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Design and the cation-templated self-assembly on the [MoOS3Cu3]+ based supramolecular polymeric clusters

Organic cation-templated self-assembly of 4,4′-bipy (4,4′-bipy = 4,4′-bipyridine) with [NH4]2MS2O 2 (M = Mo, W) and CuX (X = I) in the presence of bppt [bppt = 1, 5-bis (pyridinium) pentane] resulted in two novel neutral heterothiometallic cluster polymers: {[Mo2O2S6Cu 6BrI(4,4′-bipy)4] (4,4′-bipy)}...

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Main Authors: Zhang, Zhen-Hua, Wang, Hong-Mei, Niu, Yun-Yin, Wu, Ben-Lai, Ng, Seik Weng, Hou, Hong-Wei
Format: Article
Published: Elsevier 2011
Subjects:
Q Science (General)
QD Chemistry
Online Access:http://eprints.um.edu.my/22987/
https://doi.org/10.1016/j.inoche.2011.08.009
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spelling my.um.eprints.229872019-11-14T04:01:32Z http://eprints.um.edu.my/22987/ Design and the cation-templated self-assembly on the [MoOS3Cu3]+ based supramolecular polymeric clusters Zhang, Zhen-Hua Wang, Hong-Mei Niu, Yun-Yin Wu, Ben-Lai Ng, Seik Weng Hou, Hong-Wei Q Science (General) QD Chemistry Organic cation-templated self-assembly of 4,4′-bipy (4,4′-bipy = 4,4′-bipyridine) with [NH4]2MS2O 2 (M = Mo, W) and CuX (X = I) in the presence of bppt [bppt = 1, 5-bis (pyridinium) pentane] resulted in two novel neutral heterothiometallic cluster polymers: {[Mo2O2S6Cu 6BrI(4,4′-bipy)4] (4,4′-bipy)}n (1) and {[WOS3Cu3Br(4,4-bipy)2.5]•3 (DMF)}n (2). Compound 1 exhibits a neutral 3D 3-fold interpenetrating motif and compound 2 possesses a neutral 3D 4-fold interpenetrating architecture. Both of them have been characterized by IR, elemental analysis, TGA, UV-vis, PXRD, and single-crystal X-ray diffraction. The results may provide fascinating insights into the usage of template effect on the construction of the cluster-based coordination polymers. © 2011 Elsevier B.V. All rights reserved. Elsevier 2011 Article PeerReviewed Zhang, Zhen-Hua and Wang, Hong-Mei and Niu, Yun-Yin and Wu, Ben-Lai and Ng, Seik Weng and Hou, Hong-Wei (2011) Design and the cation-templated self-assembly on the [MoOS3Cu3]+ based supramolecular polymeric clusters. Inorganic Chemistry Communications, 14 (11). pp. 1783-1787. ISSN 1387-7003 https://doi.org/10.1016/j.inoche.2011.08.009 doi:10.1016/j.inoche.2011.08.009
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
QD Chemistry
spellingShingle Q Science (General)
QD Chemistry
Zhang, Zhen-Hua
Wang, Hong-Mei
Niu, Yun-Yin
Wu, Ben-Lai
Ng, Seik Weng
Hou, Hong-Wei
Design and the cation-templated self-assembly on the [MoOS3Cu3]+ based supramolecular polymeric clusters
description Organic cation-templated self-assembly of 4,4′-bipy (4,4′-bipy = 4,4′-bipyridine) with [NH4]2MS2O 2 (M = Mo, W) and CuX (X = I) in the presence of bppt [bppt = 1, 5-bis (pyridinium) pentane] resulted in two novel neutral heterothiometallic cluster polymers: {[Mo2O2S6Cu 6BrI(4,4′-bipy)4] (4,4′-bipy)}n (1) and {[WOS3Cu3Br(4,4-bipy)2.5]•3 (DMF)}n (2). Compound 1 exhibits a neutral 3D 3-fold interpenetrating motif and compound 2 possesses a neutral 3D 4-fold interpenetrating architecture. Both of them have been characterized by IR, elemental analysis, TGA, UV-vis, PXRD, and single-crystal X-ray diffraction. The results may provide fascinating insights into the usage of template effect on the construction of the cluster-based coordination polymers. © 2011 Elsevier B.V. All rights reserved.
format Article
author Zhang, Zhen-Hua
Wang, Hong-Mei
Niu, Yun-Yin
Wu, Ben-Lai
Ng, Seik Weng
Hou, Hong-Wei
author_facet Zhang, Zhen-Hua
Wang, Hong-Mei
Niu, Yun-Yin
Wu, Ben-Lai
Ng, Seik Weng
Hou, Hong-Wei
author_sort Zhang, Zhen-Hua
title Design and the cation-templated self-assembly on the [MoOS3Cu3]+ based supramolecular polymeric clusters
title_short Design and the cation-templated self-assembly on the [MoOS3Cu3]+ based supramolecular polymeric clusters
title_full Design and the cation-templated self-assembly on the [MoOS3Cu3]+ based supramolecular polymeric clusters
title_fullStr Design and the cation-templated self-assembly on the [MoOS3Cu3]+ based supramolecular polymeric clusters
title_full_unstemmed Design and the cation-templated self-assembly on the [MoOS3Cu3]+ based supramolecular polymeric clusters
title_sort design and the cation-templated self-assembly on the [moos3cu3]+ based supramolecular polymeric clusters
publisher Elsevier
publishDate 2011
url http://eprints.um.edu.my/22987/
https://doi.org/10.1016/j.inoche.2011.08.009
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score 13.244368

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