score 13.211869

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