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Additive Manufacturing polyurethane acrylate via stereolithography for 3D structure polymer electrolyte application

Additive manufacturing (AM), also known as 3D-printing technology, is currently integrated in many fields as it possesses an attractive fabrication process. In this work, we deployed the 3D-print stereolithography (SLA) method to print polyurethane acrylate (PUA)-based gel polymer electrolyte (GPE)....

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Main Authors: Norjeli, Muhammad Faishal, Tamchek, Nizam, Osman, Zurina, Noor, Ikhwan Syafiq Mohd, Kufian, Mohd Zieauddin, Ghazali, Mohd Ifwat Bin Mohd
Format: Article
Published: MDPI 2022
Subjects:
QC Physics
Online Access:http://eprints.um.edu.my/41148/
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spelling my.um.eprints.411482023-09-08T04:10:05Z http://eprints.um.edu.my/41148/ Additive Manufacturing polyurethane acrylate via stereolithography for 3D structure polymer electrolyte application Norjeli, Muhammad Faishal Tamchek, Nizam Osman, Zurina Noor, Ikhwan Syafiq Mohd Kufian, Mohd Zieauddin Ghazali, Mohd Ifwat Bin Mohd QC Physics Additive manufacturing (AM), also known as 3D-printing technology, is currently integrated in many fields as it possesses an attractive fabrication process. In this work, we deployed the 3D-print stereolithography (SLA) method to print polyurethane acrylate (PUA)-based gel polymer electrolyte (GPE). The printed PUA GPE was then characterized through several techniques, such as Fourier transform infrared (FTIR), electrochemical impedance spectroscopy (EIS), X-ray diffraction analysis (XRD), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and scanning electron microscope (SEM). The printed GPE exhibited high ionic conductivity of 1.24 x 10(-3) S cm(-1) at low-lithium-salt content (10 wt.%) in ambient temperature and favorable thermal stability to about 300 degrees C. The FTIR results show that addition of LiClO4 to the polymer matrix caused a shift in carbonyl, ester and amide functional groups. In addition, FTIR deconvolution peaks of LiClO4 show 10 wt.% has the highest amount of free ions, in line with the highest conductivity achieved. Finally, the PUA GPE was printed into 3D complex structure to show SLA flexibility in designing an electrolyte, which could be a potential application in advanced battery fabrication. MDPI 2022-09 Article PeerReviewed Norjeli, Muhammad Faishal and Tamchek, Nizam and Osman, Zurina and Noor, Ikhwan Syafiq Mohd and Kufian, Mohd Zieauddin and Ghazali, Mohd Ifwat Bin Mohd (2022) Additive Manufacturing polyurethane acrylate via stereolithography for 3D structure polymer electrolyte application. Gels, 8 (9). ISSN 2310-2861, DOI https://doi.org/10.3390/gels8090589 <https://doi.org/10.3390/gels8090589>. 10.3390/gels8090589
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic QC Physics
spellingShingle QC Physics
Norjeli, Muhammad Faishal
Tamchek, Nizam
Osman, Zurina
Noor, Ikhwan Syafiq Mohd
Kufian, Mohd Zieauddin
Ghazali, Mohd Ifwat Bin Mohd
Additive Manufacturing polyurethane acrylate via stereolithography for 3D structure polymer electrolyte application
description Additive manufacturing (AM), also known as 3D-printing technology, is currently integrated in many fields as it possesses an attractive fabrication process. In this work, we deployed the 3D-print stereolithography (SLA) method to print polyurethane acrylate (PUA)-based gel polymer electrolyte (GPE). The printed PUA GPE was then characterized through several techniques, such as Fourier transform infrared (FTIR), electrochemical impedance spectroscopy (EIS), X-ray diffraction analysis (XRD), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and scanning electron microscope (SEM). The printed GPE exhibited high ionic conductivity of 1.24 x 10(-3) S cm(-1) at low-lithium-salt content (10 wt.%) in ambient temperature and favorable thermal stability to about 300 degrees C. The FTIR results show that addition of LiClO4 to the polymer matrix caused a shift in carbonyl, ester and amide functional groups. In addition, FTIR deconvolution peaks of LiClO4 show 10 wt.% has the highest amount of free ions, in line with the highest conductivity achieved. Finally, the PUA GPE was printed into 3D complex structure to show SLA flexibility in designing an electrolyte, which could be a potential application in advanced battery fabrication.
format Article
author Norjeli, Muhammad Faishal
Tamchek, Nizam
Osman, Zurina
Noor, Ikhwan Syafiq Mohd
Kufian, Mohd Zieauddin
Ghazali, Mohd Ifwat Bin Mohd
author_facet Norjeli, Muhammad Faishal
Tamchek, Nizam
Osman, Zurina
Noor, Ikhwan Syafiq Mohd
Kufian, Mohd Zieauddin
Ghazali, Mohd Ifwat Bin Mohd
author_sort Norjeli, Muhammad Faishal
title Additive Manufacturing polyurethane acrylate via stereolithography for 3D structure polymer electrolyte application
title_short Additive Manufacturing polyurethane acrylate via stereolithography for 3D structure polymer electrolyte application
title_full Additive Manufacturing polyurethane acrylate via stereolithography for 3D structure polymer electrolyte application
title_fullStr Additive Manufacturing polyurethane acrylate via stereolithography for 3D structure polymer electrolyte application
title_full_unstemmed Additive Manufacturing polyurethane acrylate via stereolithography for 3D structure polymer electrolyte application
title_sort additive manufacturing polyurethane acrylate via stereolithography for 3d structure polymer electrolyte application
publisher MDPI
publishDate 2022
url http://eprints.um.edu.my/41148/
_version_ 1778161632539574272
score 13.211869

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