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Synthesis, single crystal structure determination, and solution behavior of an 8-hydroxyquinoline derivative of niobium(V) ethoxide

An 8-hydroxyquinoline derivative of niobium(V) ethoxide was synthesized and characterized by elemental analysis, mass spectrometry, infrared, electronic, and 1H, 13C, and 93NMR spectroscopies. Tetraethoxy(8-quinolinato)niobium(V), as shown by the single crystal structure determination, exists as an...

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Main Authors: Amini, Mostafa M., Mirzaee, Mehdi, Yaganeh, Farnaze, Khavasi, Hamid Reza, Mirzaei, Peiman, Ng, Seik Weng
Format: Article
Published: Springer 2008
Subjects:
Q Science (General)
QD Chemistry
Online Access:http://eprints.um.edu.my/25492/
https://doi.org/10.1007/s11243-007-9017-z
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spelling my.um.eprints.254922020-09-01T08:07:56Z http://eprints.um.edu.my/25492/ Synthesis, single crystal structure determination, and solution behavior of an 8-hydroxyquinoline derivative of niobium(V) ethoxide Amini, Mostafa M. Mirzaee, Mehdi Yaganeh, Farnaze Khavasi, Hamid Reza Mirzaei, Peiman Ng, Seik Weng Q Science (General) QD Chemistry An 8-hydroxyquinoline derivative of niobium(V) ethoxide was synthesized and characterized by elemental analysis, mass spectrometry, infrared, electronic, and 1H, 13C, and 93NMR spectroscopies. Tetraethoxy(8-quinolinato)niobium(V), as shown by the single crystal structure determination, exists as an octahedral compound in the solid state in which the 8-quinolinato group chelates to the metal atom. In solution, this group partially becomes unidentate; the six-coordinate species is in equilibrium with the five-coordinate species, as shown by 93Nb and variable-temperature 1H NMR spectroscopy. © 2007 Springer Science+Business Media B.V. Springer 2008 Article PeerReviewed Amini, Mostafa M. and Mirzaee, Mehdi and Yaganeh, Farnaze and Khavasi, Hamid Reza and Mirzaei, Peiman and Ng, Seik Weng (2008) Synthesis, single crystal structure determination, and solution behavior of an 8-hydroxyquinoline derivative of niobium(V) ethoxide. Transition Metal Chemistry, 33 (1). pp. 79-83. ISSN 0340-4285 https://doi.org/10.1007/s11243-007-9017-z doi:10.1007/s11243-007-9017-z
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
QD Chemistry
spellingShingle Q Science (General)
QD Chemistry
Amini, Mostafa M.
Mirzaee, Mehdi
Yaganeh, Farnaze
Khavasi, Hamid Reza
Mirzaei, Peiman
Ng, Seik Weng
Synthesis, single crystal structure determination, and solution behavior of an 8-hydroxyquinoline derivative of niobium(V) ethoxide
description An 8-hydroxyquinoline derivative of niobium(V) ethoxide was synthesized and characterized by elemental analysis, mass spectrometry, infrared, electronic, and 1H, 13C, and 93NMR spectroscopies. Tetraethoxy(8-quinolinato)niobium(V), as shown by the single crystal structure determination, exists as an octahedral compound in the solid state in which the 8-quinolinato group chelates to the metal atom. In solution, this group partially becomes unidentate; the six-coordinate species is in equilibrium with the five-coordinate species, as shown by 93Nb and variable-temperature 1H NMR spectroscopy. © 2007 Springer Science+Business Media B.V.
format Article
author Amini, Mostafa M.
Mirzaee, Mehdi
Yaganeh, Farnaze
Khavasi, Hamid Reza
Mirzaei, Peiman
Ng, Seik Weng
author_facet Amini, Mostafa M.
Mirzaee, Mehdi
Yaganeh, Farnaze
Khavasi, Hamid Reza
Mirzaei, Peiman
Ng, Seik Weng
author_sort Amini, Mostafa M.
title Synthesis, single crystal structure determination, and solution behavior of an 8-hydroxyquinoline derivative of niobium(V) ethoxide
title_short Synthesis, single crystal structure determination, and solution behavior of an 8-hydroxyquinoline derivative of niobium(V) ethoxide
title_full Synthesis, single crystal structure determination, and solution behavior of an 8-hydroxyquinoline derivative of niobium(V) ethoxide
title_fullStr Synthesis, single crystal structure determination, and solution behavior of an 8-hydroxyquinoline derivative of niobium(V) ethoxide
title_full_unstemmed Synthesis, single crystal structure determination, and solution behavior of an 8-hydroxyquinoline derivative of niobium(V) ethoxide
title_sort synthesis, single crystal structure determination, and solution behavior of an 8-hydroxyquinoline derivative of niobium(v) ethoxide
publisher Springer
publishDate 2008
url http://eprints.um.edu.my/25492/
https://doi.org/10.1007/s11243-007-9017-z
_version_ 1680857038132871168
score 13.211869

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