Role of ionic liquid and tin (IV) oxide nanoparticles on the ionic conductivity of biodegradable solid polymer electrolyte

Solution casting technique is used to prepare solid polymer electrolyte (SPE) utilizing biodegradable hydroxyethyl cellulose (HEC) as host polymer and magnesium trifluoromethanesulfonate (MgTf2) salt as charge carrier. However, the performance of the SPE is hindered by it's low ionic conductivi...

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Main Authors: Chong, Mee Yoke, Numan, Arshid, Evyan, Y.C.Y., Cheng, W.H., Wong, L.S., Ramesh, Kasi, Ramesh, Subramaniam
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出版: Medwell Journals 2018
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在線閱讀:http://eprints.um.edu.my/22203/
http://medwelljournals.com/abstract/?doi=jeasci.2018.9807.9812
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spelling my.um.eprints.222032019-09-04T04:05:58Z http://eprints.um.edu.my/22203/ Role of ionic liquid and tin (IV) oxide nanoparticles on the ionic conductivity of biodegradable solid polymer electrolyte Chong, Mee Yoke Numan, Arshid Evyan, Y.C.Y. Cheng, W.H. Wong, L.S. Ramesh, Kasi Ramesh, Subramaniam Q Science (General) QC Physics Solution casting technique is used to prepare solid polymer electrolyte (SPE) utilizing biodegradable hydroxyethyl cellulose (HEC) as host polymer and magnesium trifluoromethanesulfonate (MgTf2) salt as charge carrier. However, the performance of the SPE is hindered by it's low ionic conductivity at room temperature. Thus, room temperature ionic liquid, 1-ethyl-3-methylimidazolium trifluoromethane sulfonate (EMIMTf) and tin (IV) oxide (SnO2) nanoparticles have been added into the SPE to overcome the shortcomings. As a result, the room temperature ionic conductivity improved to 9.28 × 10-5 and 2.84 × × 10-4 S/cm upon addition of 40 wt.% EMIMTf ionic liquid and 2 wt.% of SnO2 nanoparticles, respectively. The conductivity-temperature plot shows that the transportation of ions in these films obey Arrhenius theory. The improvement of the ionic conductivity at room temperature for HSn2 makes it attractive for application to electrochemical devices. Medwell Journals 2018 Article PeerReviewed Chong, Mee Yoke and Numan, Arshid and Evyan, Y.C.Y. and Cheng, W.H. and Wong, L.S. and Ramesh, Kasi and Ramesh, Subramaniam (2018) Role of ionic liquid and tin (IV) oxide nanoparticles on the ionic conductivity of biodegradable solid polymer electrolyte. Journal of Engineering and Applied Sciences, 13 (23). pp. 9807-9812. ISSN 1816-949X http://medwelljournals.com/abstract/?doi=jeasci.2018.9807.9812 doi:10.3923/jeasci.2018.9807.9812
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
QC Physics
spellingShingle Q Science (General)
QC Physics
Chong, Mee Yoke
Numan, Arshid
Evyan, Y.C.Y.
Cheng, W.H.
Wong, L.S.
Ramesh, Kasi
Ramesh, Subramaniam
Role of ionic liquid and tin (IV) oxide nanoparticles on the ionic conductivity of biodegradable solid polymer electrolyte
description Solution casting technique is used to prepare solid polymer electrolyte (SPE) utilizing biodegradable hydroxyethyl cellulose (HEC) as host polymer and magnesium trifluoromethanesulfonate (MgTf2) salt as charge carrier. However, the performance of the SPE is hindered by it's low ionic conductivity at room temperature. Thus, room temperature ionic liquid, 1-ethyl-3-methylimidazolium trifluoromethane sulfonate (EMIMTf) and tin (IV) oxide (SnO2) nanoparticles have been added into the SPE to overcome the shortcomings. As a result, the room temperature ionic conductivity improved to 9.28 × 10-5 and 2.84 × × 10-4 S/cm upon addition of 40 wt.% EMIMTf ionic liquid and 2 wt.% of SnO2 nanoparticles, respectively. The conductivity-temperature plot shows that the transportation of ions in these films obey Arrhenius theory. The improvement of the ionic conductivity at room temperature for HSn2 makes it attractive for application to electrochemical devices.
format Article
author Chong, Mee Yoke
Numan, Arshid
Evyan, Y.C.Y.
Cheng, W.H.
Wong, L.S.
Ramesh, Kasi
Ramesh, Subramaniam
author_facet Chong, Mee Yoke
Numan, Arshid
Evyan, Y.C.Y.
Cheng, W.H.
Wong, L.S.
Ramesh, Kasi
Ramesh, Subramaniam
author_sort Chong, Mee Yoke
title Role of ionic liquid and tin (IV) oxide nanoparticles on the ionic conductivity of biodegradable solid polymer electrolyte
title_short Role of ionic liquid and tin (IV) oxide nanoparticles on the ionic conductivity of biodegradable solid polymer electrolyte
title_full Role of ionic liquid and tin (IV) oxide nanoparticles on the ionic conductivity of biodegradable solid polymer electrolyte
title_fullStr Role of ionic liquid and tin (IV) oxide nanoparticles on the ionic conductivity of biodegradable solid polymer electrolyte
title_full_unstemmed Role of ionic liquid and tin (IV) oxide nanoparticles on the ionic conductivity of biodegradable solid polymer electrolyte
title_sort role of ionic liquid and tin (iv) oxide nanoparticles on the ionic conductivity of biodegradable solid polymer electrolyte
publisher Medwell Journals
publishDate 2018
url http://eprints.um.edu.my/22203/
http://medwelljournals.com/abstract/?doi=jeasci.2018.9807.9812
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score 13.250607