Catena-Poly triphenyltin(IV) -mu-2- (3,5-di-tert-butyl-4-hydroxybenzyl) sulfanyl acetato-kappa O-2:O '
The title compound, [Sn(C6H5)(3)(C17H25O3S)](n), comprises two symmetry-independent five-coordinated triphenyltin molecules which are linked by carboxylate bridges into a polymeric chain. The Sn-IV atom is in a distorted trans-C3SnO2 trigonal-bipyramidal geometry. The presence of two bulky tert-buty...
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/5354/1/Lee-2009-catena-Poly_tripheny.pdf http://eprints.um.edu.my/5354/ |
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| Summary: | The title compound, [Sn(C6H5)(3)(C17H25O3S)](n), comprises two symmetry-independent five-coordinated triphenyltin molecules which are linked by carboxylate bridges into a polymeric chain. The Sn-IV atom is in a distorted trans-C3SnO2 trigonal-bipyramidal geometry. The presence of two bulky tert-butyl groups on the benzene ring prevents any hydrogen-bonding interactions involving the hydroxyl substituents. |
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