{N,N-Dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)copper(II)
The asymmetric unit of the title compound, [Cu(NCS)(2)(C11H17N3)], consists of two crystallographically independent molecules. In each molecule, the Cu-II ion is five-coordinated in a distorted square-pyramidal geometry wherein the basal plane is defined by the N,N',N ''-tridentate Sc...
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| 主要な著者: | , , |
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| フォーマット: | 論文 |
| 言語: | English |
| 出版事項: |
International Union of Crystallography
2011
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| 主題: | |
| オンライン･アクセス: | http://eprints.um.edu.my/5250/1/Gwaram-2011-%7BN%2CN-Dimethyl-N_%27-_1.pdf http://eprints.um.edu.my/5250/ http://scripts.iucr.org/cgi-bin/paper?S1600536811022057 |
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| 要約: | The asymmetric unit of the title compound, [Cu(NCS)(2)(C11H17N3)], consists of two crystallographically independent molecules. In each molecule, the Cu-II ion is five-coordinated in a distorted square-pyramidal geometry wherein the basal plane is defined by the N,N',N ''-tridentate Schiff base and one N-bound thiocyanate ligand. The second N-donor thiocyanate group, located at the apical site, completes the coordination environment. In the crystal, intermolecular C-H center dot center dot center dot S and C-H center dot center dot center dot N hydrogen bonds link adjacent molecules into infinite layers parallel to the ac plane. Intramolecular C-H center dot center dot center dot N interactions are also observed. |
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