Optimization of a high-performance poly(diallyl dimethylammonium chloride)-alumina-perfluorooctanoate intercalated ultrafiltration membrane for treating emulsified oily wastewater via response surface methodology approach

This research aimed to investigate the ultrafiltration of water from emulsified oily wastewater through the application of surface-functionalized ceramic membrane to enhance its water permeability based on optimized parameters using a cross-flow filtration system. The interactive effects of feed con...

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Main Authors: Raji, Yusuf Olabode, Othman, Mohd Hafiz Dzarfan, Nordin, Nik Abdul Hadi Sapiaa Md, Adam, Mohd Ridhwan, Said, Khairul Anwar Mohamad, Abdulyekeen, Kabir Abogunde, Ismail, Ahmad Fauzi, Rahman, Mukhlis A., Jaafar, Juhana, Abu Bakar, Suriani
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Published: MDPI 2021
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Online Access:http://eprints.um.edu.my/34379/
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spelling my.um.eprints.343792022-09-13T02:09:28Z http://eprints.um.edu.my/34379/ Optimization of a high-performance poly(diallyl dimethylammonium chloride)-alumina-perfluorooctanoate intercalated ultrafiltration membrane for treating emulsified oily wastewater via response surface methodology approach Raji, Yusuf Olabode Othman, Mohd Hafiz Dzarfan Nordin, Nik Abdul Hadi Sapiaa Md Adam, Mohd Ridhwan Said, Khairul Anwar Mohamad Abdulyekeen, Kabir Abogunde Ismail, Ahmad Fauzi Rahman, Mukhlis A. Jaafar, Juhana Abu Bakar, Suriani QC Physics QD Chemistry TP Chemical technology This research aimed to investigate the ultrafiltration of water from emulsified oily wastewater through the application of surface-functionalized ceramic membrane to enhance its water permeability based on optimized parameters using a cross-flow filtration system. The interactive effects of feed concentration (10-1000 ppm), pH (4-10), and pressure (0-3 bar) on the water flux and oil rejection were investigated. Central composite design (CCD) from response surface methodology (RSM) was employed for statistical analysis, modeling, and optimization of operating conditions. The analysis of variance (ANOVA) results showed that the oil rejection and water flux models were significant with p-values of 0.0001 and 0.0075, respectively. In addition, good correlation coefficients of 0.997 and 0.863 were obtained for the oil rejection and water flux models, respectively. The optimum conditions for pressure, pH, and feed concentration were found to be 1.5 bar, pH 8.97, and 10 ppm, respectively with water flux and oil rejection maintained at 152 L/m(2)center dot h and 98.72%, respectively. Hence, the functionalized ultrafiltration ceramic membrane enables the separation efficiency of the emulsified oil in water to be achieved. MDPI 2021-12 Article PeerReviewed Raji, Yusuf Olabode and Othman, Mohd Hafiz Dzarfan and Nordin, Nik Abdul Hadi Sapiaa Md and Adam, Mohd Ridhwan and Said, Khairul Anwar Mohamad and Abdulyekeen, Kabir Abogunde and Ismail, Ahmad Fauzi and Rahman, Mukhlis A. and Jaafar, Juhana and Abu Bakar, Suriani (2021) Optimization of a high-performance poly(diallyl dimethylammonium chloride)-alumina-perfluorooctanoate intercalated ultrafiltration membrane for treating emulsified oily wastewater via response surface methodology approach. Membranes, 11 (12). ISSN 2077-0375, DOI https://doi.org/10.3390/membranes11120956 <https://doi.org/10.3390/membranes11120956>. 10.3390/membranes11120956
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic QC Physics
QD Chemistry
TP Chemical technology
spellingShingle QC Physics
QD Chemistry
TP Chemical technology
Raji, Yusuf Olabode
Othman, Mohd Hafiz Dzarfan
Nordin, Nik Abdul Hadi Sapiaa Md
Adam, Mohd Ridhwan
Said, Khairul Anwar Mohamad
Abdulyekeen, Kabir Abogunde
Ismail, Ahmad Fauzi
Rahman, Mukhlis A.
Jaafar, Juhana
Abu Bakar, Suriani
Optimization of a high-performance poly(diallyl dimethylammonium chloride)-alumina-perfluorooctanoate intercalated ultrafiltration membrane for treating emulsified oily wastewater via response surface methodology approach
description This research aimed to investigate the ultrafiltration of water from emulsified oily wastewater through the application of surface-functionalized ceramic membrane to enhance its water permeability based on optimized parameters using a cross-flow filtration system. The interactive effects of feed concentration (10-1000 ppm), pH (4-10), and pressure (0-3 bar) on the water flux and oil rejection were investigated. Central composite design (CCD) from response surface methodology (RSM) was employed for statistical analysis, modeling, and optimization of operating conditions. The analysis of variance (ANOVA) results showed that the oil rejection and water flux models were significant with p-values of 0.0001 and 0.0075, respectively. In addition, good correlation coefficients of 0.997 and 0.863 were obtained for the oil rejection and water flux models, respectively. The optimum conditions for pressure, pH, and feed concentration were found to be 1.5 bar, pH 8.97, and 10 ppm, respectively with water flux and oil rejection maintained at 152 L/m(2)center dot h and 98.72%, respectively. Hence, the functionalized ultrafiltration ceramic membrane enables the separation efficiency of the emulsified oil in water to be achieved.
format Article
author Raji, Yusuf Olabode
Othman, Mohd Hafiz Dzarfan
Nordin, Nik Abdul Hadi Sapiaa Md
Adam, Mohd Ridhwan
Said, Khairul Anwar Mohamad
Abdulyekeen, Kabir Abogunde
Ismail, Ahmad Fauzi
Rahman, Mukhlis A.
Jaafar, Juhana
Abu Bakar, Suriani
author_facet Raji, Yusuf Olabode
Othman, Mohd Hafiz Dzarfan
Nordin, Nik Abdul Hadi Sapiaa Md
Adam, Mohd Ridhwan
Said, Khairul Anwar Mohamad
Abdulyekeen, Kabir Abogunde
Ismail, Ahmad Fauzi
Rahman, Mukhlis A.
Jaafar, Juhana
Abu Bakar, Suriani
author_sort Raji, Yusuf Olabode
title Optimization of a high-performance poly(diallyl dimethylammonium chloride)-alumina-perfluorooctanoate intercalated ultrafiltration membrane for treating emulsified oily wastewater via response surface methodology approach
title_short Optimization of a high-performance poly(diallyl dimethylammonium chloride)-alumina-perfluorooctanoate intercalated ultrafiltration membrane for treating emulsified oily wastewater via response surface methodology approach
title_full Optimization of a high-performance poly(diallyl dimethylammonium chloride)-alumina-perfluorooctanoate intercalated ultrafiltration membrane for treating emulsified oily wastewater via response surface methodology approach
title_fullStr Optimization of a high-performance poly(diallyl dimethylammonium chloride)-alumina-perfluorooctanoate intercalated ultrafiltration membrane for treating emulsified oily wastewater via response surface methodology approach
title_full_unstemmed Optimization of a high-performance poly(diallyl dimethylammonium chloride)-alumina-perfluorooctanoate intercalated ultrafiltration membrane for treating emulsified oily wastewater via response surface methodology approach
title_sort optimization of a high-performance poly(diallyl dimethylammonium chloride)-alumina-perfluorooctanoate intercalated ultrafiltration membrane for treating emulsified oily wastewater via response surface methodology approach
publisher MDPI
publishDate 2021
url http://eprints.um.edu.my/34379/
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score 13.223943