Synthesis of gold nanoparticles stabilized by a pyrazinium thioacetate ligand: A new colorimetric nanosensor for detection of heavy metal Pd(II)
We developed a facile method for the synthesis of Gold nanoparticles (AuNPs) stabilized by cationic 1-(3-(acetylthio)propyl)pyrazin-1-ium ligand denoted as APP. Gold nanoparticles stabilized by APP (APP-AuNPs) are found to be polydispersed in size and lie in the range of 5–10 nm. We report a robust...
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| 主要な著者: | , , , , , |
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| フォーマット: | 論文 |
| 出版事項: |
Elsevier
2018
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| 主題: | |
| オンライン･アクセス: | http://eprints.um.edu.my/22463/ https://doi.org/10.1016/j.snb.2017.11.040 |
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| 要約: | We developed a facile method for the synthesis of Gold nanoparticles (AuNPs) stabilized by cationic 1-(3-(acetylthio)propyl)pyrazin-1-ium ligand denoted as APP. Gold nanoparticles stabilized by APP (APP-AuNPs) are found to be polydispersed in size and lie in the range of 5–10 nm. We report a robust and sensitive protocol for the detection of heavy toxic metal ion Pd(II) in water using APP-AuNPs. From the fifteen salts tested, APP-AuNPs demonstrated a sensitive and selective spectrophotometric signal, as well as naked eye indication for recognition of Pd(II) ions. Pd(II) ions caused a colorimetric, distinguished response to APP-AuNPs based on the aggregation induced decrease of surface plasmon resonance (SPR) band. The nanosensor probe displayed a sensitive response to the Pd(II) ions in a wide range of concentration and pH, with detection limit of as low as 4.23 μM. Furthermore, the decrease in SPR band of APP-AuNPs due to Pd(II) ions was unaffected by tap water samples and/or human blood plasma. |
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