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Sporopollenin supported methylimidazolium ionic liquids based mixed matrix membrane for dispersive membrane micro-extraction of nitro and chloro-substituted phenols from various matrices

The focal point of this study is on the development of sporopollenin supported methylimidazolium ionic liquids (Sp-MIM) based mixed matrix membrane (Sp-MIM-MMM) for simultaneous dispersive membrane microextraction (DMME) of nitro- and chloro-substituted phenols from various matrixes followed by dete...

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Main Authors: Chandrasekaram, Kumuthini, Alias, Yatimah, Mohamad, Sharifah
Format: Article
Published: Elsevier 2022
Subjects:
QD Chemistry
Online Access:http://eprints.um.edu.my/33713/
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spelling my.um.eprints.337132022-07-19T10:42:44Z http://eprints.um.edu.my/33713/ Sporopollenin supported methylimidazolium ionic liquids based mixed matrix membrane for dispersive membrane micro-extraction of nitro and chloro-substituted phenols from various matrices Chandrasekaram, Kumuthini Alias, Yatimah Mohamad, Sharifah QD Chemistry The focal point of this study is on the development of sporopollenin supported methylimidazolium ionic liquids (Sp-MIM) based mixed matrix membrane (Sp-MIM-MMM) for simultaneous dispersive membrane microextraction (DMME) of nitro- and chloro-substituted phenols from various matrixes followed by determination using high performance liquid chromatography (HPLC). The Sp-MIM particle phase was incorporated through dispersion onto cellulose triacetate polymer matrix to form Sp-MIM-MMM. Several main variables influencing the Sp-MIM-MMM based DMME efficiency were investigated and optimized in detail, such as polymer phase mass, particle phase loading, number of Sp-MIM-MMM spheres per extraction, solution pH, extraction time, extraction volume, type of desorption solvent, desorption solvent volume, and desorption time. Method validation recorded notable repeatability and reproducibility performance with observed linearity 50-500 ng/mL, the calculated linear regression (R2) was 0.9994-0.9997, relative standard deviation (RSD) was 0.2-0.8%, the limit of detection (LOD) was 0.03-0.06 ng/mL, the limit of quantification (LOQ) was 0.11-0.19 ng/mL while the recovery was 99-119% for all phenol analytes analyzed. Targeted selectivity and sensitivity of the Sp-MIM-MMM towards the phenol analytes were evident in the various sample matrix tested with quantified detection calculated at 14.4-154.7 ng/mL for liquid based-real samples and 17.4-34.4 mu g/kg for solid based-real samples. SpMIM-MMM too exhibited noteworthy reusability up to 10 cycles, signifying a new venture towards environmentally sustainable technology. Elsevier 2022-01 Article PeerReviewed Chandrasekaram, Kumuthini and Alias, Yatimah and Mohamad, Sharifah (2022) Sporopollenin supported methylimidazolium ionic liquids based mixed matrix membrane for dispersive membrane micro-extraction of nitro and chloro-substituted phenols from various matrices. Microchemical Journal, 172 (B). ISSN 0026-265X, DOI https://doi.org/10.1016/j.microc.2021.106936 <https://doi.org/10.1016/j.microc.2021.106936>. 10.1016/j.microc.2021.106936
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic QD Chemistry
spellingShingle QD Chemistry
Chandrasekaram, Kumuthini
Alias, Yatimah
Mohamad, Sharifah
Sporopollenin supported methylimidazolium ionic liquids based mixed matrix membrane for dispersive membrane micro-extraction of nitro and chloro-substituted phenols from various matrices
description The focal point of this study is on the development of sporopollenin supported methylimidazolium ionic liquids (Sp-MIM) based mixed matrix membrane (Sp-MIM-MMM) for simultaneous dispersive membrane microextraction (DMME) of nitro- and chloro-substituted phenols from various matrixes followed by determination using high performance liquid chromatography (HPLC). The Sp-MIM particle phase was incorporated through dispersion onto cellulose triacetate polymer matrix to form Sp-MIM-MMM. Several main variables influencing the Sp-MIM-MMM based DMME efficiency were investigated and optimized in detail, such as polymer phase mass, particle phase loading, number of Sp-MIM-MMM spheres per extraction, solution pH, extraction time, extraction volume, type of desorption solvent, desorption solvent volume, and desorption time. Method validation recorded notable repeatability and reproducibility performance with observed linearity 50-500 ng/mL, the calculated linear regression (R2) was 0.9994-0.9997, relative standard deviation (RSD) was 0.2-0.8%, the limit of detection (LOD) was 0.03-0.06 ng/mL, the limit of quantification (LOQ) was 0.11-0.19 ng/mL while the recovery was 99-119% for all phenol analytes analyzed. Targeted selectivity and sensitivity of the Sp-MIM-MMM towards the phenol analytes were evident in the various sample matrix tested with quantified detection calculated at 14.4-154.7 ng/mL for liquid based-real samples and 17.4-34.4 mu g/kg for solid based-real samples. SpMIM-MMM too exhibited noteworthy reusability up to 10 cycles, signifying a new venture towards environmentally sustainable technology.
format Article
author Chandrasekaram, Kumuthini
Alias, Yatimah
Mohamad, Sharifah
author_facet Chandrasekaram, Kumuthini
Alias, Yatimah
Mohamad, Sharifah
author_sort Chandrasekaram, Kumuthini
title Sporopollenin supported methylimidazolium ionic liquids based mixed matrix membrane for dispersive membrane micro-extraction of nitro and chloro-substituted phenols from various matrices
title_short Sporopollenin supported methylimidazolium ionic liquids based mixed matrix membrane for dispersive membrane micro-extraction of nitro and chloro-substituted phenols from various matrices
title_full Sporopollenin supported methylimidazolium ionic liquids based mixed matrix membrane for dispersive membrane micro-extraction of nitro and chloro-substituted phenols from various matrices
title_fullStr Sporopollenin supported methylimidazolium ionic liquids based mixed matrix membrane for dispersive membrane micro-extraction of nitro and chloro-substituted phenols from various matrices
title_full_unstemmed Sporopollenin supported methylimidazolium ionic liquids based mixed matrix membrane for dispersive membrane micro-extraction of nitro and chloro-substituted phenols from various matrices
title_sort sporopollenin supported methylimidazolium ionic liquids based mixed matrix membrane for dispersive membrane micro-extraction of nitro and chloro-substituted phenols from various matrices
publisher Elsevier
publishDate 2022
url http://eprints.um.edu.my/33713/
_version_ 1739828474091143168
score 13.211869

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