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Di-[mu]-thio­cyanato-[kappa]2N:S;[kappa]2S:N-bis­[bis­(2-methyl-1H-benzimidazole-[kappa]N3)(thio­cyanato-[kappa]N)cadmium(II)]

The title compound, Cd-2(NCS)(4)(C8H8N2)(4), is a centrosymmetric dinuclear cadmium(II) complex in which each two metal ions are linked by a pair of thiocyanate N:S-bridges. Two 2-methylbenzimidazole N-atom donors and one terminal thiocyanate N atom complete a highly distorted square-pyramidal geome...

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Main Authors: Shaker, Shayma A., Khaledi, Hamid, Ali, Hapipah Mohd
Format: Article
Language:English
Published: International Union of Crystallography 2010
Subjects:
Q Science (General)
QD Chemistry
Online Access:http://eprints.um.edu.my/5270/1/Shaker-2010-Di-mu-thiocyanato-ka.pdf
http://eprints.um.edu.my/5270/
https://doi.org/10.1107/S1600536810042443
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spelling my.um.eprints.52702019-11-13T01:08:15Z http://eprints.um.edu.my/5270/ Di-[mu]-thio­cyanato-[kappa]2N:S;[kappa]2S:N-bis­[bis­(2-methyl-1H-benzimidazole-[kappa]N3)(thio­cyanato-[kappa]N)cadmium(II)] Shaker, Shayma A. Khaledi, Hamid Ali, Hapipah Mohd Q Science (General) QD Chemistry The title compound, Cd-2(NCS)(4)(C8H8N2)(4), is a centrosymmetric dinuclear cadmium(II) complex in which each two metal ions are linked by a pair of thiocyanate N:S-bridges. Two 2-methylbenzimidazole N-atom donors and one terminal thiocyanate N atom complete a highly distorted square-pyramidal geometry around the Cd atom. In the crystal structure, two N-H center dot center dot center dot S hydrogen-bonding interactions occur, resulting in a three-dimensional polymeric structure. The apical 2-methylbenzimidazole ring and its symmetry-related counterpart are arranged in an antiparallel manner with a centroid-centroid separation of 3.6050 (14) angstrom, indicative of a pi-pi interaction. International Union of Crystallography 2010 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5270/1/Shaker-2010-Di-mu-thiocyanato-ka.pdf Shaker, Shayma A. and Khaledi, Hamid and Ali, Hapipah Mohd (2010) Di-[mu]-thio­cyanato-[kappa]2N:S;[kappa]2S:N-bis­[bis­(2-methyl-1H-benzimidazole-[kappa]N3)(thio­cyanato-[kappa]N)cadmium(II)]. Acta Crystallographica Section E: Structure Reports Online, E66. M1464. ISSN 1600-5368 https://doi.org/10.1107/S1600536810042443 doi:10.1107/s1600536810042443
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
language English
topic Q Science (General)
QD Chemistry
spellingShingle Q Science (General)
QD Chemistry
Shaker, Shayma A.
Khaledi, Hamid
Ali, Hapipah Mohd
Di-[mu]-thio­cyanato-[kappa]2N:S;[kappa]2S:N-bis­[bis­(2-methyl-1H-benzimidazole-[kappa]N3)(thio­cyanato-[kappa]N)cadmium(II)]
description The title compound, Cd-2(NCS)(4)(C8H8N2)(4), is a centrosymmetric dinuclear cadmium(II) complex in which each two metal ions are linked by a pair of thiocyanate N:S-bridges. Two 2-methylbenzimidazole N-atom donors and one terminal thiocyanate N atom complete a highly distorted square-pyramidal geometry around the Cd atom. In the crystal structure, two N-H center dot center dot center dot S hydrogen-bonding interactions occur, resulting in a three-dimensional polymeric structure. The apical 2-methylbenzimidazole ring and its symmetry-related counterpart are arranged in an antiparallel manner with a centroid-centroid separation of 3.6050 (14) angstrom, indicative of a pi-pi interaction.
format Article
author Shaker, Shayma A.
Khaledi, Hamid
Ali, Hapipah Mohd
author_facet Shaker, Shayma A.
Khaledi, Hamid
Ali, Hapipah Mohd
author_sort Shaker, Shayma A.
title Di-[mu]-thio­cyanato-[kappa]2N:S;[kappa]2S:N-bis­[bis­(2-methyl-1H-benzimidazole-[kappa]N3)(thio­cyanato-[kappa]N)cadmium(II)]
title_short Di-[mu]-thio­cyanato-[kappa]2N:S;[kappa]2S:N-bis­[bis­(2-methyl-1H-benzimidazole-[kappa]N3)(thio­cyanato-[kappa]N)cadmium(II)]
title_full Di-[mu]-thio­cyanato-[kappa]2N:S;[kappa]2S:N-bis­[bis­(2-methyl-1H-benzimidazole-[kappa]N3)(thio­cyanato-[kappa]N)cadmium(II)]
title_fullStr Di-[mu]-thio­cyanato-[kappa]2N:S;[kappa]2S:N-bis­[bis­(2-methyl-1H-benzimidazole-[kappa]N3)(thio­cyanato-[kappa]N)cadmium(II)]
title_full_unstemmed Di-[mu]-thio­cyanato-[kappa]2N:S;[kappa]2S:N-bis­[bis­(2-methyl-1H-benzimidazole-[kappa]N3)(thio­cyanato-[kappa]N)cadmium(II)]
title_sort di-[mu]-thio­cyanato-[kappa]2n:s;[kappa]2s:n-bis­[bis­(2-methyl-1h-benzimidazole-[kappa]n3)(thio­cyanato-[kappa]n)cadmium(ii)]
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/5270/1/Shaker-2010-Di-mu-thiocyanato-ka.pdf
http://eprints.um.edu.my/5270/
https://doi.org/10.1107/S1600536810042443
_version_ 1651867324039299072
score 13.211869

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