Hydrostannolysis reactions-II. Reaction of phenolic esters with tri-n-butyltin hydride
Reaction of phenyl benzoate with tri-n-butyltin hydride has been found to give mainly toluene, benzyl benzoate, tri-n-butyltin phenoxide and tri-n-butyltin benzoate. Possible reaction paths leading to these products are discussed. A SH2 mechanism involving initial attack of tri-n-butyltin radical at...
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| Main Authors: | , |
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| Format: | Article |
| Published: |
Elsevier
1970
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/24613/ https://doi.org/10.1016/S0040-4020(01)93069-8 |
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| Summary: | Reaction of phenyl benzoate with tri-n-butyltin hydride has been found to give mainly toluene, benzyl benzoate, tri-n-butyltin phenoxide and tri-n-butyltin benzoate. Possible reaction paths leading to these products are discussed. A SH2 mechanism involving initial attack of tri-n-butyltin radical at the ethereal oxygen atom of the ester with displacement of the benzoyl moiety appears to be consistent with observed experimental evidence. © 1970. |
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