Dichlorido{N,N-dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa N-3,N ',N ''} manganese(II)

The asymmetric unit of the title compound, [MnCl2(C11H17N3)], contains two crystallographically independent molecules with slightly different geometries. In each molecule, the Mn-II ion is five coordinated by the N,N',N ''-tridentate Schiff base and two Cl atoms in a distorted square-...

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Bibliographic Details
Main Authors: Hisham, N.A.I., Ali, Hapipah Mohd, Khaledi, H., Gwaram, N.S.
Format: Article
Language:English
Published: International Union of Crystallography 2011
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Online Access:http://eprints.um.edu.my/5237/1/Hisham-2011-Dichlorido%7BN%2CN-dimet.pdf
http://eprints.um.edu.my/5237/
http://journals.iucr.org/e/issues/2011/02/00/is2666/is2666.pdf
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Summary:The asymmetric unit of the title compound, [MnCl2(C11H17N3)], contains two crystallographically independent molecules with slightly different geometries. In each molecule, the Mn-II ion is five coordinated by the N,N',N ''-tridentate Schiff base and two Cl atoms in a distorted square-pyramidal geometry. In the crystal, C-H center dot center dot center dot Cl hydrogen bonds link adjacent molecules into a three-dimensional network.