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Hybrid emulsifier systems: Alkyl imidazolium lactoside surfactants derived from natural resources

A new series of hybrid surfactants comprising an imidazolium as a cation and a disaccharide as a non-ion were synthesized, and their aggregation behavior was also investigated. The synthetic approach used alkylation as an easily accessible route on an imidazole to attempt an economic production foll...

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Main Author: Salman, Abbas Abdulameer
Format: Article
Published: Elsevier 2022
Subjects:
QD Chemistry
Online Access:http://eprints.um.edu.my/41608/
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spelling my.um.eprints.416082023-11-08T03:43:18Z http://eprints.um.edu.my/41608/ Hybrid emulsifier systems: Alkyl imidazolium lactoside surfactants derived from natural resources Salman, Abbas Abdulameer QD Chemistry A new series of hybrid surfactants comprising an imidazolium as a cation and a disaccharide as a non-ion were synthesized, and their aggregation behavior was also investigated. The synthetic approach used alkylation as an easily accessible route on an imidazole to attempt an economic production followed by coupling with bromoethyl lactoside to form lacto-imidazolium salts surfactants. The coupled surfactants were obtained in almost quantitative yield over several steps. The surfactant surface properties in aqueous media were investigated, including critical micelle concentration (CMC), Krafft temperature, and emulsion stability were studied. The CMC measurements of the alkyl imidazolium lactoside surfactants are significantly lower than normal imidazolium surfactants, while the emulsion investigations encourage the use of alkyl imidazolium lactoside surfactants owing to stabilized assemble behavior as good as APGs. Elsevier 2022-10 Article PeerReviewed Salman, Abbas Abdulameer (2022) Hybrid emulsifier systems: Alkyl imidazolium lactoside surfactants derived from natural resources. Carbohydrate Research, 520. ISSN 0008-6215, DOI https://doi.org/10.1016/j.carres.2022.108634 <https://doi.org/10.1016/j.carres.2022.108634>. 10.1016/j.carres.2022.108634
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic QD Chemistry
spellingShingle QD Chemistry
Salman, Abbas Abdulameer
Hybrid emulsifier systems: Alkyl imidazolium lactoside surfactants derived from natural resources
description A new series of hybrid surfactants comprising an imidazolium as a cation and a disaccharide as a non-ion were synthesized, and their aggregation behavior was also investigated. The synthetic approach used alkylation as an easily accessible route on an imidazole to attempt an economic production followed by coupling with bromoethyl lactoside to form lacto-imidazolium salts surfactants. The coupled surfactants were obtained in almost quantitative yield over several steps. The surfactant surface properties in aqueous media were investigated, including critical micelle concentration (CMC), Krafft temperature, and emulsion stability were studied. The CMC measurements of the alkyl imidazolium lactoside surfactants are significantly lower than normal imidazolium surfactants, while the emulsion investigations encourage the use of alkyl imidazolium lactoside surfactants owing to stabilized assemble behavior as good as APGs.
format Article
author Salman, Abbas Abdulameer
author_facet Salman, Abbas Abdulameer
author_sort Salman, Abbas Abdulameer
title Hybrid emulsifier systems: Alkyl imidazolium lactoside surfactants derived from natural resources
title_short Hybrid emulsifier systems: Alkyl imidazolium lactoside surfactants derived from natural resources
title_full Hybrid emulsifier systems: Alkyl imidazolium lactoside surfactants derived from natural resources
title_fullStr Hybrid emulsifier systems: Alkyl imidazolium lactoside surfactants derived from natural resources
title_full_unstemmed Hybrid emulsifier systems: Alkyl imidazolium lactoside surfactants derived from natural resources
title_sort hybrid emulsifier systems: alkyl imidazolium lactoside surfactants derived from natural resources
publisher Elsevier
publishDate 2022
url http://eprints.um.edu.my/41608/
_version_ 1783876727827595264
score 13.211869

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