Cover Image

Alternative route for biodiesel synthesis with co-production of Glycerol carbonate

As an alternative route from the conventional alkali-catalyzed biodiesel production, the supercritical dimethyl carbonate method had been proven to successfully produce biodiesel with the co-production of glycerol carbonate in a one-step and two-step non-catalytic methods. Biodiesel or fatty acid me...

Full description

Saved in:
Bibliographic Details
Main Authors: Ilham, Zul, Saka, Shiro
Format: Conference or Workshop Item
Published: 2021
Subjects:
QC Physics
QH301 Biology
Online Access:http://eprints.um.edu.my/36052/
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85123676478&doi=10.1088%2f1742-6596%2f2129%2f1%2f012063&partnerID=40&md5=f4a00213d61bdda49a4dd82eac2f0245
Tags: Add Tag
No Tags, Be the first to tag this record!
id my.um.eprints.36052
record_format eprints
spelling my.um.eprints.360522024-07-14T23:51:37Z http://eprints.um.edu.my/36052/ Alternative route for biodiesel synthesis with co-production of Glycerol carbonate Ilham, Zul Saka, Shiro QC Physics QH301 Biology As an alternative route from the conventional alkali-catalyzed biodiesel production, the supercritical dimethyl carbonate method had been proven to successfully produce biodiesel with the co-production of glycerol carbonate in a one-step and two-step non-catalytic methods. Biodiesel or fatty acid methyl esters (FAME) obtained were high in yield, comparable with supercritical methanol method and satisfy the international standards for use as biodiesel in engines. In this paper, key parameters for the processes such as reaction temperature, pressure, time, molar ratio of dimethyl carbonate to oil, the FAME yield, thermal decomposition, degree of denaturation, tocopherol content, oxidation stability and fuel properties were discussed. The optimized condition for supercritical dimethyl carbonate method is at 300ºC/20MPa/20min/42:1 molar ratio of dimethyl carbonate to oil with a satisfactory yield of FAME at 97.4wt. The extensive approach in this study is very important to complement mathematical model for optimization in the literatures, and to ensure that only high-quality biodiesel could be produced by supercritical dimethyl carbonate method under an optimized condition. © 2021 Institute of Physics Publishing. All rights reserved. 2021 Conference or Workshop Item PeerReviewed Ilham, Zul and Saka, Shiro (2021) Alternative route for biodiesel synthesis with co-production of Glycerol carbonate. In: 1st International Conference on Material Processing and Technology, ICMProTech 2021, 14-15 July 2021, Perlis, Virtual. https://www.scopus.com/inward/record.uri?eid=2-s2.0-85123676478&doi=10.1088%2f1742-6596%2f2129%2f1%2f012063&partnerID=40&md5=f4a00213d61bdda49a4dd82eac2f0245
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic QC Physics
QH301 Biology
spellingShingle QC Physics
QH301 Biology
Ilham, Zul
Saka, Shiro
Alternative route for biodiesel synthesis with co-production of Glycerol carbonate
description As an alternative route from the conventional alkali-catalyzed biodiesel production, the supercritical dimethyl carbonate method had been proven to successfully produce biodiesel with the co-production of glycerol carbonate in a one-step and two-step non-catalytic methods. Biodiesel or fatty acid methyl esters (FAME) obtained were high in yield, comparable with supercritical methanol method and satisfy the international standards for use as biodiesel in engines. In this paper, key parameters for the processes such as reaction temperature, pressure, time, molar ratio of dimethyl carbonate to oil, the FAME yield, thermal decomposition, degree of denaturation, tocopherol content, oxidation stability and fuel properties were discussed. The optimized condition for supercritical dimethyl carbonate method is at 300ºC/20MPa/20min/42:1 molar ratio of dimethyl carbonate to oil with a satisfactory yield of FAME at 97.4wt. The extensive approach in this study is very important to complement mathematical model for optimization in the literatures, and to ensure that only high-quality biodiesel could be produced by supercritical dimethyl carbonate method under an optimized condition. © 2021 Institute of Physics Publishing. All rights reserved.
format Conference or Workshop Item
author Ilham, Zul
Saka, Shiro
author_facet Ilham, Zul
Saka, Shiro
author_sort Ilham, Zul
title Alternative route for biodiesel synthesis with co-production of Glycerol carbonate
title_short Alternative route for biodiesel synthesis with co-production of Glycerol carbonate
title_full Alternative route for biodiesel synthesis with co-production of Glycerol carbonate
title_fullStr Alternative route for biodiesel synthesis with co-production of Glycerol carbonate
title_full_unstemmed Alternative route for biodiesel synthesis with co-production of Glycerol carbonate
title_sort alternative route for biodiesel synthesis with co-production of glycerol carbonate
publishDate 2021
url http://eprints.um.edu.my/36052/
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85123676478&doi=10.1088%2f1742-6596%2f2129%2f1%2f012063&partnerID=40&md5=f4a00213d61bdda49a4dd82eac2f0245
_version_ 1805881094422134784
score 13.211869

Similar Items