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Structures that should be Described in Higher-Symmetry, Centrosymmetric Space Groups. Part 2.

The space groups of the transition metal-Schiff base complexes, [ Ni (C5H4NO-2-CH = N-CH2CH2-N = CH-2-C5H4NO) · 2H2O] (ClO4)2 (described in Cc), [Ni(C5H4NO-Z-CH = N-CH(CH3)CH2-N = CH-2-C5H4NO) · 2H2O](ClO4)2 (described in An) and {Cu[(C5H4NO-2-CH = N-N = C(NH2)S] (H2O)}2 (NO3)2 · H2O (described in C...

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Main Authors: Ng, Seik Weng, Hu, Shengzhi
Format: Article
Published: Fujian Institute of Research of the Structure of Matter 2000
Subjects:
Q Science (General)
QD Chemistry
Online Access:http://eprints.um.edu.my/25858/
http://manu30.magtech.com.cn/jghx/EN/volumn/current.shtml
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spelling my.um.eprints.258582021-04-12T02:21:10Z http://eprints.um.edu.my/25858/ Structures that should be Described in Higher-Symmetry, Centrosymmetric Space Groups. Part 2. Ng, Seik Weng Hu, Shengzhi Q Science (General) QD Chemistry The space groups of the transition metal-Schiff base complexes, [ Ni (C5H4NO-2-CH = N-CH2CH2-N = CH-2-C5H4NO) · 2H2O] (ClO4)2 (described in Cc), [Ni(C5H4NO-Z-CH = N-CH(CH3)CH2-N = CH-2-C5H4NO) · 2H2O](ClO4)2 (described in An) and {Cu[(C5H4NO-2-CH = N-N = C(NH2)S] (H2O)}2 (NO3)2 · H2O (described in Cc), have been revised to C2/c. The general descriptions of the first two structures are unchanged in the higher-symmetry setting; for the last structure, the copper atom is re-assigned an octahedral coordination geometry instead of the reported square-pyramidal coordination geometry. The space group of {[CuO2CCH2NHCH2CO2] · (C10H8N2)}2 · 12H2O is similarly revised from P1 to P1. Atomic coordinates for the revised structures are reported. Fujian Institute of Research of the Structure of Matter 2000 Article PeerReviewed Ng, Seik Weng and Hu, Shengzhi (2000) Structures that should be Described in Higher-Symmetry, Centrosymmetric Space Groups. Part 2. Jiegou Huaxue, 19 (6). pp. 411-414. ISSN 0254-5861 http://manu30.magtech.com.cn/jghx/EN/volumn/current.shtml
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
QD Chemistry
spellingShingle Q Science (General)
QD Chemistry
Ng, Seik Weng
Hu, Shengzhi
Structures that should be Described in Higher-Symmetry, Centrosymmetric Space Groups. Part 2.
description The space groups of the transition metal-Schiff base complexes, [ Ni (C5H4NO-2-CH = N-CH2CH2-N = CH-2-C5H4NO) · 2H2O] (ClO4)2 (described in Cc), [Ni(C5H4NO-Z-CH = N-CH(CH3)CH2-N = CH-2-C5H4NO) · 2H2O](ClO4)2 (described in An) and {Cu[(C5H4NO-2-CH = N-N = C(NH2)S] (H2O)}2 (NO3)2 · H2O (described in Cc), have been revised to C2/c. The general descriptions of the first two structures are unchanged in the higher-symmetry setting; for the last structure, the copper atom is re-assigned an octahedral coordination geometry instead of the reported square-pyramidal coordination geometry. The space group of {[CuO2CCH2NHCH2CO2] · (C10H8N2)}2 · 12H2O is similarly revised from P1 to P1. Atomic coordinates for the revised structures are reported.
format Article
author Ng, Seik Weng
Hu, Shengzhi
author_facet Ng, Seik Weng
Hu, Shengzhi
author_sort Ng, Seik Weng
title Structures that should be Described in Higher-Symmetry, Centrosymmetric Space Groups. Part 2.
title_short Structures that should be Described in Higher-Symmetry, Centrosymmetric Space Groups. Part 2.
title_full Structures that should be Described in Higher-Symmetry, Centrosymmetric Space Groups. Part 2.
title_fullStr Structures that should be Described in Higher-Symmetry, Centrosymmetric Space Groups. Part 2.
title_full_unstemmed Structures that should be Described in Higher-Symmetry, Centrosymmetric Space Groups. Part 2.
title_sort structures that should be described in higher-symmetry, centrosymmetric space groups. part 2.
publisher Fujian Institute of Research of the Structure of Matter
publishDate 2000
url http://eprints.um.edu.my/25858/
http://manu30.magtech.com.cn/jghx/EN/volumn/current.shtml
_version_ 1696976592234872832
score 13.211869

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