Lubricity performance of non-ionic surfactants in high-solid drilling fluids: A perspective from quantum chemical calculations and filtration properties

Quantum chemical calculations and mud filtration analysis were used to assess the performance of three types of non-ionic surfactants as lubricating additives in synthetic-based drilling mud (SBM) contaminated with drilled solids. High solid contaminants can have an impact on mud lubricity and can c...

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Main Authors: Kania, Dina, Yunus, Robiah, Omar, Rozita, Rashid, Suraya Abdul, Jan, Badrul Mohamed, Aulia, Akmal
Format: Article
Published: Elsevier 2021
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Online Access:http://eprints.um.edu.my/28367/
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spelling my.um.eprints.283672022-07-31T14:47:41Z http://eprints.um.edu.my/28367/ Lubricity performance of non-ionic surfactants in high-solid drilling fluids: A perspective from quantum chemical calculations and filtration properties Kania, Dina Yunus, Robiah Omar, Rozita Rashid, Suraya Abdul Jan, Badrul Mohamed Aulia, Akmal T Technology (General) TP Chemical technology Quantum chemical calculations and mud filtration analysis were used to assess the performance of three types of non-ionic surfactants as lubricating additives in synthetic-based drilling mud (SBM) contaminated with drilled solids. High solid contaminants can have an impact on mud lubricity and can contribute to thicker a mud cake. Experimental results showed that all non-ionic surfactants reduced the coefficient of friction (COF) of mud by approximately 27%. Quantum chemical parameters and molecular electrostatic potential (MEP) provided further insights into the interaction between non-ionic surfactants and metal surfaces. MEP indicated the most lubricious non-ionic surfactant based on polar sites and the electron density distribution. Dipole moment represented the dipole interaction between the polar head of non-ionic surfactant with the metal surface of the drilling tools. Filtration tests showed that despite solid contamination, non-ionic surfactants decreased the fluid loss by 20% due to better solid dispersion in the mud. The mud cake formed was thinner, which may reduce the differential pressure sticking tendency. XRD and SEM observations of the mud cake confirmed the presence of non-ionic surfactants layer adsorbed to the solid particles of SBM. The adsorbed non-ionic surfactants could contribute to a higher lubricity of mud cake, thus minimizing friction during drilling. Elsevier 2021-12 Article PeerReviewed Kania, Dina and Yunus, Robiah and Omar, Rozita and Rashid, Suraya Abdul and Jan, Badrul Mohamed and Aulia, Akmal (2021) Lubricity performance of non-ionic surfactants in high-solid drilling fluids: A perspective from quantum chemical calculations and filtration properties. Journal of Petroleum Science and Engineering, 207. ISSN 0920-4105, DOI https://doi.org/10.1016/j.petrol.2021.109162 <https://doi.org/10.1016/j.petrol.2021.109162>. 10.1016/j.petrol.2021.109162
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic T Technology (General)
TP Chemical technology
spellingShingle T Technology (General)
TP Chemical technology
Kania, Dina
Yunus, Robiah
Omar, Rozita
Rashid, Suraya Abdul
Jan, Badrul Mohamed
Aulia, Akmal
Lubricity performance of non-ionic surfactants in high-solid drilling fluids: A perspective from quantum chemical calculations and filtration properties
description Quantum chemical calculations and mud filtration analysis were used to assess the performance of three types of non-ionic surfactants as lubricating additives in synthetic-based drilling mud (SBM) contaminated with drilled solids. High solid contaminants can have an impact on mud lubricity and can contribute to thicker a mud cake. Experimental results showed that all non-ionic surfactants reduced the coefficient of friction (COF) of mud by approximately 27%. Quantum chemical parameters and molecular electrostatic potential (MEP) provided further insights into the interaction between non-ionic surfactants and metal surfaces. MEP indicated the most lubricious non-ionic surfactant based on polar sites and the electron density distribution. Dipole moment represented the dipole interaction between the polar head of non-ionic surfactant with the metal surface of the drilling tools. Filtration tests showed that despite solid contamination, non-ionic surfactants decreased the fluid loss by 20% due to better solid dispersion in the mud. The mud cake formed was thinner, which may reduce the differential pressure sticking tendency. XRD and SEM observations of the mud cake confirmed the presence of non-ionic surfactants layer adsorbed to the solid particles of SBM. The adsorbed non-ionic surfactants could contribute to a higher lubricity of mud cake, thus minimizing friction during drilling.
format Article
author Kania, Dina
Yunus, Robiah
Omar, Rozita
Rashid, Suraya Abdul
Jan, Badrul Mohamed
Aulia, Akmal
author_facet Kania, Dina
Yunus, Robiah
Omar, Rozita
Rashid, Suraya Abdul
Jan, Badrul Mohamed
Aulia, Akmal
author_sort Kania, Dina
title Lubricity performance of non-ionic surfactants in high-solid drilling fluids: A perspective from quantum chemical calculations and filtration properties
title_short Lubricity performance of non-ionic surfactants in high-solid drilling fluids: A perspective from quantum chemical calculations and filtration properties
title_full Lubricity performance of non-ionic surfactants in high-solid drilling fluids: A perspective from quantum chemical calculations and filtration properties
title_fullStr Lubricity performance of non-ionic surfactants in high-solid drilling fluids: A perspective from quantum chemical calculations and filtration properties
title_full_unstemmed Lubricity performance of non-ionic surfactants in high-solid drilling fluids: A perspective from quantum chemical calculations and filtration properties
title_sort lubricity performance of non-ionic surfactants in high-solid drilling fluids: a perspective from quantum chemical calculations and filtration properties
publisher Elsevier
publishDate 2021
url http://eprints.um.edu.my/28367/
_version_ 1740826005506883584
score 13.211869