Versatile coordination modes of 2-(Diformylmethylene)-3,3-dimethylindole towards late-transition-metal ions: C-H bond activation and formation of cyclic acyl-palladium(ii) complexes
The reaction of the potential multidentate ligand, 2-(diformylmethylene)-3,3-dimethylindole (diformyl), with M(OAc)(2) (M = Co-II, Ni-II, Cu-II, Zn-II, Cd-II, and Pd-II) afforded a series of metal complexes with different nuclearity in which the mono-deprotonated diformyl behaves as an N,O-bidentate...
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| Format: | Article |
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2011
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| Online Access: | http://eprints.um.edu.my/5221/ http://onlinelibrary.wiley.com/store/10.1002/ejic.201100052/asset/2394_ftp.pdf?v=1&t=h9fc3t41&s=97dd1735478f260cf20c9948ddfa4262d7a781dd |
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