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Poly[dimethylammonium [bis(dimethylamine)tri-μ4-terephthalato-sodium(I)dizinc(II)]]

The three terephthalate groups in the title polymeric coordination compound, {(C2H8N)[NaZn2(C8H4O4)3(C2H7N)2]} n , lie on inversion centers. One functions as a bridge to two Na and two Zn atoms. The O atoms of the other two terephthalate groups bind to only one Zn atom. The Zn atom is additionally c...

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Main Authors: Zhu, Li-Na, Gao, Shan, Ng, Seik Weng
Format: Article
Published: International Union of Crystallography 2007
Subjects:
Q Science (General)
QD Chemistry
Online Access:http://eprints.um.edu.my/25299/
https://doi.org/10.1107/S1600536807056243
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spelling my.um.eprints.252992020-08-07T01:58:54Z http://eprints.um.edu.my/25299/ Poly[dimethylammonium [bis(dimethylamine)tri-μ4-terephthalato-sodium(I)dizinc(II)]] Zhu, Li-Na Gao, Shan Ng, Seik Weng Q Science (General) QD Chemistry The three terephthalate groups in the title polymeric coordination compound, {(C2H8N)[NaZn2(C8H4O4)3(C2H7N)2]} n , lie on inversion centers. One functions as a bridge to two Na and two Zn atoms. The O atoms of the other two terephthalate groups bind to only one Zn atom. The Zn atom is additionally coordinated by a dimethyl-amine mol-ecule; together with bonding from the O atoms of the three terephthalate groups, the geometry is tetra-hedral. The manner of bridging of the terephalate groups gives rise to a polyanionic honeycomb sheet motif; the sheets are held into a three-dimensional network through the Na atoms. The cavities in the network are occupied by the dimethyl-ammonium cations. The organic cation is disordered about a centre of inversion. © International Union of Crystallography 2007. International Union of Crystallography 2007 Article PeerReviewed Zhu, Li-Na and Gao, Shan and Ng, Seik Weng (2007) Poly[dimethylammonium [bis(dimethylamine)tri-μ4-terephthalato-sodium(I)dizinc(II)]]. Acta Crystallographica Section E: Structure Reports Online, 63 (12). m2987-m2988. ISSN 1600-5368 https://doi.org/10.1107/S1600536807056243 doi:10.1107/S1600536807056243
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
QD Chemistry
spellingShingle Q Science (General)
QD Chemistry
Zhu, Li-Na
Gao, Shan
Ng, Seik Weng
Poly[dimethylammonium [bis(dimethylamine)tri-μ4-terephthalato-sodium(I)dizinc(II)]]
description The three terephthalate groups in the title polymeric coordination compound, {(C2H8N)[NaZn2(C8H4O4)3(C2H7N)2]} n , lie on inversion centers. One functions as a bridge to two Na and two Zn atoms. The O atoms of the other two terephthalate groups bind to only one Zn atom. The Zn atom is additionally coordinated by a dimethyl-amine mol-ecule; together with bonding from the O atoms of the three terephthalate groups, the geometry is tetra-hedral. The manner of bridging of the terephalate groups gives rise to a polyanionic honeycomb sheet motif; the sheets are held into a three-dimensional network through the Na atoms. The cavities in the network are occupied by the dimethyl-ammonium cations. The organic cation is disordered about a centre of inversion. © International Union of Crystallography 2007.
format Article
author Zhu, Li-Na
Gao, Shan
Ng, Seik Weng
author_facet Zhu, Li-Na
Gao, Shan
Ng, Seik Weng
author_sort Zhu, Li-Na
title Poly[dimethylammonium [bis(dimethylamine)tri-μ4-terephthalato-sodium(I)dizinc(II)]]
title_short Poly[dimethylammonium [bis(dimethylamine)tri-μ4-terephthalato-sodium(I)dizinc(II)]]
title_full Poly[dimethylammonium [bis(dimethylamine)tri-μ4-terephthalato-sodium(I)dizinc(II)]]
title_fullStr Poly[dimethylammonium [bis(dimethylamine)tri-μ4-terephthalato-sodium(I)dizinc(II)]]
title_full_unstemmed Poly[dimethylammonium [bis(dimethylamine)tri-μ4-terephthalato-sodium(I)dizinc(II)]]
title_sort poly[dimethylammonium [bis(dimethylamine)tri-μ4-terephthalato-sodium(i)dizinc(ii)]]
publisher International Union of Crystallography
publishDate 2007
url http://eprints.um.edu.my/25299/
https://doi.org/10.1107/S1600536807056243
_version_ 1680857016760795136
score 13.211869

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