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Facile synthesis of mordenite zeolites from bamboo leaves ash for acetalization of benzaldehye and glycerol using non-microwave instant heating

Backgrounds: Bamboo leaves ash (BLA) is a cheap and sustainable silica source but under-utilized. In this work, mordenite zeolites with various morphologies synthesized from BLA are reported. Methodology: Our strategy involves merely mixing of silicate and aluminate solutions where parametric crysta...

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Main Authors: Gong, Jiang-Tian, AlMasoud, Najla, Alomar, Taghrid S., Maireles-Torres, Pedro, El-Bahy, Zeinhom M., Juan, Joon Ching, Ling, Tau Chuan, Ng, Eng-Poh
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Published: Elsevier 2024
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TP Chemical technology
Online Access:http://eprints.um.edu.my/45174/
https://doi.org/10.1016/j.jtice.2024.105507
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spelling my.um.eprints.451742024-09-20T05:04:48Z http://eprints.um.edu.my/45174/ Facile synthesis of mordenite zeolites from bamboo leaves ash for acetalization of benzaldehye and glycerol using non-microwave instant heating Gong, Jiang-Tian AlMasoud, Najla Alomar, Taghrid S. Maireles-Torres, Pedro El-Bahy, Zeinhom M. Juan, Joon Ching Ling, Tau Chuan Ng, Eng-Poh TP Chemical technology Backgrounds: Bamboo leaves ash (BLA) is a cheap and sustainable silica source but under-utilized. In this work, mordenite zeolites with various morphologies synthesized from BLA are reported. Methodology: Our strategy involves merely mixing of silicate and aluminate solutions where parametric crystallization study successfully captured three mordenite synthesis recipes. The prepared solids are then characterized with XRD, SEM, XRF, FTIR, TGA/DTG, N-2 sorption and TPD-NH3 before their catalytic behavior is tested in acetalization . Significant findings: Mordenites with three distinct shapes (nanostick, intergrown bulky ball, nanorod) are successfully synthesized via parametric crystallization study. Some mordenite zeolites contain hierarchical micro/mesoporosity which is beneficial in acetalization of benzaldehye and glycerol. The nanorod-like mordenite is the best catalyst (80.2 +/- 2.4 % conversion, 54.4 +/- 0.3 % selective towards 2-benzyl-4-hydroxymethyl-1,3-dioxolane) and its catalytic performance is better than those of classical homogeneous and zeolite catalysts with high recyclability. Elsevier 2024-06 Article PeerReviewed Gong, Jiang-Tian and AlMasoud, Najla and Alomar, Taghrid S. and Maireles-Torres, Pedro and El-Bahy, Zeinhom M. and Juan, Joon Ching and Ling, Tau Chuan and Ng, Eng-Poh (2024) Facile synthesis of mordenite zeolites from bamboo leaves ash for acetalization of benzaldehye and glycerol using non-microwave instant heating. Journal of the Taiwan Institute of Chemical Engineers, 159. p. 105507. ISSN 1876-1070, DOI https://doi.org/10.1016/j.jtice.2024.105507 <https://doi.org/10.1016/j.jtice.2024.105507>. https://doi.org/10.1016/j.jtice.2024.105507 10.1016/j.jtice.2024.105507
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic TP Chemical technology
spellingShingle TP Chemical technology
Gong, Jiang-Tian
AlMasoud, Najla
Alomar, Taghrid S.
Maireles-Torres, Pedro
El-Bahy, Zeinhom M.
Juan, Joon Ching
Ling, Tau Chuan
Ng, Eng-Poh
Facile synthesis of mordenite zeolites from bamboo leaves ash for acetalization of benzaldehye and glycerol using non-microwave instant heating
description Backgrounds: Bamboo leaves ash (BLA) is a cheap and sustainable silica source but under-utilized. In this work, mordenite zeolites with various morphologies synthesized from BLA are reported. Methodology: Our strategy involves merely mixing of silicate and aluminate solutions where parametric crystallization study successfully captured three mordenite synthesis recipes. The prepared solids are then characterized with XRD, SEM, XRF, FTIR, TGA/DTG, N-2 sorption and TPD-NH3 before their catalytic behavior is tested in acetalization . Significant findings: Mordenites with three distinct shapes (nanostick, intergrown bulky ball, nanorod) are successfully synthesized via parametric crystallization study. Some mordenite zeolites contain hierarchical micro/mesoporosity which is beneficial in acetalization of benzaldehye and glycerol. The nanorod-like mordenite is the best catalyst (80.2 +/- 2.4 % conversion, 54.4 +/- 0.3 % selective towards 2-benzyl-4-hydroxymethyl-1,3-dioxolane) and its catalytic performance is better than those of classical homogeneous and zeolite catalysts with high recyclability.
format Article
author Gong, Jiang-Tian
AlMasoud, Najla
Alomar, Taghrid S.
Maireles-Torres, Pedro
El-Bahy, Zeinhom M.
Juan, Joon Ching
Ling, Tau Chuan
Ng, Eng-Poh
author_facet Gong, Jiang-Tian
AlMasoud, Najla
Alomar, Taghrid S.
Maireles-Torres, Pedro
El-Bahy, Zeinhom M.
Juan, Joon Ching
Ling, Tau Chuan
Ng, Eng-Poh
author_sort Gong, Jiang-Tian
title Facile synthesis of mordenite zeolites from bamboo leaves ash for acetalization of benzaldehye and glycerol using non-microwave instant heating
title_short Facile synthesis of mordenite zeolites from bamboo leaves ash for acetalization of benzaldehye and glycerol using non-microwave instant heating
title_full Facile synthesis of mordenite zeolites from bamboo leaves ash for acetalization of benzaldehye and glycerol using non-microwave instant heating
title_fullStr Facile synthesis of mordenite zeolites from bamboo leaves ash for acetalization of benzaldehye and glycerol using non-microwave instant heating
title_full_unstemmed Facile synthesis of mordenite zeolites from bamboo leaves ash for acetalization of benzaldehye and glycerol using non-microwave instant heating
title_sort facile synthesis of mordenite zeolites from bamboo leaves ash for acetalization of benzaldehye and glycerol using non-microwave instant heating
publisher Elsevier
publishDate 2024
url http://eprints.um.edu.my/45174/
https://doi.org/10.1016/j.jtice.2024.105507
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score 13.211869

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