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(E)-N '-(2,4-Dihydroxybenzylidene)-4-nitrobenzohydrazide

The title compound, C14H11N3O5, is essentially planar, with an r.m.s. deviation for the non-H atoms of 0.0832 (3) angstrom. In the crystal, O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds link adjacent molecules into layers parallel to (101). These la...

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Main Authors: Lair, N.M., Ali, Hapipah Mohd, Khaledi, H.
Format: Article
Language:English
Published: International Union of Crystallography 2011
Subjects:
QD Chemistry
Online Access:http://eprints.um.edu.my/5214/1/Lair-2011-%28E%29-N_%27-%282%2C4-Dihydro.pdf
http://eprints.um.edu.my/5214/
http://scripts.iucr.org/cgi-bin/paper?S1600536811002224
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spelling my.um.eprints.52142019-01-30T00:45:27Z http://eprints.um.edu.my/5214/ (E)-N '-(2,4-Dihydroxybenzylidene)-4-nitrobenzohydrazide Lair, N.M. Ali, Hapipah Mohd Khaledi, H. QD Chemistry The title compound, C14H11N3O5, is essentially planar, with an r.m.s. deviation for the non-H atoms of 0.0832 (3) angstrom. In the crystal, O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds link adjacent molecules into layers parallel to (101). These layers are further connected into a three-dimensional network via C-H center dot center dot center dot O interactions. In addition, a pi-pi interaction occurs between the aromatic rings [centroid-centroid distance = 3.5425 (8) angstrom]. An intramolecular O-H center dot center dot center dot N hydrogen bond is also observed. International Union of Crystallography 2011 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5214/1/Lair-2011-%28E%29-N_%27-%282%2C4-Dihydro.pdf Lair, N.M. and Ali, Hapipah Mohd and Khaledi, H. (2011) (E)-N '-(2,4-Dihydroxybenzylidene)-4-nitrobenzohydrazide. Acta Crystallographica Section E: Structure Reports Online, 67. O459-U1447. ISSN 1600-5368 http://scripts.iucr.org/cgi-bin/paper?S1600536811002224 10.1107/s1600536811002224
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
language English
topic QD Chemistry
spellingShingle QD Chemistry
Lair, N.M.
Ali, Hapipah Mohd
Khaledi, H.
(E)-N '-(2,4-Dihydroxybenzylidene)-4-nitrobenzohydrazide
description The title compound, C14H11N3O5, is essentially planar, with an r.m.s. deviation for the non-H atoms of 0.0832 (3) angstrom. In the crystal, O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds link adjacent molecules into layers parallel to (101). These layers are further connected into a three-dimensional network via C-H center dot center dot center dot O interactions. In addition, a pi-pi interaction occurs between the aromatic rings [centroid-centroid distance = 3.5425 (8) angstrom]. An intramolecular O-H center dot center dot center dot N hydrogen bond is also observed.
format Article
author Lair, N.M.
Ali, Hapipah Mohd
Khaledi, H.
author_facet Lair, N.M.
Ali, Hapipah Mohd
Khaledi, H.
author_sort Lair, N.M.
title (E)-N '-(2,4-Dihydroxybenzylidene)-4-nitrobenzohydrazide
title_short (E)-N '-(2,4-Dihydroxybenzylidene)-4-nitrobenzohydrazide
title_full (E)-N '-(2,4-Dihydroxybenzylidene)-4-nitrobenzohydrazide
title_fullStr (E)-N '-(2,4-Dihydroxybenzylidene)-4-nitrobenzohydrazide
title_full_unstemmed (E)-N '-(2,4-Dihydroxybenzylidene)-4-nitrobenzohydrazide
title_sort (e)-n '-(2,4-dihydroxybenzylidene)-4-nitrobenzohydrazide
publisher International Union of Crystallography
publishDate 2011
url http://eprints.um.edu.my/5214/1/Lair-2011-%28E%29-N_%27-%282%2C4-Dihydro.pdf
http://eprints.um.edu.my/5214/
http://scripts.iucr.org/cgi-bin/paper?S1600536811002224
_version_ 1643687516336816128
score 13.211869

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