Excimer and exciplex formation in a pair of bright phosphorescent isomers constructed from Cu3(pyrazolate)3 and Cu3I3 coordination luminophores
Reported herein are a pair of supramolecular pseudo-isomers, namely, (Cu 3I 3)(Cu 3L 3) 2· H 2O (1) and (Cu 3I 3)(Cu 3L 3) 2 (2) (L = 3-(4-pyridyl)-5-isobutyl-pyrazolate), both of which incorporate Cu 3Pz 3 (Pz = pyrazolate) and Cu 3I 3 clusters as luminophores. The two complexes show distinct yello...
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| Main Authors: | , , , , |
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| Format: | Article |
| Published: |
Royal Society of Chemistry
2011
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/23008/ https://doi.org/10.1039/c1ra00566a |
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