Bis N '-(2-oxo-1H-indol-3-ylidene)furan2-carbohydrazidato-kappa O-3,N ',O ' manganese(II) N,N-dimethylformide monosolvate monohydrate
In the title compound, [Mn(C13H8N3O3)(2)]center dot C3H7NO center dot H2O, the metal atom is O,N,O'-chelated by two deprotonated Schiff bases and exists in a distorted octahedral geometry. The N-H groups, the carbonyl group of the DMF molecule and the uncoordinated water molecule engage in N-H...
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International Union of Crystallography
2010
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my.um.eprints.53072019-01-29T09:08:39Z http://eprints.um.edu.my/5307/ Bis N '-(2-oxo-1H-indol-3-ylidene)furan2-carbohydrazidato-kappa O-3,N ',O ' manganese(II) N,N-dimethylformide monosolvate monohydrate Halim, S.N.A. Ng, S.W. Ali, Hapipah Mohd QD Chemistry In the title compound, [Mn(C13H8N3O3)(2)]center dot C3H7NO center dot H2O, the metal atom is O,N,O'-chelated by two deprotonated Schiff bases and exists in a distorted octahedral geometry. The N-H groups, the carbonyl group of the DMF molecule and the uncoordinated water molecule engage in N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen-bonding interactions, generating a hydrogen-bonded ribbon that propagates along [110]. International Union of Crystallography 2010 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5307/1/Halim-2010-Bis_N_%27-%282-oxo-1H-in.pdf Halim, S.N.A. and Ng, S.W. and Ali, Hapipah Mohd (2010) Bis N '-(2-oxo-1H-indol-3-ylidene)furan2-carbohydrazidato-kappa O-3,N ',O ' manganese(II) N,N-dimethylformide monosolvate monohydrate. Acta Crystallographica Section E: Structure Reports Online, 66. M1439-U950. ISSN 1600-5368 http://scripts.iucr.org/cgi-bin/paper?S1600536810039516 10.1107/s1600536810039516 |
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QD Chemistry Halim, S.N.A. Ng, S.W. Ali, Hapipah Mohd Bis N '-(2-oxo-1H-indol-3-ylidene)furan2-carbohydrazidato-kappa O-3,N ',O ' manganese(II) N,N-dimethylformide monosolvate monohydrate |
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In the title compound, [Mn(C13H8N3O3)(2)]center dot C3H7NO center dot H2O, the metal atom is O,N,O'-chelated by two deprotonated Schiff bases and exists in a distorted octahedral geometry. The N-H groups, the carbonyl group of the DMF molecule and the uncoordinated water molecule engage in N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen-bonding interactions, generating a hydrogen-bonded ribbon that propagates along [110]. |
format |
Article |
author |
Halim, S.N.A. Ng, S.W. Ali, Hapipah Mohd |
author_facet |
Halim, S.N.A. Ng, S.W. Ali, Hapipah Mohd |
author_sort |
Halim, S.N.A. |
title |
Bis N '-(2-oxo-1H-indol-3-ylidene)furan2-carbohydrazidato-kappa O-3,N ',O ' manganese(II) N,N-dimethylformide monosolvate monohydrate |
title_short |
Bis N '-(2-oxo-1H-indol-3-ylidene)furan2-carbohydrazidato-kappa O-3,N ',O ' manganese(II) N,N-dimethylformide monosolvate monohydrate |
title_full |
Bis N '-(2-oxo-1H-indol-3-ylidene)furan2-carbohydrazidato-kappa O-3,N ',O ' manganese(II) N,N-dimethylformide monosolvate monohydrate |
title_fullStr |
Bis N '-(2-oxo-1H-indol-3-ylidene)furan2-carbohydrazidato-kappa O-3,N ',O ' manganese(II) N,N-dimethylformide monosolvate monohydrate |
title_full_unstemmed |
Bis N '-(2-oxo-1H-indol-3-ylidene)furan2-carbohydrazidato-kappa O-3,N ',O ' manganese(II) N,N-dimethylformide monosolvate monohydrate |
title_sort |
bis n '-(2-oxo-1h-indol-3-ylidene)furan2-carbohydrazidato-kappa o-3,n ',o ' manganese(ii) n,n-dimethylformide monosolvate monohydrate |
publisher |
International Union of Crystallography |
publishDate |
2010 |
url |
http://eprints.um.edu.my/5307/1/Halim-2010-Bis_N_%27-%282-oxo-1H-in.pdf http://eprints.um.edu.my/5307/ http://scripts.iucr.org/cgi-bin/paper?S1600536810039516 |
_version_ |
1643687540245397504 |
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13.211869 |