Structural characterization of copper (II) tetradecanoate with 2,2′-bipyridine and 4,4′-bipyridine to study magnetic properties

This paper presents synthesis, structural characterization and spintronic applications of copper (II) tetradecanoate derived magnetic complexes. The complexes were prepared by a chemical reaction between [Cu2(CH3(CH2)12COO)4](EtOH)2 and 2,2′-bipyridine-4,4′-bipyridine ligands respectively. The compl...

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Main Authors: Bedowr, Noha Said, Yahya, Rosiyah, Farhan, Nesrain
Format: Article
Published: Elsevier 2018
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Online Access:http://eprints.um.edu.my/22328/
https://doi.org/10.1016/j.jscs.2017.08.003
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spelling my.um.eprints.223282019-09-13T03:21:26Z http://eprints.um.edu.my/22328/ Structural characterization of copper (II) tetradecanoate with 2,2′-bipyridine and 4,4′-bipyridine to study magnetic properties Bedowr, Noha Said Yahya, Rosiyah Farhan, Nesrain Q Science (General) QD Chemistry This paper presents synthesis, structural characterization and spintronic applications of copper (II) tetradecanoate derived magnetic complexes. The complexes were prepared by a chemical reaction between [Cu2(CH3(CH2)12COO)4](EtOH)2 and 2,2′-bipyridine-4,4′-bipyridine ligands respectively. The complexes were further reacted between the product of the first reaction and 4,4′-bipyridine-2,2′-bipyridine respectively. The structural characterization techniques included elemental analysis, Fourier transformed infrared spectroscopy (FTIR), Ultra-violet–Visible (UV–Vis) spectroscopy, polarized optical microscopy, magnetic moment and thermogravimetric analysis. The structural and characterization results suggested that the synthesized complexes were binuclear and mononuclear covalent complexes of copper(II) with structural formulas [Cu2(η2-(OOCR)4](4,4′-bpy)2H2O] and [Cu(η1-(OOCR)2(2,2′-bpy) (4,4′-bpy)] respectively. Elsevier 2018 Article PeerReviewed Bedowr, Noha Said and Yahya, Rosiyah and Farhan, Nesrain (2018) Structural characterization of copper (II) tetradecanoate with 2,2′-bipyridine and 4,4′-bipyridine to study magnetic properties. Journal of Saudi Chemical Society, 22 (3). pp. 255-260. ISSN 1319-6103 https://doi.org/10.1016/j.jscs.2017.08.003 doi:10.1016/j.jscs.2017.08.003
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
QD Chemistry
spellingShingle Q Science (General)
QD Chemistry
Bedowr, Noha Said
Yahya, Rosiyah
Farhan, Nesrain
Structural characterization of copper (II) tetradecanoate with 2,2′-bipyridine and 4,4′-bipyridine to study magnetic properties
description This paper presents synthesis, structural characterization and spintronic applications of copper (II) tetradecanoate derived magnetic complexes. The complexes were prepared by a chemical reaction between [Cu2(CH3(CH2)12COO)4](EtOH)2 and 2,2′-bipyridine-4,4′-bipyridine ligands respectively. The complexes were further reacted between the product of the first reaction and 4,4′-bipyridine-2,2′-bipyridine respectively. The structural characterization techniques included elemental analysis, Fourier transformed infrared spectroscopy (FTIR), Ultra-violet–Visible (UV–Vis) spectroscopy, polarized optical microscopy, magnetic moment and thermogravimetric analysis. The structural and characterization results suggested that the synthesized complexes were binuclear and mononuclear covalent complexes of copper(II) with structural formulas [Cu2(η2-(OOCR)4](4,4′-bpy)2H2O] and [Cu(η1-(OOCR)2(2,2′-bpy) (4,4′-bpy)] respectively.
format Article
author Bedowr, Noha Said
Yahya, Rosiyah
Farhan, Nesrain
author_facet Bedowr, Noha Said
Yahya, Rosiyah
Farhan, Nesrain
author_sort Bedowr, Noha Said
title Structural characterization of copper (II) tetradecanoate with 2,2′-bipyridine and 4,4′-bipyridine to study magnetic properties
title_short Structural characterization of copper (II) tetradecanoate with 2,2′-bipyridine and 4,4′-bipyridine to study magnetic properties
title_full Structural characterization of copper (II) tetradecanoate with 2,2′-bipyridine and 4,4′-bipyridine to study magnetic properties
title_fullStr Structural characterization of copper (II) tetradecanoate with 2,2′-bipyridine and 4,4′-bipyridine to study magnetic properties
title_full_unstemmed Structural characterization of copper (II) tetradecanoate with 2,2′-bipyridine and 4,4′-bipyridine to study magnetic properties
title_sort structural characterization of copper (ii) tetradecanoate with 2,2′-bipyridine and 4,4′-bipyridine to study magnetic properties
publisher Elsevier
publishDate 2018
url http://eprints.um.edu.my/22328/
https://doi.org/10.1016/j.jscs.2017.08.003
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