Investigation on the Electrochemical Performances of Mn2O3 as a Potential Anode for Na-Ion Batteries

Currently, the development of the sodium-ion (Na-ion) batteries as an alternative to lithium-ion batteries has been accelerated to meet the energy demands of large-scale power applications. The difficulty of obtaining suitable electrode materials capable of storing large amount of Na-ion arises from...

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Main Authors: Yusoff, Nor Fazila Mahamad, Idris, Nurul Hayati, Din, Muhamad Faiz Md., Majid, Siti Rohana, Harun, Noor Aniza, Rahman, Md. Mokhlesur
Format: Article
Published: Nature Research 2020
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Online Access:http://eprints.um.edu.my/25732/
https://doi.org/10.1038/s41598-020-66148-w
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spelling my.um.eprints.257322021-02-09T04:49:30Z http://eprints.um.edu.my/25732/ Investigation on the Electrochemical Performances of Mn2O3 as a Potential Anode for Na-Ion Batteries Yusoff, Nor Fazila Mahamad Idris, Nurul Hayati Din, Muhamad Faiz Md. Majid, Siti Rohana Harun, Noor Aniza Rahman, Md. Mokhlesur QC Physics TK Electrical engineering. Electronics Nuclear engineering Currently, the development of the sodium-ion (Na-ion) batteries as an alternative to lithium-ion batteries has been accelerated to meet the energy demands of large-scale power applications. The difficulty of obtaining suitable electrode materials capable of storing large amount of Na-ion arises from the large radius of Na-ion that restricts its reversible capacity. Herein, Mn2O3 powders are synthesised through the thermal conversion of MnCO3 and reported for the first time as an anode for Na-ion batteries. The phase, morphology and charge/discharge characteristics of Mn2O3 obtained are evaluated systematically. The cubic-like Mn2O3 with particle sizes approximately 1.0–1.5 µm coupled with the formation of Mn2O3 sub-units on its surface create a positive effect on the insertion/deinsertion of Na-ion. Mn2O3 delivers a first discharge capacity of 544 mAh g−1 and retains its capacity by 85% after 200 cycles at 100 mA g−1, demonstrating the excellent cyclability of the Mn2O3 electrode. Therefore, this study provides a significant contribution towards exploring the potential of Mn2O3 as a promising anode in the development of Na-ion batteries. © 2020, The Author(s). Nature Research 2020 Article PeerReviewed Yusoff, Nor Fazila Mahamad and Idris, Nurul Hayati and Din, Muhamad Faiz Md. and Majid, Siti Rohana and Harun, Noor Aniza and Rahman, Md. Mokhlesur (2020) Investigation on the Electrochemical Performances of Mn2O3 as a Potential Anode for Na-Ion Batteries. Scientific Reports, 10 (1). p. 9207. ISSN 2045-2322 https://doi.org/10.1038/s41598-020-66148-w doi:10.1038/s41598-020-66148-w
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic QC Physics
TK Electrical engineering. Electronics Nuclear engineering
spellingShingle QC Physics
TK Electrical engineering. Electronics Nuclear engineering
Yusoff, Nor Fazila Mahamad
Idris, Nurul Hayati
Din, Muhamad Faiz Md.
Majid, Siti Rohana
Harun, Noor Aniza
Rahman, Md. Mokhlesur
Investigation on the Electrochemical Performances of Mn2O3 as a Potential Anode for Na-Ion Batteries
description Currently, the development of the sodium-ion (Na-ion) batteries as an alternative to lithium-ion batteries has been accelerated to meet the energy demands of large-scale power applications. The difficulty of obtaining suitable electrode materials capable of storing large amount of Na-ion arises from the large radius of Na-ion that restricts its reversible capacity. Herein, Mn2O3 powders are synthesised through the thermal conversion of MnCO3 and reported for the first time as an anode for Na-ion batteries. The phase, morphology and charge/discharge characteristics of Mn2O3 obtained are evaluated systematically. The cubic-like Mn2O3 with particle sizes approximately 1.0–1.5 µm coupled with the formation of Mn2O3 sub-units on its surface create a positive effect on the insertion/deinsertion of Na-ion. Mn2O3 delivers a first discharge capacity of 544 mAh g−1 and retains its capacity by 85% after 200 cycles at 100 mA g−1, demonstrating the excellent cyclability of the Mn2O3 electrode. Therefore, this study provides a significant contribution towards exploring the potential of Mn2O3 as a promising anode in the development of Na-ion batteries. © 2020, The Author(s).
format Article
author Yusoff, Nor Fazila Mahamad
Idris, Nurul Hayati
Din, Muhamad Faiz Md.
Majid, Siti Rohana
Harun, Noor Aniza
Rahman, Md. Mokhlesur
author_facet Yusoff, Nor Fazila Mahamad
Idris, Nurul Hayati
Din, Muhamad Faiz Md.
Majid, Siti Rohana
Harun, Noor Aniza
Rahman, Md. Mokhlesur
author_sort Yusoff, Nor Fazila Mahamad
title Investigation on the Electrochemical Performances of Mn2O3 as a Potential Anode for Na-Ion Batteries
title_short Investigation on the Electrochemical Performances of Mn2O3 as a Potential Anode for Na-Ion Batteries
title_full Investigation on the Electrochemical Performances of Mn2O3 as a Potential Anode for Na-Ion Batteries
title_fullStr Investigation on the Electrochemical Performances of Mn2O3 as a Potential Anode for Na-Ion Batteries
title_full_unstemmed Investigation on the Electrochemical Performances of Mn2O3 as a Potential Anode for Na-Ion Batteries
title_sort investigation on the electrochemical performances of mn2o3 as a potential anode for na-ion batteries
publisher Nature Research
publishDate 2020
url http://eprints.um.edu.my/25732/
https://doi.org/10.1038/s41598-020-66148-w
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score 13.211869