{N,N-Dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)copper(II)
The asymmetric unit of the title compound, [Cu(NCS)(2)(C11H17N3)], consists of two crystallographically independent molecules. In each molecule, the Cu-II ion is five-coordinated in a distorted square-pyramidal geometry wherein the basal plane is defined by the N,N',N ''-tridentate Sc...
محفوظ في:
| المؤلفون الرئيسيون: | , , |
|---|---|
| التنسيق: | مقال |
| اللغة: | English |
| منشور في: |
International Union of Crystallography
2011
|
| الموضوعات: | |
| الوصول للمادة أونلاين: | http://eprints.um.edu.my/5250/1/Gwaram-2011-%7BN%2CN-Dimethyl-N_%27-_1.pdf http://eprints.um.edu.my/5250/ http://scripts.iucr.org/cgi-bin/paper?S1600536811022057 |
| الوسوم: |
إضافة وسم
لا توجد وسوم, كن أول من يضع وسما على هذه التسجيلة!
|
| الملخص: | The asymmetric unit of the title compound, [Cu(NCS)(2)(C11H17N3)], consists of two crystallographically independent molecules. In each molecule, the Cu-II ion is five-coordinated in a distorted square-pyramidal geometry wherein the basal plane is defined by the N,N',N ''-tridentate Schiff base and one N-bound thiocyanate ligand. The second N-donor thiocyanate group, located at the apical site, completes the coordination environment. In the crystal, intermolecular C-H center dot center dot center dot S and C-H center dot center dot center dot N hydrogen bonds link adjacent molecules into infinite layers parallel to the ac plane. Intramolecular C-H center dot center dot center dot N interactions are also observed. |
|---|