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Valorization of Nutraceutical Industrial Coriander Seed Spent by the Process of Sustainable Adsorption System of Acid Black 52 from Aqueous Solution

The potential usage of coriander seed spent which is a nutraceutical industrial by-product in the removal of Acid Black 52 (AB52) dye from aqueous solutions was evaluated with respect to various experimental parameters including pH, initial dye concentration, adsorbent dosage, adsorbent particle siz...

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Main Authors: Taqui, Syed Noeman, Yahya, Rosiyah, Hassan, Aziz, Khanum, Farhath, Syed, Akheel Ahmed
Format: Article
Published: Springer International Publishing 2019
Subjects:
Q Science (General)
QD Chemistry
Online Access:http://eprints.um.edu.my/23275/
https://doi.org/10.1007/s41742-019-00207-7
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spelling my.um.eprints.232752019-12-23T02:39:08Z http://eprints.um.edu.my/23275/ Valorization of Nutraceutical Industrial Coriander Seed Spent by the Process of Sustainable Adsorption System of Acid Black 52 from Aqueous Solution Taqui, Syed Noeman Yahya, Rosiyah Hassan, Aziz Khanum, Farhath Syed, Akheel Ahmed Q Science (General) QD Chemistry The potential usage of coriander seed spent which is a nutraceutical industrial by-product in the removal of Acid Black 52 (AB52) dye from aqueous solutions was evaluated with respect to various experimental parameters including pH, initial dye concentration, adsorbent dosage, adsorbent particle size, duration of contact time and temperature. The optimal qe value at pH 2, pH 7 and pH 12 was 432 mg g−1, 164 mg g−1 and 220 mg g−1, respectively. Two-level fractional factorial experimental design model yielded maximum adsorption value of 867.00 mg g−1. The influence of each parameter and combination of parameters on the final adsorption capacity of the system has been shown by analysis of variance (ANOVA). Equilibrium data were analyzed by four two-parameter and five three-parameter isotherm models. The dye uptake obeyed pseudo-second order kinetic expression. Intra-particle diffusion showed that the adsorption mechanism was more governed by external mass transfer. AB52 dye adsorption on nutraceutical industrial coriander seed spent (NICSS) was endothermic and almost spontaneous. The NICSS has a highly fibrous matrix with hierarchical porous structure as evidenced by SEM images. The FTIR analysis of the spent confirmed the presence of cellulosic and ligno-cellulosic matter imparting both hydrophilic and hydrophobic properties. The results proved that NICSS efficiently removes AB52 dye from water and textile industrial effluent. © 2019, University of Tehran. Springer International Publishing 2019 Article PeerReviewed Taqui, Syed Noeman and Yahya, Rosiyah and Hassan, Aziz and Khanum, Farhath and Syed, Akheel Ahmed (2019) Valorization of Nutraceutical Industrial Coriander Seed Spent by the Process of Sustainable Adsorption System of Acid Black 52 from Aqueous Solution. International Journal of Environmental Research, 13 (4). pp. 639-659. ISSN 1735-6865 https://doi.org/10.1007/s41742-019-00207-7 doi:10.1007/s41742-019-00207-7
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
QD Chemistry
spellingShingle Q Science (General)
QD Chemistry
Taqui, Syed Noeman
Yahya, Rosiyah
Hassan, Aziz
Khanum, Farhath
Syed, Akheel Ahmed
Valorization of Nutraceutical Industrial Coriander Seed Spent by the Process of Sustainable Adsorption System of Acid Black 52 from Aqueous Solution
description The potential usage of coriander seed spent which is a nutraceutical industrial by-product in the removal of Acid Black 52 (AB52) dye from aqueous solutions was evaluated with respect to various experimental parameters including pH, initial dye concentration, adsorbent dosage, adsorbent particle size, duration of contact time and temperature. The optimal qe value at pH 2, pH 7 and pH 12 was 432 mg g−1, 164 mg g−1 and 220 mg g−1, respectively. Two-level fractional factorial experimental design model yielded maximum adsorption value of 867.00 mg g−1. The influence of each parameter and combination of parameters on the final adsorption capacity of the system has been shown by analysis of variance (ANOVA). Equilibrium data were analyzed by four two-parameter and five three-parameter isotherm models. The dye uptake obeyed pseudo-second order kinetic expression. Intra-particle diffusion showed that the adsorption mechanism was more governed by external mass transfer. AB52 dye adsorption on nutraceutical industrial coriander seed spent (NICSS) was endothermic and almost spontaneous. The NICSS has a highly fibrous matrix with hierarchical porous structure as evidenced by SEM images. The FTIR analysis of the spent confirmed the presence of cellulosic and ligno-cellulosic matter imparting both hydrophilic and hydrophobic properties. The results proved that NICSS efficiently removes AB52 dye from water and textile industrial effluent. © 2019, University of Tehran.
format Article
author Taqui, Syed Noeman
Yahya, Rosiyah
Hassan, Aziz
Khanum, Farhath
Syed, Akheel Ahmed
author_facet Taqui, Syed Noeman
Yahya, Rosiyah
Hassan, Aziz
Khanum, Farhath
Syed, Akheel Ahmed
author_sort Taqui, Syed Noeman
title Valorization of Nutraceutical Industrial Coriander Seed Spent by the Process of Sustainable Adsorption System of Acid Black 52 from Aqueous Solution
title_short Valorization of Nutraceutical Industrial Coriander Seed Spent by the Process of Sustainable Adsorption System of Acid Black 52 from Aqueous Solution
title_full Valorization of Nutraceutical Industrial Coriander Seed Spent by the Process of Sustainable Adsorption System of Acid Black 52 from Aqueous Solution
title_fullStr Valorization of Nutraceutical Industrial Coriander Seed Spent by the Process of Sustainable Adsorption System of Acid Black 52 from Aqueous Solution
title_full_unstemmed Valorization of Nutraceutical Industrial Coriander Seed Spent by the Process of Sustainable Adsorption System of Acid Black 52 from Aqueous Solution
title_sort valorization of nutraceutical industrial coriander seed spent by the process of sustainable adsorption system of acid black 52 from aqueous solution
publisher Springer International Publishing
publishDate 2019
url http://eprints.um.edu.my/23275/
https://doi.org/10.1007/s41742-019-00207-7
_version_ 1654960710927515648
score 13.211869

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